The role of alcohols and diols as co-solvents in fabrication of TON zeolite

Anas Karrar Jamil; Oki Muraza; Adnan M. Al-Amer

doi:10.1016/j.jiec.2015.03.023

The role of alcohols and diols as co-solvents in fabrication of TON zeolite

Anas Karrar Jamil, Oki Muraza^*, Adnan M. Al-Amer

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Numerous industrial catalysts and sorbents require better control of crystal size and morphology of the zeolites. Here, we report a method to selectively control the crystal size and morphology of ZSM-22 by using alcohols and diols as co-solvents in water-alcohol system. The results demonstrated the role of co-solvent in controlling the crystallization growth of ZSM-22 zeolite. Addition of co-solvent suppressed nucleation of unwanted cristobalite phase in crystallization and growth of ZSM-22 zeolite. We found that alcohols and diols as cheap co-solvent are effective in tuning and controlling crystal size, aspect ratio and co-crystalization phases of zeolite ZSM-22.

Original language	English
Pages (from-to)	112-119
Number of pages	8
Journal	Journal of Industrial and Engineering Chemistry
Volume	29
DOIs	https://doi.org/10.1016/j.jiec.2015.03.023
State	Published - 25 Sep 2015

Bibliographical note

Publisher Copyright:
© 2015 The Korean Society of Industrial and Engineering Chemistry.

Keywords

Co-solvent
Crystal growth modifier
One-dimensional zeolites
Size and morphology
ZSM-22

ASJC Scopus subject areas

General Chemical Engineering

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10.1016/j.jiec.2015.03.023

Cite this

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title = "The role of alcohols and diols as co-solvents in fabrication of TON zeolite",

abstract = "Numerous industrial catalysts and sorbents require better control of crystal size and morphology of the zeolites. Here, we report a method to selectively control the crystal size and morphology of ZSM-22 by using alcohols and diols as co-solvents in water-alcohol system. The results demonstrated the role of co-solvent in controlling the crystallization growth of ZSM-22 zeolite. Addition of co-solvent suppressed nucleation of unwanted cristobalite phase in crystallization and growth of ZSM-22 zeolite. We found that alcohols and diols as cheap co-solvent are effective in tuning and controlling crystal size, aspect ratio and co-crystalization phases of zeolite ZSM-22.",

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author = "Jamil, \{Anas Karrar\} and Oki Muraza and Al-Amer, \{Adnan M.\}",

note = "Publisher Copyright: {\textcopyright} 2015 The Korean Society of Industrial and Engineering Chemistry.",

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doi = "10.1016/j.jiec.2015.03.023",

language = "English",

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journal = "Journal of Industrial and Engineering Chemistry",

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T1 - The role of alcohols and diols as co-solvents in fabrication of TON zeolite

AU - Jamil, Anas Karrar

AU - Muraza, Oki

AU - Al-Amer, Adnan M.

PY - 2015/9/25

Y1 - 2015/9/25

N2 - Numerous industrial catalysts and sorbents require better control of crystal size and morphology of the zeolites. Here, we report a method to selectively control the crystal size and morphology of ZSM-22 by using alcohols and diols as co-solvents in water-alcohol system. The results demonstrated the role of co-solvent in controlling the crystallization growth of ZSM-22 zeolite. Addition of co-solvent suppressed nucleation of unwanted cristobalite phase in crystallization and growth of ZSM-22 zeolite. We found that alcohols and diols as cheap co-solvent are effective in tuning and controlling crystal size, aspect ratio and co-crystalization phases of zeolite ZSM-22.

AB - Numerous industrial catalysts and sorbents require better control of crystal size and morphology of the zeolites. Here, we report a method to selectively control the crystal size and morphology of ZSM-22 by using alcohols and diols as co-solvents in water-alcohol system. The results demonstrated the role of co-solvent in controlling the crystallization growth of ZSM-22 zeolite. Addition of co-solvent suppressed nucleation of unwanted cristobalite phase in crystallization and growth of ZSM-22 zeolite. We found that alcohols and diols as cheap co-solvent are effective in tuning and controlling crystal size, aspect ratio and co-crystalization phases of zeolite ZSM-22.

KW - Co-solvent

KW - Crystal growth modifier

KW - One-dimensional zeolites

KW - Size and morphology

KW - ZSM-22

UR - https://www.scopus.com/pages/publications/84938749725

U2 - 10.1016/j.jiec.2015.03.023

DO - 10.1016/j.jiec.2015.03.023

M3 - Article

AN - SCOPUS:84938749725

SN - 1226-086X

VL - 29

SP - 112

EP - 119

JO - Journal of Industrial and Engineering Chemistry

JF - Journal of Industrial and Engineering Chemistry

ER -

The role of alcohols and diols as co-solvents in fabrication of TON zeolite

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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