Well-defined silica supported bipodal molybdenum oxo alkyl complexes: A model of the active sites of industrial olefin metathesis catalysts

Nicolas Merle; Frédéric Le Quéméner; Samir Barman; Manoja K. Samantaray; Kai C. Szeto; Aimery De Mallmann; Mostafa Taoufik; Jean Marie Basset

doi:10.1039/c7cc06041f

Well-defined silica supported bipodal molybdenum oxo alkyl complexes: A model of the active sites of industrial olefin metathesis catalysts

Nicolas Merle
, Frédéric Le Quéméner
, Samir Barman
, Manoja K. Samantaray
, Kai C. Szeto
, Aimery De Mallmann
, Mostafa Taoufik^*
, Jean Marie Basset

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A well-defined, silica-supported molybdenum oxo alkyl species, (SiO-)₂Mo(O)(CH₂^tBu)₂, was prepared by the selective grafting of Mo(O)(CH₂^tBu)₃Cl onto a silica partially dehydroxylated at 200 °C using a rigorous surface organometallic chemistry approach. The immobilized bipodal surface species, partly resembling the active species of industrial MoO₃/SiO₂ olefin metathesis catalysts, exhibited excellent functional group tolerance in conjunction with its high activity in homocoupling, self and ring closing olefin metathesis.

Original language	English
Pages (from-to)	11338-11341
Number of pages	4
Journal	Chemical Communications
Volume	53
Issue number	82
DOIs	https://doi.org/10.1039/c7cc06041f
State	Published - 2017
Externally published	Yes

Bibliographical note

Funding Information:
This study was supported by the Competitive Research Grant Program, supported by the KAUST Research Fund (project # 2174 CRG3). We would like to thank Olivier Mathon for his help during the recording of the XAS spectra on the BM23 beam-line at ESRF (experiment code IN-986).

Publisher Copyright:
© 2017 The Royal Society of Chemistry.

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c7cc06041f

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title = "Well-defined silica supported bipodal molybdenum oxo alkyl complexes: A model of the active sites of industrial olefin metathesis catalysts",

abstract = "A well-defined, silica-supported molybdenum oxo alkyl species, (SiO-)2Mo(O)(CH2tBu)2, was prepared by the selective grafting of Mo(O)(CH2tBu)3Cl onto a silica partially dehydroxylated at 200 °C using a rigorous surface organometallic chemistry approach. The immobilized bipodal surface species, partly resembling the active species of industrial MoO3/SiO2 olefin metathesis catalysts, exhibited excellent functional group tolerance in conjunction with its high activity in homocoupling, self and ring closing olefin metathesis.",

author = "Nicolas Merle and \{Le Qu{\'e}m{\'e}ner\}, Fr{\'e}d{\'e}ric and Samir Barman and Samantaray, \{Manoja K.\} and Szeto, \{Kai C.\} and \{De Mallmann\}, Aimery and Mostafa Taoufik and Basset, \{Jean Marie\}",

note = "Funding Information: This study was supported by the Competitive Research Grant Program, supported by the KAUST Research Fund (project \# 2174 CRG3). We would like to thank Olivier Mathon for his help during the recording of the XAS spectra on the BM23 beam-line at ESRF (experiment code IN-986). Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7cc06041f",

language = "English",

volume = "53",

pages = "11338--11341",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "82",

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TY - JOUR

T1 - Well-defined silica supported bipodal molybdenum oxo alkyl complexes

T2 - A model of the active sites of industrial olefin metathesis catalysts

AU - Merle, Nicolas

AU - Le Quéméner, Frédéric

AU - Barman, Samir

AU - Samantaray, Manoja K.

AU - Szeto, Kai C.

AU - De Mallmann, Aimery

AU - Taoufik, Mostafa

AU - Basset, Jean Marie

N1 - Funding Information: This study was supported by the Competitive Research Grant Program, supported by the KAUST Research Fund (project # 2174 CRG3). We would like to thank Olivier Mathon for his help during the recording of the XAS spectra on the BM23 beam-line at ESRF (experiment code IN-986). Publisher Copyright: © 2017 The Royal Society of Chemistry.

PY - 2017

Y1 - 2017

N2 - A well-defined, silica-supported molybdenum oxo alkyl species, (SiO-)2Mo(O)(CH2tBu)2, was prepared by the selective grafting of Mo(O)(CH2tBu)3Cl onto a silica partially dehydroxylated at 200 °C using a rigorous surface organometallic chemistry approach. The immobilized bipodal surface species, partly resembling the active species of industrial MoO3/SiO2 olefin metathesis catalysts, exhibited excellent functional group tolerance in conjunction with its high activity in homocoupling, self and ring closing olefin metathesis.

AB - A well-defined, silica-supported molybdenum oxo alkyl species, (SiO-)2Mo(O)(CH2tBu)2, was prepared by the selective grafting of Mo(O)(CH2tBu)3Cl onto a silica partially dehydroxylated at 200 °C using a rigorous surface organometallic chemistry approach. The immobilized bipodal surface species, partly resembling the active species of industrial MoO3/SiO2 olefin metathesis catalysts, exhibited excellent functional group tolerance in conjunction with its high activity in homocoupling, self and ring closing olefin metathesis.

UR - https://www.scopus.com/pages/publications/85031326588

U2 - 10.1039/c7cc06041f

DO - 10.1039/c7cc06041f

M3 - Article

C2 - 28967651

AN - SCOPUS:85031326588

SN - 1359-7345

VL - 53

SP - 11338

EP - 11341

JO - Chemical Communications

JF - Chemical Communications

IS - 82

ER -

Well-defined silica supported bipodal molybdenum oxo alkyl complexes: A model of the active sites of industrial olefin metathesis catalysts

Abstract

Bibliographical note

ASJC Scopus subject areas

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