Thermodynamic properties of molecules interacting with inverse power potentials

  • Esam Hamad*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

The thermodynamic properties of soft-sphere molecules are analyzed using differential equations. The analysis is extended to multi-term inverse-power potentials by introducing an approximation which isexact for soft spheres. The approximation is tested using the Lennard-Jones equation of state which is found most accurate at high densities. The analysis suggests a simple non-perturbation method of combiningthe contributions from different inverse-power terms to obtain the thermodynamic properties for molecules interacting with multi-term potentials.

Original languageEnglish
Pages (from-to)183-191
Number of pages9
JournalZeitschrift fur Physikalische Chemie
Volume190
Issue numberPart_2
DOIs
StatePublished - 1995

Keywords

  • Inverse power terms
  • Lennard-Jones equation of state
  • Multi-term potentials
  • Soft-sphere molecules

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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