Abstract
Controlling the electron transfer process at donor-acceptor interfaces is a research direction that has not yet seen much progress. Here, with careful control of the charge localization on the porphyrin macrocycle using β-cyclodextrin as an external cage, we are able to improve the electron injection efficiency from cationic porphyrin to graphene carboxylate by 120%. The detailed reaction mechanism is also discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 14513-14517 |
| Number of pages | 5 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 17 |
| Issue number | 22 |
| DOIs | |
| State | Published - 14 Jun 2015 |
| Externally published | Yes |
Bibliographical note
Publisher Copyright:© the Owner Societies 2015.
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry
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