Ultralarge Free-Standing Imine-Based Covalent Organic Framework Membranes Fabricated via Compression

Jesús Martín-Illán; José Antonio Suárez; Julio Gómez-Herrero; Pablo Ares; Daniel Gallego-Fuente; Youdong Cheng; Dan Zhao; Daniel Maspoch; Félix Zamora

doi:10.1002/advs.202104643

Ultralarge Free-Standing Imine-Based Covalent Organic Framework Membranes Fabricated via Compression

Jesús Martín-Illán
, José Antonio Suárez
, Julio Gómez-Herrero
, Pablo Ares
, Daniel Gallego-Fuente
, Youdong Cheng
, Dan Zhao
, Daniel Maspoch
, Félix Zamora^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

Demand continues for processing methods to shape covalent organic frameworks (COFs) into macroscopic objects that are needed for their practical applications. Herein, a simple compression method to prepare large-scale, free-standing homogeneous and porous imine-based COF-membranes with dimensions in the centimeter range and excellent mechanical properties is reported. This method entails the compression of imine-based COF-aerogels, which undergo a morphological change from an elastic to plastic material. The COF-membranes fabricated upon compression show good performances for the separation of gas mixtures of industrial interest, N₂/CO₂ and CH₄/CO₂. It is believed that the new procedure paves the way to a broader range of COF-membranes.

Original language	English
Article number	2104643
Journal	Advanced Science
Volume	9
Issue number	7
DOIs	https://doi.org/10.1002/advs.202104643
State	Published - 4 Mar 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2022 The Authors. Advanced Science published by Wiley-VCH GmbH.

Keywords

aerogels
COF-membranes
covalent organic frameworks
gas mixtures separation
porous materials

ASJC Scopus subject areas

Medicine (miscellaneous)
General Chemical Engineering
General Materials Science
Biochemistry, Genetics and Molecular Biology (miscellaneous)
General Engineering
General Physics and Astronomy

Access to Document

10.1002/advs.202104643

Cite this

@article{65d2e1ce069649e791c940a296695039,

title = "Ultralarge Free-Standing Imine-Based Covalent Organic Framework Membranes Fabricated via Compression",

abstract = "Demand continues for processing methods to shape covalent organic frameworks (COFs) into macroscopic objects that are needed for their practical applications. Herein, a simple compression method to prepare large-scale, free-standing homogeneous and porous imine-based COF-membranes with dimensions in the centimeter range and excellent mechanical properties is reported. This method entails the compression of imine-based COF-aerogels, which undergo a morphological change from an elastic to plastic material. The COF-membranes fabricated upon compression show good performances for the separation of gas mixtures of industrial interest, N2/CO2 and CH4/CO2. It is believed that the new procedure paves the way to a broader range of COF-membranes.",

keywords = "aerogels, COF-membranes, covalent organic frameworks, gas mixtures separation, porous materials",

author = "Jes{\'u}s Mart{\'i}n-Ill{\'a}n and Su{\'a}rez, \{Jos{\'e} Antonio\} and Julio G{\'o}mez-Herrero and Pablo Ares and Daniel Gallego-Fuente and Youdong Cheng and Dan Zhao and Daniel Maspoch and F{\'e}lix Zamora",

note = "Publisher Copyright: {\textcopyright} 2022 The Authors. Advanced Science published by Wiley-VCH GmbH.",

year = "2022",

month = mar,

day = "4",

doi = "10.1002/advs.202104643",

language = "English",

volume = "9",

journal = "Advanced Science",

issn = "2198-3844",

publisher = "Wiley-VCH Verlag",

number = "7",

}

TY - JOUR

T1 - Ultralarge Free-Standing Imine-Based Covalent Organic Framework Membranes Fabricated via Compression

AU - Martín-Illán, Jesús

AU - Suárez, José Antonio

AU - Gómez-Herrero, Julio

AU - Ares, Pablo

AU - Gallego-Fuente, Daniel

AU - Cheng, Youdong

AU - Zhao, Dan

AU - Maspoch, Daniel

AU - Zamora, Félix

PY - 2022/3/4

Y1 - 2022/3/4

N2 - Demand continues for processing methods to shape covalent organic frameworks (COFs) into macroscopic objects that are needed for their practical applications. Herein, a simple compression method to prepare large-scale, free-standing homogeneous and porous imine-based COF-membranes with dimensions in the centimeter range and excellent mechanical properties is reported. This method entails the compression of imine-based COF-aerogels, which undergo a morphological change from an elastic to plastic material. The COF-membranes fabricated upon compression show good performances for the separation of gas mixtures of industrial interest, N2/CO2 and CH4/CO2. It is believed that the new procedure paves the way to a broader range of COF-membranes.

AB - Demand continues for processing methods to shape covalent organic frameworks (COFs) into macroscopic objects that are needed for their practical applications. Herein, a simple compression method to prepare large-scale, free-standing homogeneous and porous imine-based COF-membranes with dimensions in the centimeter range and excellent mechanical properties is reported. This method entails the compression of imine-based COF-aerogels, which undergo a morphological change from an elastic to plastic material. The COF-membranes fabricated upon compression show good performances for the separation of gas mixtures of industrial interest, N2/CO2 and CH4/CO2. It is believed that the new procedure paves the way to a broader range of COF-membranes.

KW - aerogels

KW - COF-membranes

KW - covalent organic frameworks

KW - gas mixtures separation

KW - porous materials

UR - https://www.scopus.com/pages/publications/85122810668

U2 - 10.1002/advs.202104643

DO - 10.1002/advs.202104643

M3 - Article

C2 - 35038248

AN - SCOPUS:85122810668

SN - 2198-3844

VL - 9

JO - Advanced Science

JF - Advanced Science

IS - 7

M1 - 2104643

ER -

Ultralarge Free-Standing Imine-Based Covalent Organic Framework Membranes Fabricated via Compression

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this