Ultra-weak chemiluminescence from the decomposition of peroxymonocarbonate

Hui Chen; Syed Niaz Ali Shah; Jin Ming Lin

doi:10.1007/978-3-662-64841-4_2

Ultra-weak chemiluminescence from the decomposition of peroxymonocarbonate

Hui Chen
, Syed Niaz Ali Shah
, Jin Ming Lin^*

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

1 Scopus citations

Abstract

In this chapter, we will discuss the preparation methods for peroxymonocarbonate ions (HCO4-). The reaction of bicarbonate with different peroxides especially with hydrogen peroxide to form HCO4- at different pH solutions will be studied. The data and results will be interpreted based on kinetic and spectroscopic evidence, that how HCO4- ions were produced. Furthermore, the ultra-weak chemiluminescence (CL) generated from the decomposition of HCO4- will be discussed in detail. We will also consider the enhancement of peroxymonocarbonate ions containing CL systems with different enhancers, i.e., fluorescent compounds, metallic complexes, nanoparticles, and other molecules added into the system. The role of the generation of different free radicals and the CL mechanism revealed based on the experimental results and literature proofs will be discussed.

Original language	English
Title of host publication	Ultra-Weak Chemiluminescence
Publisher	Springer Berlin Heidelberg
Pages	17-50
Number of pages	34
ISBN (Electronic)	9783662648414
ISBN (Print)	9783662648391
DOIs	https://doi.org/10.1007/978-3-662-64841-4_2
State	Published - 28 Feb 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
© Springer-Verlag GmbH Germany, part of Springer Nature 2022. All rights reserved.

Keywords

Bicarbonate
Hydrogen peroxide
Mechanism
Peroxymonocarbonate
Ultra-weak chemiluminescence

ASJC Scopus subject areas

General Chemistry
General Engineering

Access to Document

10.1007/978-3-662-64841-4_2

Cite this

@inbook{ce6823a6e1d14d0f9599969357176a0e,

title = "Ultra-weak chemiluminescence from the decomposition of peroxymonocarbonate",

abstract = "In this chapter, we will discuss the preparation methods for peroxymonocarbonate ions (HCO4-). The reaction of bicarbonate with different peroxides especially with hydrogen peroxide to form HCO4- at different pH solutions will be studied. The data and results will be interpreted based on kinetic and spectroscopic evidence, that how HCO4- ions were produced. Furthermore, the ultra-weak chemiluminescence (CL) generated from the decomposition of HCO4- will be discussed in detail. We will also consider the enhancement of peroxymonocarbonate ions containing CL systems with different enhancers, i.e., fluorescent compounds, metallic complexes, nanoparticles, and other molecules added into the system. The role of the generation of different free radicals and the CL mechanism revealed based on the experimental results and literature proofs will be discussed.",

keywords = "Bicarbonate, Hydrogen peroxide, Mechanism, Peroxymonocarbonate, Ultra-weak chemiluminescence",

author = "Hui Chen and Shah, \{Syed Niaz Ali\} and Lin, \{Jin Ming\}",

year = "2022",

month = feb,

day = "28",

doi = "10.1007/978-3-662-64841-4\_2",

language = "English",

isbn = "9783662648391",

pages = "17--50",

booktitle = "Ultra-Weak Chemiluminescence",

publisher = "Springer Berlin Heidelberg",

}

TY - CHAP

T1 - Ultra-weak chemiluminescence from the decomposition of peroxymonocarbonate

AU - Chen, Hui

AU - Shah, Syed Niaz Ali

AU - Lin, Jin Ming

PY - 2022/2/28

Y1 - 2022/2/28

N2 - In this chapter, we will discuss the preparation methods for peroxymonocarbonate ions (HCO4-). The reaction of bicarbonate with different peroxides especially with hydrogen peroxide to form HCO4- at different pH solutions will be studied. The data and results will be interpreted based on kinetic and spectroscopic evidence, that how HCO4- ions were produced. Furthermore, the ultra-weak chemiluminescence (CL) generated from the decomposition of HCO4- will be discussed in detail. We will also consider the enhancement of peroxymonocarbonate ions containing CL systems with different enhancers, i.e., fluorescent compounds, metallic complexes, nanoparticles, and other molecules added into the system. The role of the generation of different free radicals and the CL mechanism revealed based on the experimental results and literature proofs will be discussed.

AB - In this chapter, we will discuss the preparation methods for peroxymonocarbonate ions (HCO4-). The reaction of bicarbonate with different peroxides especially with hydrogen peroxide to form HCO4- at different pH solutions will be studied. The data and results will be interpreted based on kinetic and spectroscopic evidence, that how HCO4- ions were produced. Furthermore, the ultra-weak chemiluminescence (CL) generated from the decomposition of HCO4- will be discussed in detail. We will also consider the enhancement of peroxymonocarbonate ions containing CL systems with different enhancers, i.e., fluorescent compounds, metallic complexes, nanoparticles, and other molecules added into the system. The role of the generation of different free radicals and the CL mechanism revealed based on the experimental results and literature proofs will be discussed.

KW - Bicarbonate

KW - Hydrogen peroxide

KW - Mechanism

KW - Peroxymonocarbonate

KW - Ultra-weak chemiluminescence

UR - https://www.scopus.com/pages/publications/85153720636

U2 - 10.1007/978-3-662-64841-4_2

DO - 10.1007/978-3-662-64841-4_2

M3 - Chapter

AN - SCOPUS:85153720636

SN - 9783662648391

SP - 17

EP - 50

BT - Ultra-Weak Chemiluminescence

PB - Springer Berlin Heidelberg

ER -

Ultra-weak chemiluminescence from the decomposition of peroxymonocarbonate

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this