Abstract
The thermodynamic properties of soft-sphere molecules are analyzed using differential equations. The analysis is extended to multi-term inverse-power potentials by introducing an approximation which isexact for soft spheres. The approximation is tested using the Lennard-Jones equation of state which is found most accurate at high densities. The analysis suggests a simple non-perturbation method of combiningthe contributions from different inverse-power terms to obtain the thermodynamic properties for molecules interacting with multi-term potentials.
| Original language | English |
|---|---|
| Pages (from-to) | 183-191 |
| Number of pages | 9 |
| Journal | Zeitschrift fur Physikalische Chemie |
| Volume | 190 |
| Issue number | Part_2 |
| DOIs | |
| State | Published - 1995 |
Keywords
- Inverse power terms
- Lennard-Jones equation of state
- Multi-term potentials
- Soft-sphere molecules
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
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