Vibration-rotation transitions in the CF radical, studied by laser magnetic resonance spectroscopy at 7.8 μm

M. A. Gondal; W. Rohrbeck; W. Urban; R. Blanckart; J. M. Brown

doi:10.1016/0022-2852(83)90087-5

Vibration-rotation transitions in the CF radical, studied by laser magnetic resonance spectroscopy at 7.8 μm

M. A. Gondal, W. Rohrbeck, W. Urban, R. Blanckart, J. M. Brown^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Several transitions in the vibration-rotation spectrum of the CF radical in its X²Π state have been detected by CO-laser magnetic resonance. In addition to strong resonances for the ²Π_{3 2}-²Π_{3 2} transitions in the fundamental band at 1286 cm^-1, weaker "cross" ²Π_{3 2}-²Π_{1 2} and hot band transitions have also been observed. The ¹⁹F nuclear hyperfine splitting is clearly resolved for almost every transition. These observations provide an interesting comparison with the recent study of the same (1, 0) band of CF by diode laser spectroscopy.

Original language	English
Pages (from-to)	290-302
Number of pages	13
Journal	Journal of Molecular Spectroscopy
Volume	100
Issue number	2
DOIs	https://doi.org/10.1016/0022-2852(83)90087-5
State	Published - Aug 1983
Externally published	Yes

Bibliographical note

Funding Information:
The authors are gratefult o W. Seebassf or help in the experimentalw ork. M.A.G. thanks the DAAD for financials upport. The work has been funded by Deutsche Forschungsgemeinschaft, SFB 42.

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Spectroscopy
Physical and Theoretical Chemistry

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Cite this

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title = "Vibration-rotation transitions in the CF radical, studied by laser magnetic resonance spectroscopy at 7.8 μm",

abstract = "Several transitions in the vibration-rotation spectrum of the CF radical in its X2Π state have been detected by CO-laser magnetic resonance. In addition to strong resonances for the 2Π 3 2-2Π 3 2 transitions in the fundamental band at 1286 cm-1, weaker {"}cross{"} 2Π 3 2-2Π 1 2 and hot band transitions have also been observed. The 19F nuclear hyperfine splitting is clearly resolved for almost every transition. These observations provide an interesting comparison with the recent study of the same (1, 0) band of CF by diode laser spectroscopy.",

author = "Gondal, \{M. A.\} and W. Rohrbeck and W. Urban and R. Blanckart and Brown, \{J. M.\}",

note = "Funding Information: The authors are gratefult o W. Seebassf or help in the experimentalw ork. M.A.G. thanks the DAAD for financials upport. The work has been funded by Deutsche Forschungsgemeinschaft, SFB 42.",

year = "1983",

month = aug,

doi = "10.1016/0022-2852(83)90087-5",

language = "English",

volume = "100",

pages = "290--302",

journal = "Journal of Molecular Spectroscopy",

issn = "0022-2852",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Vibration-rotation transitions in the CF radical, studied by laser magnetic resonance spectroscopy at 7.8 μm

AU - Gondal, M. A.

AU - Rohrbeck, W.

AU - Urban, W.

AU - Blanckart, R.

AU - Brown, J. M.

N1 - Funding Information: The authors are gratefult o W. Seebassf or help in the experimentalw ork. M.A.G. thanks the DAAD for financials upport. The work has been funded by Deutsche Forschungsgemeinschaft, SFB 42.

PY - 1983/8

Y1 - 1983/8

N2 - Several transitions in the vibration-rotation spectrum of the CF radical in its X2Π state have been detected by CO-laser magnetic resonance. In addition to strong resonances for the 2Π 3 2-2Π 3 2 transitions in the fundamental band at 1286 cm-1, weaker "cross" 2Π 3 2-2Π 1 2 and hot band transitions have also been observed. The 19F nuclear hyperfine splitting is clearly resolved for almost every transition. These observations provide an interesting comparison with the recent study of the same (1, 0) band of CF by diode laser spectroscopy.

AB - Several transitions in the vibration-rotation spectrum of the CF radical in its X2Π state have been detected by CO-laser magnetic resonance. In addition to strong resonances for the 2Π 3 2-2Π 3 2 transitions in the fundamental band at 1286 cm-1, weaker "cross" 2Π 3 2-2Π 1 2 and hot band transitions have also been observed. The 19F nuclear hyperfine splitting is clearly resolved for almost every transition. These observations provide an interesting comparison with the recent study of the same (1, 0) band of CF by diode laser spectroscopy.

UR - https://www.scopus.com/pages/publications/0000520668

U2 - 10.1016/0022-2852(83)90087-5

DO - 10.1016/0022-2852(83)90087-5

M3 - Article

AN - SCOPUS:0000520668

SN - 0022-2852

VL - 100

SP - 290

EP - 302

JO - Journal of Molecular Spectroscopy

JF - Journal of Molecular Spectroscopy

IS - 2

ER -

Vibration-rotation transitions in the CF radical, studied by laser magnetic resonance spectroscopy at 7.8 μm

Abstract

Bibliographical note

ASJC Scopus subject areas

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