Ultrasound assisted synthesis of chalcones as green corrosion inhibitors for mild steel in 1M hydrochloric solution

Pooja Singh; M. A. Quraishi; E. E. Ebenso; Chandra Bhan Verma

Ultrasound assisted synthesis of chalcones as green corrosion inhibitors for mild steel in 1M hydrochloric solution

Pooja Singh, M. A. Quraishi^*, E. E. Ebenso, Chandra Bhan Verma

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

The three chalcones namely (E)-3-(4-hydroxyphenyl)-N-phenylacrylamide (INH-1), (E)-3-(4dimethylamino)phenyl)-N-phenylacrylamide (INH-2) and (E) -3-(4-hydroxy-3-methoxyphenyl)-N-phenylacrylamide (INH-3) were synthesized and their corrosion inhibition properties on mild steel in 1M HCl was investigated using weight loss, potentiodynamic polarization method, linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) techniques. Potentiodynamic results showed that, chalcones are act as mixed type inhibitors and adsorption of these compounds follow Langmuir adsorption isotherm. Nyquist plots indicates that the addition of chalcones increases the charge-transfer resistance (R_ct) and decreases the double-layer capacitance (C_dl) of the corrosion process this reveals that investigated chalcones inhibits mild steel corrosion by adsorption on its surface. Some thermodynamic and kinetic parameters also determined in relevance to describe the mechanism of adsorption.

Original language	English
Pages (from-to)	7446-7459
Number of pages	14
Journal	International Journal of Electrochemical Science
Volume	9
Issue number	12
State	Published - 2014
Externally published	Yes

Keywords

Acid corrosion
Chalcone
Mild steel
Thermodynamic parametersvEIS

ASJC Scopus subject areas

Electrochemistry

Cite this

@article{65b2b478e07f4a3187a91ca25e12d615,

title = "Ultrasound assisted synthesis of chalcones as green corrosion inhibitors for mild steel in 1M hydrochloric solution",

abstract = "The three chalcones namely (E)-3-(4-hydroxyphenyl)-N-phenylacrylamide (INH-1), (E)-3-(4dimethylamino)phenyl)-N-phenylacrylamide (INH-2) and (E) -3-(4-hydroxy-3-methoxyphenyl)-N-phenylacrylamide (INH-3) were synthesized and their corrosion inhibition properties on mild steel in 1M HCl was investigated using weight loss, potentiodynamic polarization method, linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) techniques. Potentiodynamic results showed that, chalcones are act as mixed type inhibitors and adsorption of these compounds follow Langmuir adsorption isotherm. Nyquist plots indicates that the addition of chalcones increases the charge-transfer resistance (Rct) and decreases the double-layer capacitance (Cdl) of the corrosion process this reveals that investigated chalcones inhibits mild steel corrosion by adsorption on its surface. Some thermodynamic and kinetic parameters also determined in relevance to describe the mechanism of adsorption.",

keywords = "Acid corrosion, Chalcone, Mild steel, Thermodynamic parametersvEIS",

author = "Pooja Singh and Quraishi, \{M. A.\} and Ebenso, \{E. E.\} and Verma, \{Chandra Bhan\}",

year = "2014",

language = "English",

volume = "9",

pages = "7446--7459",

journal = "International Journal of Electrochemical Science",

issn = "1452-3981",

publisher = "Elsevier B.V.",

number = "12",

}

TY - JOUR

T1 - Ultrasound assisted synthesis of chalcones as green corrosion inhibitors for mild steel in 1M hydrochloric solution

AU - Singh, Pooja

AU - Quraishi, M. A.

AU - Ebenso, E. E.

AU - Verma, Chandra Bhan

PY - 2014

Y1 - 2014

N2 - The three chalcones namely (E)-3-(4-hydroxyphenyl)-N-phenylacrylamide (INH-1), (E)-3-(4dimethylamino)phenyl)-N-phenylacrylamide (INH-2) and (E) -3-(4-hydroxy-3-methoxyphenyl)-N-phenylacrylamide (INH-3) were synthesized and their corrosion inhibition properties on mild steel in 1M HCl was investigated using weight loss, potentiodynamic polarization method, linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) techniques. Potentiodynamic results showed that, chalcones are act as mixed type inhibitors and adsorption of these compounds follow Langmuir adsorption isotherm. Nyquist plots indicates that the addition of chalcones increases the charge-transfer resistance (Rct) and decreases the double-layer capacitance (Cdl) of the corrosion process this reveals that investigated chalcones inhibits mild steel corrosion by adsorption on its surface. Some thermodynamic and kinetic parameters also determined in relevance to describe the mechanism of adsorption.

AB - The three chalcones namely (E)-3-(4-hydroxyphenyl)-N-phenylacrylamide (INH-1), (E)-3-(4dimethylamino)phenyl)-N-phenylacrylamide (INH-2) and (E) -3-(4-hydroxy-3-methoxyphenyl)-N-phenylacrylamide (INH-3) were synthesized and their corrosion inhibition properties on mild steel in 1M HCl was investigated using weight loss, potentiodynamic polarization method, linear polarization resistance (LPR) and electrochemical impedance spectroscopy (EIS) techniques. Potentiodynamic results showed that, chalcones are act as mixed type inhibitors and adsorption of these compounds follow Langmuir adsorption isotherm. Nyquist plots indicates that the addition of chalcones increases the charge-transfer resistance (Rct) and decreases the double-layer capacitance (Cdl) of the corrosion process this reveals that investigated chalcones inhibits mild steel corrosion by adsorption on its surface. Some thermodynamic and kinetic parameters also determined in relevance to describe the mechanism of adsorption.

KW - Acid corrosion

KW - Chalcone

KW - Mild steel

KW - Thermodynamic parametersvEIS

UR - https://www.scopus.com/pages/publications/84908691608

M3 - Article

AN - SCOPUS:84908691608

SN - 1452-3981

VL - 9

SP - 7446

EP - 7459

JO - International Journal of Electrochemical Science

JF - International Journal of Electrochemical Science

IS - 12

ER -

Ultrasound assisted synthesis of chalcones as green corrosion inhibitors for mild steel in 1M hydrochloric solution

Abstract

Keywords

ASJC Scopus subject areas

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