Vapor pressure of aqueous methyldiethanolamine mixed with ionic liquids

Afshin Ahmady; Ahmad Shamiri; Mohd Ali Hashim; Mohamed Kheireddine Aroua

doi:10.1016/j.jtice.2013.07.004

Vapor pressure of aqueous methyldiethanolamine mixed with ionic liquids

Afshin Ahmady
, Ahmad Shamiri
, Mohd Ali Hashim
, Mohamed Kheireddine Aroua^*

^*Corresponding author for this work

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Vapor pressure of aqueous methyldiethanolamine (MDEA) mixed with various concentrations of 1-butyl-3-methyl-imidazolium tetrafluoroborate ([bmim][BF₄]) and 1-butyl-3-methyl-imidazoliumdicyanamide ([bmim][DCA]) have been measured and compared with conventional solvents.A standard response surface methodology (RSM) design, namely central composite design (CCD) has been applied in this work to investigate the effects of temperature and concentration of Piperazine, [bmim][BF₄] and [bmim][DCA] on the vapor pressure of aqueous 4kmolm^-3 MDEA.The vapor pressure data of aqueous 4kmolm^-3 MDEA mixed with ionic liquids ranging from 0 to 2.0kmolm^-3 and temperatures ranging from 30 to 80°C, showed that the ionic liquids reduced the vapor pressure of solvents with the order of [bmim][DCA]>[bmim][BF₄].The experimental values are in good agreement with the values predicted by the models. The model results showed that the quadratic model was suitable and sufficient for predicting the vapor pressure of solutions in the investigated ranges of temperature and concentration.

Original language	English
Pages (from-to)	380-386
Number of pages	7
Journal	Journal of the Taiwan Institute of Chemical Engineers
Volume	45
Issue number	2
DOIs	https://doi.org/10.1016/j.jtice.2013.07.004
State	Published - Mar 2014

Keywords

Ionic liquid
MDEA
Piperazine
Quadratic model
Vapor pressure

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Access to Document

10.1016/j.jtice.2013.07.004

Cite this

@article{d55464af1eb84783ba292ad0817f5938,

title = "Vapor pressure of aqueous methyldiethanolamine mixed with ionic liquids",

abstract = "Vapor pressure of aqueous methyldiethanolamine (MDEA) mixed with various concentrations of 1-butyl-3-methyl-imidazolium tetrafluoroborate ([bmim][BF4]) and 1-butyl-3-methyl-imidazoliumdicyanamide ([bmim][DCA]) have been measured and compared with conventional solvents.A standard response surface methodology (RSM) design, namely central composite design (CCD) has been applied in this work to investigate the effects of temperature and concentration of Piperazine, [bmim][BF4] and [bmim][DCA] on the vapor pressure of aqueous 4kmolm-3 MDEA.The vapor pressure data of aqueous 4kmolm-3 MDEA mixed with ionic liquids ranging from 0 to 2.0kmolm-3 and temperatures ranging from 30 to 80°C, showed that the ionic liquids reduced the vapor pressure of solvents with the order of [bmim][DCA]>[bmim][BF4].The experimental values are in good agreement with the values predicted by the models. The model results showed that the quadratic model was suitable and sufficient for predicting the vapor pressure of solutions in the investigated ranges of temperature and concentration.",

keywords = "Ionic liquid, MDEA, Piperazine, Quadratic model, Vapor pressure",

author = "Afshin Ahmady and Ahmad Shamiri and Hashim, \{Mohd Ali\} and Aroua, \{Mohamed Kheireddine\}",

year = "2014",

month = mar,

doi = "10.1016/j.jtice.2013.07.004",

language = "English",

volume = "45",

pages = "380--386",

number = "2",

}

TY - JOUR

T1 - Vapor pressure of aqueous methyldiethanolamine mixed with ionic liquids

AU - Ahmady, Afshin

AU - Shamiri, Ahmad

AU - Hashim, Mohd Ali

AU - Aroua, Mohamed Kheireddine

PY - 2014/3

Y1 - 2014/3

N2 - Vapor pressure of aqueous methyldiethanolamine (MDEA) mixed with various concentrations of 1-butyl-3-methyl-imidazolium tetrafluoroborate ([bmim][BF4]) and 1-butyl-3-methyl-imidazoliumdicyanamide ([bmim][DCA]) have been measured and compared with conventional solvents.A standard response surface methodology (RSM) design, namely central composite design (CCD) has been applied in this work to investigate the effects of temperature and concentration of Piperazine, [bmim][BF4] and [bmim][DCA] on the vapor pressure of aqueous 4kmolm-3 MDEA.The vapor pressure data of aqueous 4kmolm-3 MDEA mixed with ionic liquids ranging from 0 to 2.0kmolm-3 and temperatures ranging from 30 to 80°C, showed that the ionic liquids reduced the vapor pressure of solvents with the order of [bmim][DCA]>[bmim][BF4].The experimental values are in good agreement with the values predicted by the models. The model results showed that the quadratic model was suitable and sufficient for predicting the vapor pressure of solutions in the investigated ranges of temperature and concentration.

AB - Vapor pressure of aqueous methyldiethanolamine (MDEA) mixed with various concentrations of 1-butyl-3-methyl-imidazolium tetrafluoroborate ([bmim][BF4]) and 1-butyl-3-methyl-imidazoliumdicyanamide ([bmim][DCA]) have been measured and compared with conventional solvents.A standard response surface methodology (RSM) design, namely central composite design (CCD) has been applied in this work to investigate the effects of temperature and concentration of Piperazine, [bmim][BF4] and [bmim][DCA] on the vapor pressure of aqueous 4kmolm-3 MDEA.The vapor pressure data of aqueous 4kmolm-3 MDEA mixed with ionic liquids ranging from 0 to 2.0kmolm-3 and temperatures ranging from 30 to 80°C, showed that the ionic liquids reduced the vapor pressure of solvents with the order of [bmim][DCA]>[bmim][BF4].The experimental values are in good agreement with the values predicted by the models. The model results showed that the quadratic model was suitable and sufficient for predicting the vapor pressure of solutions in the investigated ranges of temperature and concentration.

KW - Ionic liquid

KW - MDEA

KW - Piperazine

KW - Quadratic model

KW - Vapor pressure

UR - https://www.scopus.com/pages/publications/84894682822

U2 - 10.1016/j.jtice.2013.07.004

DO - 10.1016/j.jtice.2013.07.004

M3 - Article

AN - SCOPUS:84894682822

SN - 1876-1070

VL - 45

SP - 380

EP - 386

JO - Journal of the Taiwan Institute of Chemical Engineers

JF - Journal of the Taiwan Institute of Chemical Engineers

IS - 2

ER -