X-ray photoelectron spectroscopy study of copper sodium silicate glass surfaces

A. Mekki; D. Holland; C. F. McConville

doi:10.1016/S0022-3093(97)00048-3

X-ray photoelectron spectroscopy study of copper sodium silicate glass surfaces

A. Mekki
, D. Holland^*
, C. F. McConville

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

Copper oxide-containing, sodium silicate glasses with composition (0.70-x)SiO₂-0.30Na₂O-xCuO (x in the range 0-0.2), were prepared by conventional melting and casting. The surface structure has been investigated by X-ray photoelectron spectroscopy. Evidence for the presence of copper in the Cu⁺ state for glasses with x ≤ 0.14, and for both oxidation states (Cu⁺ and Cu²⁺) in the glass where x = 0.18, has been obtained from the "shake up" satellite structure of the Cu 2p core level spectra. A deconvolution procedure has been undertaken to determine quantitatively the [Cu²⁺]/[Cu_total] ratio. The non-bridging oxygen content, obtained from the deconvolution of the O 1s core level spectra, increases with increasing copper oxide content indicating that copper acts as a network modifier. The O 1s spectra were modelled in such a way as to separate the contributions from SiOCu and SiONa to the non-bridging oxygen signal.

Original language	English
Pages (from-to)	271-282
Number of pages	12
Journal	Journal of Non-Crystalline Solids
Volume	215
Issue number	2-3
DOIs	https://doi.org/10.1016/S0022-3093(97)00048-3
State	Published - Jul 1997

Bibliographical note

Funding Information:
One of us (A.M.) would like to acknowledge the support of King Fahd University of Petroleum and Minerals (KFUPM) and the Physics Department of KFUPM.

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

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10.1016/S0022-3093(97)00048-3

Cite this

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title = "X-ray photoelectron spectroscopy study of copper sodium silicate glass surfaces",

abstract = "Copper oxide-containing, sodium silicate glasses with composition (0.70-x)SiO2-0.30Na2O-xCuO (x in the range 0-0.2), were prepared by conventional melting and casting. The surface structure has been investigated by X-ray photoelectron spectroscopy. Evidence for the presence of copper in the Cu+ state for glasses with x ≤ 0.14, and for both oxidation states (Cu+ and Cu2+) in the glass where x = 0.18, has been obtained from the {"}shake up{"} satellite structure of the Cu 2p core level spectra. A deconvolution procedure has been undertaken to determine quantitatively the [Cu2+]/[Cutotal] ratio. The non-bridging oxygen content, obtained from the deconvolution of the O 1s core level spectra, increases with increasing copper oxide content indicating that copper acts as a network modifier. The O 1s spectra were modelled in such a way as to separate the contributions from SiOCu and SiONa to the non-bridging oxygen signal.",

author = "A. Mekki and D. Holland and McConville, \{C. F.\}",

note = "Funding Information: One of us (A.M.) would like to acknowledge the support of King Fahd University of Petroleum and Minerals (KFUPM) and the Physics Department of KFUPM.",

year = "1997",

month = jul,

doi = "10.1016/S0022-3093(97)00048-3",

language = "English",

volume = "215",

pages = "271--282",

journal = "Journal of Non-Crystalline Solids",

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T1 - X-ray photoelectron spectroscopy study of copper sodium silicate glass surfaces

AU - Mekki, A.

AU - Holland, D.

AU - McConville, C. F.

N1 - Funding Information: One of us (A.M.) would like to acknowledge the support of King Fahd University of Petroleum and Minerals (KFUPM) and the Physics Department of KFUPM.

PY - 1997/7

Y1 - 1997/7

N2 - Copper oxide-containing, sodium silicate glasses with composition (0.70-x)SiO2-0.30Na2O-xCuO (x in the range 0-0.2), were prepared by conventional melting and casting. The surface structure has been investigated by X-ray photoelectron spectroscopy. Evidence for the presence of copper in the Cu+ state for glasses with x ≤ 0.14, and for both oxidation states (Cu+ and Cu2+) in the glass where x = 0.18, has been obtained from the "shake up" satellite structure of the Cu 2p core level spectra. A deconvolution procedure has been undertaken to determine quantitatively the [Cu2+]/[Cutotal] ratio. The non-bridging oxygen content, obtained from the deconvolution of the O 1s core level spectra, increases with increasing copper oxide content indicating that copper acts as a network modifier. The O 1s spectra were modelled in such a way as to separate the contributions from SiOCu and SiONa to the non-bridging oxygen signal.

AB - Copper oxide-containing, sodium silicate glasses with composition (0.70-x)SiO2-0.30Na2O-xCuO (x in the range 0-0.2), were prepared by conventional melting and casting. The surface structure has been investigated by X-ray photoelectron spectroscopy. Evidence for the presence of copper in the Cu+ state for glasses with x ≤ 0.14, and for both oxidation states (Cu+ and Cu2+) in the glass where x = 0.18, has been obtained from the "shake up" satellite structure of the Cu 2p core level spectra. A deconvolution procedure has been undertaken to determine quantitatively the [Cu2+]/[Cutotal] ratio. The non-bridging oxygen content, obtained from the deconvolution of the O 1s core level spectra, increases with increasing copper oxide content indicating that copper acts as a network modifier. The O 1s spectra were modelled in such a way as to separate the contributions from SiOCu and SiONa to the non-bridging oxygen signal.

UR - https://www.scopus.com/pages/publications/0031549064

U2 - 10.1016/S0022-3093(97)00048-3

DO - 10.1016/S0022-3093(97)00048-3

M3 - Article

AN - SCOPUS:0031549064

SN - 0022-3093

VL - 215

SP - 271

EP - 282

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 2-3

ER -

X-ray photoelectron spectroscopy study of copper sodium silicate glass surfaces

Abstract

Bibliographical note

ASJC Scopus subject areas

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