Abstract
The coupled-environment fracture model (CEFM) for intergranular stress corrosion cracking (IGSCC) of sensitized type 304 (UNS S30400) stainless steel (SS) in light-water reactor (LWR) heat-transport circuits was extended by incorporating steel corrosion, hydrogen (H2) oxidation, and hydrogen peroxide (H2O2 reduction In addition to oxygen (O2) reduction as charge-transfer reactions occurring on the external surfaces. A theoretical fracture mechanics approach was incorporated to estimate the crack-tip strain rate, and a void nucleation model was included to account for ductile failure at very negative potentials. In the CEFM, coupling between the Internal and external environments and the need to conserve charge are the key physical and mathematical constraints that determine the rate of crack advance. The model provides rational explanations for the effects of O2, H2O2, H2, conductivity, stress intensity, and flow velocity on the crack growth rate (CGR) In sensitized type 304 SS In simulated LWR Invessel environments. The CEFM was proposed as the basis of a deterministic method for estimating component lifetimes in LWR heat-transport circuits.
| Original language | English |
|---|---|
| Pages (from-to) | 768-785 |
| Number of pages | 18 |
| Journal | Material und Organismen |
| Volume | 52 |
| Issue number | 10 |
| State | Published - 1996 |
Keywords
- Boiling-water reactors
- Coupled-environment fracture model
- High-temperature water
- Hydrogen peroxide
- Irradiation-assisted stress corrosion cracking
- Nuclear reactors
- Queous solutions
- Stress corrosion cracking
- Type 304 stainless steel
ASJC Scopus subject areas
- General Agricultural and Biological Sciences
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