Through-Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: AgII⋅⋅⋅AgII, AgII⋅⋅⋅AgIII, and AgIII⋅⋅⋅AgIII Metallophilic Interactions

Akhil Kumar Singh; Mohammad Usman; Giuseppe Sciortino; Eugenio Garribba; Sankar Prasad Rath

doi:10.1002/chem.201902705

Through-Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: Ag^II⋅⋅⋅Ag^II, Ag^II⋅⋅⋅Ag^III, and Ag^III⋅⋅⋅Ag^III Metallophilic Interactions

Akhil Kumar Singh
, Mohammad Usman
, Giuseppe Sciortino
, Eugenio Garribba
, Sankar Prasad Rath^*

^*Corresponding author for this work

Research output: Contribution to journal › Comment/debate

Abstract

Invited for the cover of this issue are Sankar Prasad Rath and co-workers at the Indian Institute of Technology (IIT Kanpur) and the University of Sassari. The image depicts through space interactions in a cofacial Ag^II porphyrin dimer upon stepwise oxidations, which allow the estimation of the structure and energy characteristics of metallophilic interactions between Ag^II/Ag^II (d⁹/d⁹), Ag^III/Ag^III (d⁸/d⁸) and also mixed-valent Ag^II/Ag^III (d⁹/d⁸) complexes. Read the full text of the article at 10.1002/chem.201901731.

Original language	English
Pages (from-to)	10025
Number of pages	1
Journal	Chemistry - A European Journal
Volume	25
Issue number	43
DOIs	https://doi.org/10.1002/chem.201902705
State	Published - Aug 2019
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1002/chem.201902705

Cite this

@article{e72f6ffa0d3545b8adb097f37999d462,

title = "Through-Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: AgII⋅⋅⋅AgII, AgII⋅⋅⋅AgIII, and AgIII⋅⋅⋅AgIII Metallophilic Interactions",

abstract = "Invited for the cover of this issue are Sankar Prasad Rath and co-workers at the Indian Institute of Technology (IIT Kanpur) and the University of Sassari. The image depicts through space interactions in a cofacial AgII porphyrin dimer upon stepwise oxidations, which allow the estimation of the structure and energy characteristics of metallophilic interactions between AgII/AgII (d9/d9), AgIII/AgIII (d8/d8) and also mixed-valent AgII/AgIII (d9/d8) complexes. Read the full text of the article at 10.1002/chem.201901731.",

author = "Singh, \{Akhil Kumar\} and Mohammad Usman and Giuseppe Sciortino and Eugenio Garribba and Rath, \{Sankar Prasad\}",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

month = aug,

doi = "10.1002/chem.201902705",

language = "English",

volume = "25",

pages = "10025",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "John Wiley and Sons Inc.",

number = "43",

}

Through-Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations: Ag^II⋅⋅⋅Ag^II, Ag^II⋅⋅⋅Ag^III, and Ag^III⋅⋅⋅Ag^III Metallophilic Interactions. / Singh, Akhil Kumar; Usman, Mohammad; Sciortino, Giuseppe et al.
In: Chemistry - A European Journal, Vol. 25, No. 43, 08.2019, p. 10025.

Research output: Contribution to journal › Comment/debate

TY - JOUR

T1 - Through-Space Spin Coupling in a Silver(II) Porphyrin Dimer upon Stepwise Oxidations

T2 - AgII⋅⋅⋅AgII, AgII⋅⋅⋅AgIII, and AgIII⋅⋅⋅AgIII Metallophilic Interactions

AU - Singh, Akhil Kumar

AU - Usman, Mohammad

AU - Sciortino, Giuseppe

AU - Garribba, Eugenio

AU - Rath, Sankar Prasad

PY - 2019/8

Y1 - 2019/8

N2 - Invited for the cover of this issue are Sankar Prasad Rath and co-workers at the Indian Institute of Technology (IIT Kanpur) and the University of Sassari. The image depicts through space interactions in a cofacial AgII porphyrin dimer upon stepwise oxidations, which allow the estimation of the structure and energy characteristics of metallophilic interactions between AgII/AgII (d9/d9), AgIII/AgIII (d8/d8) and also mixed-valent AgII/AgIII (d9/d8) complexes. Read the full text of the article at 10.1002/chem.201901731.

AB - Invited for the cover of this issue are Sankar Prasad Rath and co-workers at the Indian Institute of Technology (IIT Kanpur) and the University of Sassari. The image depicts through space interactions in a cofacial AgII porphyrin dimer upon stepwise oxidations, which allow the estimation of the structure and energy characteristics of metallophilic interactions between AgII/AgII (d9/d9), AgIII/AgIII (d8/d8) and also mixed-valent AgII/AgIII (d9/d8) complexes. Read the full text of the article at 10.1002/chem.201901731.

UR - https://www.scopus.com/pages/publications/85069806964

U2 - 10.1002/chem.201902705

DO - 10.1002/chem.201902705

M3 - Comment/debate

AN - SCOPUS:85069806964

SN - 0947-6539

VL - 25

SP - 10025

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 43

ER -