The Use of Graphite to Improve the Stability of Saudi Class G Oil-Well Cement against the Carbonation Process

Oil-well cement physical characteristics considerably change after being carbonated by a CO₂-rich solution. In this study, the influence of graphite particles in the characteristics of oil-well cement reacted with a CO₂-rich solution at 130 °C and 10 MPa for 10 days was studied. After 10 days of carbonation, incorporating 0.2% by weight of cement (BWOC) of graphite into the cement slurry decreased the carbonation depth by 29.8% as confirmed by the direct measurement and the micro-computerized tomography scan technique. The addition of 0.2% BWOC of graphite also reduced the cement matrix permeability by 31.4% and increased its compressive strength by 16.4% and tensile strength by 23.8% compared to the sample without graphite. The decrease in the cement matrix portlandite concentration and permeability of the samples prepared with graphite contributed to promote the cement matrix carbonation resistance. The microscopic images also proved that the incorporation of graphite delayed the leaching of calcium carbonate, and this is also attributed to decreasing the cement strength deterioration.