Abstract
Ascorbic acid was used for the first time to synthesize crystalline starch nanoparticles (CSNP). The physical properties of the CSNP were investigated. Rheological properties of the crystalline starch nanofluid (CSNF) were compared with native cassava starch (CS) and commercial polymer xanthan. Interfacial properties of the CSNF at the interface of oil and water (O/W) were investigated at different concentrations and temperatures. Wettability alteration efficiency of CSNF on oil-wet sandstone surface was investigated using the sessile drop method. Core flooding experiment was conducted at reservoir conditions. The methods were effective in producing spherical and polygonal nanoparticles with a mean diameter of 100 nm and increased in crystallinity of 7%. Viscosity increased with increase in surface area and temperature of the CSNF compared to a decrease in viscosity as the temperature increases for xanthan. Interfacial tension (IFT) decreased with increase in concentration of CSNF, electrolyte and temperature. The results show that CSNF can change the wettability of sandstone at low concentration, high salinity and elevated temperature. Pressure drops data shows stability of CSNF at 120 °C. The formation of oil bank was enough to increase oil recovery by 23%.
| Original language | English |
|---|---|
| Pages (from-to) | 1251-1271 |
| Number of pages | 21 |
| Journal | International Journal of Biological Macromolecules |
| Volume | 148 |
| DOIs | |
| State | Published - 1 Apr 2020 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:© 2019 Elsevier B.V.
Keywords
- Enhanced oil recovery
- Nanoparticles
- Ultrasonic
ASJC Scopus subject areas
- Structural Biology
- Biochemistry
- Molecular Biology