Uniformly dispersed flowery EuZrSe3 derived from the europium-based metal–organic framework for energy storage devices

  • Abdul Ghafoor Abid
  • , Soumaya Gouadria
  • , Sumaira Manzoor
  • , Khadijah Mohammed Saleh Katubi
  • , Karam Jabbour
  • , Muhammad Abdullah
  • , Mehar Un Nisa
  • , Salma Aman
  • , Mohammed Sultan Al-Buriahi
  • , Muhammad Naeem Ashiq*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

63 Scopus citations

Abstract

Recently, it has become more popular to use in-situ growth of transition metal chalcogenides for efficacious supercapacitor (SCs) applications. Metal-organic framework (MOF) is considered as a good source of precursor for a transition metal. Herein, Eu-MOF was used as a precursor for Eu transition metal to fabricate EuZrSe3 via the wet chemical method. The various physical and chemical characteristics such as X-ray diffraction spectroscopy (XRD), surface Scanning electron microscopy (SEM), and Brunner-Emmet Teller were utilized to study the phase orientation, crystallinity, morphology, and textual properties of fabricated material, respectively. All the electrochemical parameters like polarization curve (CV), galvanostatic charge–discharge (GCD) and electrochemical impedance spectroscopy (EIS) for estimating various parameters such as specific capacitance (Cs) around 1543 F/g & detected a remarkable energy density of 97 Wh/kg at a current density around 3.0 A/g in 2.0 M alkaline KOH electrolyte. Enhanced performance of the fabricated novel electrode owing to its huge electroactive surface area and excellent electrochemical conductivity and good morphology. Despite its greater specific energy (97 Wh/kg) and high-power density (658.8 W/kg), it also has 93.58 % retention efficiency after 10,000 cycles.

Original languageEnglish
Article number127066
JournalFuel
Volume336
DOIs
StatePublished - 15 Mar 2023
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2022 Elsevier Ltd

Keywords

  • Cyclic voltammetry
  • EuZrSe
  • Specific capacitance
  • Supercapacitors

ASJC Scopus subject areas

  • General Chemical Engineering
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Organic Chemistry

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