The Influence of Electrolytes on the Mixed Micellization of Equimolar (Monomeric and Dimeric) Surfactants

Md Sayem Alam; A. Mohammed Siddiq; Asit Baran Mandal

doi:10.1134/S0036024418010028

The Influence of Electrolytes on the Mixed Micellization of Equimolar (Monomeric and Dimeric) Surfactants

Md Sayem Alam^*, A. Mohammed Siddiq, Asit Baran Mandal

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The influence of halide ions of (sodium salt) electrolytes on the mixed micellization of a cationic gemini (dimeric) surfactant, hexanediyl-1,6-bis(dimethylcetylammonium) bromide (16-6-16) and a cationic conventional (monomeric) surfactant, cetyltrimethylammonium bromide (CTAB) have been investigated. The critical micelle concentration (CMC) of the mixed (16-6-16+CTAB) surfactants was measured by the surface tension measurements. The surface properties: viz., the surfactant concentration required to reduce the surface tension by 20 mN/m (C₂₀), the surface pressure at the CMC (Π_CMC), the maximum surface excess concentration at the air/water interface (Γ_max), the minimum area per surfactant molecule at the air/water interface (A_min), etc. of the mixed micellar surfactant systems were evaluated. In the absence and presence of electrolytes, the thermodynamic parameters of the mixed micellar surfactant systems were also evaluated.

Original language	English
Pages (from-to)	185-190
Number of pages	6
Journal	Russian Journal of Physical Chemistry A
Volume	92
Issue number	1
DOIs	https://doi.org/10.1134/S0036024418010028
State	Published - 1 Jan 2018
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2018, Pleiades Publishing, Ltd.

Keywords

critical micelle concentration
gemini surfactant
halide ions
mixed micelles
thermodynamics

ASJC Scopus subject areas

Physical and Theoretical Chemistry

Access to Document

10.1134/S0036024418010028

Cite this

@article{42225fa1398d4ecbba81871ae5355b04,

title = "The Influence of Electrolytes on the Mixed Micellization of Equimolar (Monomeric and Dimeric) Surfactants",

abstract = "The influence of halide ions of (sodium salt) electrolytes on the mixed micellization of a cationic gemini (dimeric) surfactant, hexanediyl-1,6-bis(dimethylcetylammonium) bromide (16-6-16) and a cationic conventional (monomeric) surfactant, cetyltrimethylammonium bromide (CTAB) have been investigated. The critical micelle concentration (CMC) of the mixed (16-6-16+CTAB) surfactants was measured by the surface tension measurements. The surface properties: viz., the surfactant concentration required to reduce the surface tension by 20 mN/m (C20), the surface pressure at the CMC (ΠCMC), the maximum surface excess concentration at the air/water interface (Γmax), the minimum area per surfactant molecule at the air/water interface (Amin), etc. of the mixed micellar surfactant systems were evaluated. In the absence and presence of electrolytes, the thermodynamic parameters of the mixed micellar surfactant systems were also evaluated.",

keywords = "critical micelle concentration, gemini surfactant, halide ions, mixed micelles, thermodynamics",

author = "Alam, \{Md Sayem\} and Siddiq, \{A. Mohammed\} and Mandal, \{Asit Baran\}",

note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",

year = "2018",

month = jan,

day = "1",

doi = "10.1134/S0036024418010028",

language = "English",

volume = "92",

pages = "185--190",

journal = "Russian Journal of Physical Chemistry A",

issn = "0036-0244",

publisher = "Pleiades Publishing",

number = "1",

}

TY - JOUR

T1 - The Influence of Electrolytes on the Mixed Micellization of Equimolar (Monomeric and Dimeric) Surfactants

AU - Alam, Md Sayem

AU - Siddiq, A. Mohammed

AU - Mandal, Asit Baran

PY - 2018/1/1

Y1 - 2018/1/1

N2 - The influence of halide ions of (sodium salt) electrolytes on the mixed micellization of a cationic gemini (dimeric) surfactant, hexanediyl-1,6-bis(dimethylcetylammonium) bromide (16-6-16) and a cationic conventional (monomeric) surfactant, cetyltrimethylammonium bromide (CTAB) have been investigated. The critical micelle concentration (CMC) of the mixed (16-6-16+CTAB) surfactants was measured by the surface tension measurements. The surface properties: viz., the surfactant concentration required to reduce the surface tension by 20 mN/m (C20), the surface pressure at the CMC (ΠCMC), the maximum surface excess concentration at the air/water interface (Γmax), the minimum area per surfactant molecule at the air/water interface (Amin), etc. of the mixed micellar surfactant systems were evaluated. In the absence and presence of electrolytes, the thermodynamic parameters of the mixed micellar surfactant systems were also evaluated.

AB - The influence of halide ions of (sodium salt) electrolytes on the mixed micellization of a cationic gemini (dimeric) surfactant, hexanediyl-1,6-bis(dimethylcetylammonium) bromide (16-6-16) and a cationic conventional (monomeric) surfactant, cetyltrimethylammonium bromide (CTAB) have been investigated. The critical micelle concentration (CMC) of the mixed (16-6-16+CTAB) surfactants was measured by the surface tension measurements. The surface properties: viz., the surfactant concentration required to reduce the surface tension by 20 mN/m (C20), the surface pressure at the CMC (ΠCMC), the maximum surface excess concentration at the air/water interface (Γmax), the minimum area per surfactant molecule at the air/water interface (Amin), etc. of the mixed micellar surfactant systems were evaluated. In the absence and presence of electrolytes, the thermodynamic parameters of the mixed micellar surfactant systems were also evaluated.

KW - critical micelle concentration

KW - gemini surfactant

KW - halide ions

KW - mixed micelles

KW - thermodynamics

UR - https://www.scopus.com/pages/publications/85042636991

U2 - 10.1134/S0036024418010028

DO - 10.1134/S0036024418010028

M3 - Article

AN - SCOPUS:85042636991

SN - 0036-0244

VL - 92

SP - 185

EP - 190

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

IS - 1

ER -

The Influence of Electrolytes on the Mixed Micellization of Equimolar (Monomeric and Dimeric) Surfactants

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this