Vacuum UV of a PPV type polymer and possible PTFE induced orientation

Mikkel Jørgensen; Peter Sommer-Larsen; Kion Norrman; Frederik C. Krebs

doi:10.1016/j.synthmet.2003.08.008

Vacuum UV of a PPV type polymer and possible PTFE induced orientation

Mikkel Jørgensen^*, Peter Sommer-Larsen, Kion Norrman, Frederik C. Krebs

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Films of poly(2,5-dinonyl-1,4-phenylene-vinylene-1,4-phenylene-vinylene) spin coated or cast on lithium fluoride disks, either pristine or PTFE coated, where studied by vacuum ultraviolet (VUV) techniques in the 120-350nm range. Significant spectral differences in the low wavelength band corresponding to the aliphatic C(sp³)-H(1s) to unoccupied H(1s) transition were observed that could be related to orientation effects induced by the PTFE coating. The local density functional calculated spectrum was used to assign the different transitions and to obtain information of transition dipole moments.

Original language	English
Pages (from-to)	121-125
Number of pages	5
Journal	Synthetic Metals
Volume	142
Issue number	1-3
DOIs	https://doi.org/10.1016/j.synthmet.2003.08.008
State	Published - 13 Apr 2004
Externally published	Yes

Bibliographical note

Funding Information:
This work was supported by the Danish Technical Research Council (STVF). We would also like to express sincere gratitude to Søren V. Hoffmann for technical support at the ASTRID storage ring and at the UV1 beamline.

Keywords

Poly(phenylenevinylene)
Vacuum ultraviolet spectroscopy

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/j.synthmet.2003.08.008

Cite this

@article{27bae8308ca44882a0eee37dc7a7a5dd,

title = "Vacuum UV of a PPV type polymer and possible PTFE induced orientation",

abstract = "Films of poly(2,5-dinonyl-1,4-phenylene-vinylene-1,4-phenylene-vinylene) spin coated or cast on lithium fluoride disks, either pristine or PTFE coated, where studied by vacuum ultraviolet (VUV) techniques in the 120-350nm range. Significant spectral differences in the low wavelength band corresponding to the aliphatic C(sp3)-H(1s) to unoccupied H(1s) transition were observed that could be related to orientation effects induced by the PTFE coating. The local density functional calculated spectrum was used to assign the different transitions and to obtain information of transition dipole moments.",

keywords = "Poly(phenylenevinylene), Vacuum ultraviolet spectroscopy",

author = "Mikkel J{\o}rgensen and Peter Sommer-Larsen and Kion Norrman and Krebs, \{Frederik C.\}",

note = "Funding Information: This work was supported by the Danish Technical Research Council (STVF). We would also like to express sincere gratitude to S{\o}ren V. Hoffmann for technical support at the ASTRID storage ring and at the UV1 beamline.",

year = "2004",

month = apr,

day = "13",

doi = "10.1016/j.synthmet.2003.08.008",

language = "English",

volume = "142",

pages = "121--125",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

number = "1-3",

}

TY - JOUR

T1 - Vacuum UV of a PPV type polymer and possible PTFE induced orientation

AU - Jørgensen, Mikkel

AU - Sommer-Larsen, Peter

AU - Norrman, Kion

AU - Krebs, Frederik C.

N1 - Funding Information: This work was supported by the Danish Technical Research Council (STVF). We would also like to express sincere gratitude to Søren V. Hoffmann for technical support at the ASTRID storage ring and at the UV1 beamline.

PY - 2004/4/13

Y1 - 2004/4/13

N2 - Films of poly(2,5-dinonyl-1,4-phenylene-vinylene-1,4-phenylene-vinylene) spin coated or cast on lithium fluoride disks, either pristine or PTFE coated, where studied by vacuum ultraviolet (VUV) techniques in the 120-350nm range. Significant spectral differences in the low wavelength band corresponding to the aliphatic C(sp3)-H(1s) to unoccupied H(1s) transition were observed that could be related to orientation effects induced by the PTFE coating. The local density functional calculated spectrum was used to assign the different transitions and to obtain information of transition dipole moments.

AB - Films of poly(2,5-dinonyl-1,4-phenylene-vinylene-1,4-phenylene-vinylene) spin coated or cast on lithium fluoride disks, either pristine or PTFE coated, where studied by vacuum ultraviolet (VUV) techniques in the 120-350nm range. Significant spectral differences in the low wavelength band corresponding to the aliphatic C(sp3)-H(1s) to unoccupied H(1s) transition were observed that could be related to orientation effects induced by the PTFE coating. The local density functional calculated spectrum was used to assign the different transitions and to obtain information of transition dipole moments.

KW - Poly(phenylenevinylene)

KW - Vacuum ultraviolet spectroscopy

UR - https://www.scopus.com/pages/publications/1842427244

U2 - 10.1016/j.synthmet.2003.08.008

DO - 10.1016/j.synthmet.2003.08.008

M3 - Article

AN - SCOPUS:1842427244

SN - 0379-6779

VL - 142

SP - 121

EP - 125

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -

Vacuum UV of a PPV type polymer and possible PTFE induced orientation

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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