Toluene side chain alkylation with methanol over silica catalyst

M. A.H. Aziz; A. A. Jalil; A. F.A. Rahman; N. A.A. Fatah; S. M. Izan; I. Hussain; H. U. Hambali

doi:10.1088/1757-899X/808/1/012004

Toluene side chain alkylation with methanol over silica catalyst

M. A.H. Aziz, A. A. Jalil^*, A. F.A. Rahman, N. A.A. Fatah, S. M. Izan, I. Hussain, H. U. Hambali

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

2 Scopus citations

Abstract

MSN and SiO₂ catalyst were investigated on side chain toluene alkylation with methanol reaction. Characterization of the catalyst were carried out by XRD, N₂ physisorption analysis, FTIR spectroscopy. A pyrrole adsorption FTIR study reveals shifting of perturbed NH stretching increasing slightly in MSN compared to SiO₂ catalyst revealed that MSN possessed higher basic sites than SiO₂. N₂ adsorption desorption isotherm analysis showed that MSN possessed higher surface area than SiO₂ as well as increased the amount of mesopores in catalyst. The catalytic side chain toluene alkylation with methanol reaction was conducted in the range of 523K-673K under atmospheric pressure. MSN exhibits the highest catalytic performance compared to SiO₂ catalyst.

Original language	English
Article number	012004
Journal	IOP Conference Series: Materials Science and Engineering
Volume	808
Issue number	1
DOIs	https://doi.org/10.1088/1757-899X/808/1/012004
State	Published - 31 Mar 2020
Externally published	Yes
Event	8th Conference on Emerging Energy and Process Technology 2019, CONCEPT 2019 - Kuala Lumpur, Malaysia Duration: 27 Nov 2019 → 28 Nov 2019

Bibliographical note

Publisher Copyright:
© Published under licence by IOP Publishing Ltd.

ASJC Scopus subject areas

General Materials Science
General Engineering

Access to Document

10.1088/1757-899X/808/1/012004

Cite this

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title = "Toluene side chain alkylation with methanol over silica catalyst",

abstract = "MSN and SiO2 catalyst were investigated on side chain toluene alkylation with methanol reaction. Characterization of the catalyst were carried out by XRD, N2 physisorption analysis, FTIR spectroscopy. A pyrrole adsorption FTIR study reveals shifting of perturbed NH stretching increasing slightly in MSN compared to SiO2 catalyst revealed that MSN possessed higher basic sites than SiO2. N2 adsorption desorption isotherm analysis showed that MSN possessed higher surface area than SiO2 as well as increased the amount of mesopores in catalyst. The catalytic side chain toluene alkylation with methanol reaction was conducted in the range of 523K-673K under atmospheric pressure. MSN exhibits the highest catalytic performance compared to SiO2 catalyst.",

author = "Aziz, \{M. A.H.\} and Jalil, \{A. A.\} and Rahman, \{A. F.A.\} and Fatah, \{N. A.A.\} and Izan, \{S. M.\} and I. Hussain and Hambali, \{H. U.\}",

note = "Publisher Copyright: {\textcopyright} Published under licence by IOP Publishing Ltd.; 8th Conference on Emerging Energy and Process Technology 2019, CONCEPT 2019 ; Conference date: 27-11-2019 Through 28-11-2019",

year = "2020",

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day = "31",

doi = "10.1088/1757-899X/808/1/012004",

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journal = "IOP Conference Series: Materials Science and Engineering",

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T1 - Toluene side chain alkylation with methanol over silica catalyst

AU - Aziz, M. A.H.

AU - Jalil, A. A.

AU - Rahman, A. F.A.

AU - Fatah, N. A.A.

AU - Izan, S. M.

AU - Hussain, I.

AU - Hambali, H. U.

PY - 2020/3/31

Y1 - 2020/3/31

N2 - MSN and SiO2 catalyst were investigated on side chain toluene alkylation with methanol reaction. Characterization of the catalyst were carried out by XRD, N2 physisorption analysis, FTIR spectroscopy. A pyrrole adsorption FTIR study reveals shifting of perturbed NH stretching increasing slightly in MSN compared to SiO2 catalyst revealed that MSN possessed higher basic sites than SiO2. N2 adsorption desorption isotherm analysis showed that MSN possessed higher surface area than SiO2 as well as increased the amount of mesopores in catalyst. The catalytic side chain toluene alkylation with methanol reaction was conducted in the range of 523K-673K under atmospheric pressure. MSN exhibits the highest catalytic performance compared to SiO2 catalyst.

AB - MSN and SiO2 catalyst were investigated on side chain toluene alkylation with methanol reaction. Characterization of the catalyst were carried out by XRD, N2 physisorption analysis, FTIR spectroscopy. A pyrrole adsorption FTIR study reveals shifting of perturbed NH stretching increasing slightly in MSN compared to SiO2 catalyst revealed that MSN possessed higher basic sites than SiO2. N2 adsorption desorption isotherm analysis showed that MSN possessed higher surface area than SiO2 as well as increased the amount of mesopores in catalyst. The catalytic side chain toluene alkylation with methanol reaction was conducted in the range of 523K-673K under atmospheric pressure. MSN exhibits the highest catalytic performance compared to SiO2 catalyst.

UR - https://www.scopus.com/pages/publications/85083043539

U2 - 10.1088/1757-899X/808/1/012004

DO - 10.1088/1757-899X/808/1/012004

M3 - Conference article

AN - SCOPUS:85083043539

SN - 1757-8981

VL - 808

JO - IOP Conference Series: Materials Science and Engineering

JF - IOP Conference Series: Materials Science and Engineering

IS - 1

M1 - 012004

T2 - 8th Conference on Emerging Energy and Process Technology 2019, CONCEPT 2019

Y2 - 27 November 2019 through 28 November 2019

ER -

Toluene side chain alkylation with methanol over silica catalyst

Abstract

Bibliographical note

ASJC Scopus subject areas

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