The structure of (1,2:5, 6η-cyclononatetraene) (η-cyclopentadienyl)cobalt, CoC14H15

Mazhar-Ul-Haque; Jamil Ahmed; William Horne

doi:10.1007/BF01160737

The structure of (1,2:5, 6η-cyclononatetraene) (η-cyclopentadienyl)cobalt, CoC₁₄H₁₅

Mazhar-Ul-Haque^*, Jamil Ahmed, William Horne

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound crystallizes in the monoclinic space group P2₁/a, a=11.50(2), b=7.724(1), c=12.599(3) Å, β=102.22(5)°, Z=4. The structure was solved by direct methods and refined by full-matrix least squares to R=0.049 for 1032 observed reflections. The cobalt atom is π-bonded to the cyclopentadienyl ring, with a mean Co-C distance of 2.07(1) Å, and also π-bonded to the cyclonoatetraene ring at C(2)-C(3) and at C(6)-C(7), with a mean Co-C distance of 2.00(1) Å.

Original language	English
Pages (from-to)	729-737
Number of pages	9
Journal	Journal of Crystallographic and Spectroscopic Research
Volume	17
Issue number	6
DOIs	https://doi.org/10.1007/BF01160737
State	Published - Dec 1987

ASJC Scopus subject areas

Structural Biology
Condensed Matter Physics
Spectroscopy

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10.1007/BF01160737

Cite this

@article{1d2f18d545b241d890a3f45986b4af5f,

title = "The structure of (1,2:5, 6η-cyclononatetraene) (η-cyclopentadienyl)cobalt, CoC14H15",

abstract = "The title compound crystallizes in the monoclinic space group P21/a, a=11.50(2), b=7.724(1), c=12.599(3) {\AA}, β=102.22(5)°, Z=4. The structure was solved by direct methods and refined by full-matrix least squares to R=0.049 for 1032 observed reflections. The cobalt atom is π-bonded to the cyclopentadienyl ring, with a mean Co-C distance of 2.07(1) {\AA}, and also π-bonded to the cyclonoatetraene ring at C(2)-C(3) and at C(6)-C(7), with a mean Co-C distance of 2.00(1) {\AA}.",

author = "Mazhar-Ul-Haque and Jamil Ahmed and William Horne",

year = "1987",

month = dec,

doi = "10.1007/BF01160737",

language = "English",

volume = "17",

pages = "729--737",

journal = "Journal of Crystallographic and Spectroscopic Research",

issn = "0277-8068",

number = "6",

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TY - JOUR

T1 - The structure of (1,2:5, 6η-cyclononatetraene) (η-cyclopentadienyl)cobalt, CoC14H15

AU - Mazhar-Ul-Haque,

AU - Ahmed, Jamil

AU - Horne, William

PY - 1987/12

Y1 - 1987/12

N2 - The title compound crystallizes in the monoclinic space group P21/a, a=11.50(2), b=7.724(1), c=12.599(3) Å, β=102.22(5)°, Z=4. The structure was solved by direct methods and refined by full-matrix least squares to R=0.049 for 1032 observed reflections. The cobalt atom is π-bonded to the cyclopentadienyl ring, with a mean Co-C distance of 2.07(1) Å, and also π-bonded to the cyclonoatetraene ring at C(2)-C(3) and at C(6)-C(7), with a mean Co-C distance of 2.00(1) Å.

AB - The title compound crystallizes in the monoclinic space group P21/a, a=11.50(2), b=7.724(1), c=12.599(3) Å, β=102.22(5)°, Z=4. The structure was solved by direct methods and refined by full-matrix least squares to R=0.049 for 1032 observed reflections. The cobalt atom is π-bonded to the cyclopentadienyl ring, with a mean Co-C distance of 2.07(1) Å, and also π-bonded to the cyclonoatetraene ring at C(2)-C(3) and at C(6)-C(7), with a mean Co-C distance of 2.00(1) Å.

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U2 - 10.1007/BF01160737

DO - 10.1007/BF01160737

M3 - Article

AN - SCOPUS:34250099483

SN - 0277-8068

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JO - Journal of Crystallographic and Spectroscopic Research

JF - Journal of Crystallographic and Spectroscopic Research

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