Tobacco extracted from the discarded cigarettes as an inhibitor of copper and zinc corrosion in an ASTM standard D1141-98(2013) artificial seawater solution

Ambrish Singh; Xia Dayu; Ekemini Ituen; Kashif Ansari; M. A. Quraishi; Savas Kaya; Yuanhua Lin

doi:10.1016/j.jmrt.2020.03.033

Tobacco extracted from the discarded cigarettes as an inhibitor of copper and zinc corrosion in an ASTM standard D1141-98(2013) artificial seawater solution

Ambrish Singh^*, Xia Dayu, Ekemini Ituen, Kashif Ansari, M. A. Quraishi, Savas Kaya, Yuanhua Lin

^*Corresponding author for this work

Interdisciplinary Research Center for Advanced Materials

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The ability of tobacco extracted from discarded cigarettes (NDC) to mitigate the corrosion of copper and zinc in artificial seawater was investigated using electrochemical, weight loss, and surface characterization methods. The PDP results revealed that NDC acts as a mixed type inhibitor with cathodic predominance. EIS measurements suggest that the increase in charge transfer resistance with increasing NDC concentration with maximum inhibition efficiency of 96.8% (copper) and 98.2% (zinc). Langmuir adsorption isotherm was found to be the best fit. ΔG_ads reveals the mixed nature of adsorption. EFMT suggest the lower current density in presence of NDC. SECM, SEM and AFM analysis reveals the NDC film formation. UV-vis spectroscopy suggest the inhibitor/metal complex formation.

Original language	English
Pages (from-to)	5161-5173
Number of pages	13
Journal	Journal of Materials Research and Technology
Volume	9
Issue number	3
DOIs	https://doi.org/10.1016/j.jmrt.2020.03.033
State	Published - 2020

Bibliographical note

Publisher Copyright:
© 2020 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Keywords

Copper
Corrosion
EFMT
Seawater
Zinc

ASJC Scopus subject areas

Ceramics and Composites
Biomaterials
Surfaces, Coatings and Films
Metals and Alloys

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10.1016/j.jmrt.2020.03.033

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title = "Tobacco extracted from the discarded cigarettes as an inhibitor of copper and zinc corrosion in an ASTM standard D1141-98(2013) artificial seawater solution",

abstract = "The ability of tobacco extracted from discarded cigarettes (NDC) to mitigate the corrosion of copper and zinc in artificial seawater was investigated using electrochemical, weight loss, and surface characterization methods. The PDP results revealed that NDC acts as a mixed type inhibitor with cathodic predominance. EIS measurements suggest that the increase in charge transfer resistance with increasing NDC concentration with maximum inhibition efficiency of 96.8% (copper) and 98.2% (zinc). Langmuir adsorption isotherm was found to be the best fit. ΔGads reveals the mixed nature of adsorption. EFMT suggest the lower current density in presence of NDC. SECM, SEM and AFM analysis reveals the NDC film formation. UV-vis spectroscopy suggest the inhibitor/metal complex formation.",

keywords = "Copper, Corrosion, EFMT, Seawater, Zinc",

author = "Ambrish Singh and Xia Dayu and Ekemini Ituen and Kashif Ansari and Quraishi, {M. A.} and Savas Kaya and Yuanhua Lin",

note = "Publisher Copyright: {\textcopyright} 2020 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).",

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doi = "10.1016/j.jmrt.2020.03.033",

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T1 - Tobacco extracted from the discarded cigarettes as an inhibitor of copper and zinc corrosion in an ASTM standard D1141-98(2013) artificial seawater solution

AU - Singh, Ambrish

AU - Dayu, Xia

AU - Ituen, Ekemini

AU - Ansari, Kashif

AU - Quraishi, M. A.

AU - Kaya, Savas

AU - Lin, Yuanhua

PY - 2020

Y1 - 2020

N2 - The ability of tobacco extracted from discarded cigarettes (NDC) to mitigate the corrosion of copper and zinc in artificial seawater was investigated using electrochemical, weight loss, and surface characterization methods. The PDP results revealed that NDC acts as a mixed type inhibitor with cathodic predominance. EIS measurements suggest that the increase in charge transfer resistance with increasing NDC concentration with maximum inhibition efficiency of 96.8% (copper) and 98.2% (zinc). Langmuir adsorption isotherm was found to be the best fit. ΔGads reveals the mixed nature of adsorption. EFMT suggest the lower current density in presence of NDC. SECM, SEM and AFM analysis reveals the NDC film formation. UV-vis spectroscopy suggest the inhibitor/metal complex formation.

AB - The ability of tobacco extracted from discarded cigarettes (NDC) to mitigate the corrosion of copper and zinc in artificial seawater was investigated using electrochemical, weight loss, and surface characterization methods. The PDP results revealed that NDC acts as a mixed type inhibitor with cathodic predominance. EIS measurements suggest that the increase in charge transfer resistance with increasing NDC concentration with maximum inhibition efficiency of 96.8% (copper) and 98.2% (zinc). Langmuir adsorption isotherm was found to be the best fit. ΔGads reveals the mixed nature of adsorption. EFMT suggest the lower current density in presence of NDC. SECM, SEM and AFM analysis reveals the NDC film formation. UV-vis spectroscopy suggest the inhibitor/metal complex formation.

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KW - Corrosion

KW - EFMT

KW - Seawater

KW - Zinc

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Tobacco extracted from the discarded cigarettes as an inhibitor of copper and zinc corrosion in an ASTM standard D1141-98(2013) artificial seawater solution

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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