TLC-FID calibration and accurate weight determination of SARA fractions in heavy crude oil

  • S. A. Khan*
  • , S. Sarfraz
  • , D. Price
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

The authors specifically aimed to separate and characterize clean saturates, aromatics, resins, and asphaltenes (SARA) fractions and develop standards for accurate quantification purposes. A standard method ASTM D4124-86 was employed for the SARA separation of an Athabasca crude oil. These four recovered fractions were analyzed by using an Iatroscan thin-layer chromatograph with flame ionization detection (TLC-FID). The Iatroscan responseto the complete burnoff of known sample weights of each fraction deposited on chromarods via known volumes of standard solutions was determined and area count versus sample weight calibration graphs subsequently obtained. From the established weight versus peak area calibration curves for each pure separated SARA fraction their accurate quantitative percentage in an Athabasca heavy crude oil was determined.

Original languageEnglish
Pages (from-to)2401-2406
Number of pages6
JournalPetroleum Science and Technology
Volume30
Issue number23
DOIs
StatePublished - 2012

Bibliographical note

Funding Information:
The support by King Fahd University of Petroleum and Minerals and Center of Excellence in Nanotechnology is gratefully acknowledged for financial support and facilities to publish this work.

Keywords

  • Athabasca
  • Bitumen
  • Crude oil
  • Iatroscan
  • SARA fractions
  • TLC-FID

ASJC Scopus subject areas

  • General Chemistry
  • General Chemical Engineering
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Geotechnical Engineering and Engineering Geology

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