The effect of annealing on structural and optical properties of α-Fe 2 O 3 /CdS/α-Fe 2 O 3 multilayer heterostructures

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Abstract

Multilayered thin film heterostructures of α-Fe 2 O 3 /CdS/α-Fe 2 O 3 were prepared through physical vapor deposition. Each α-Fe 2 O 3 layer was deposited by e-beam evaporation of iron in an oxygen atmosphere. The CdS layer was deposited by thermal evaporation in a vacuum. The effect of post annealing of multilayered thin films in air in the temperature range 250°C to 450°C was investigated. Structural characterization indicated the growth of the α-Fe 2 O 3 phase with a polycrystalline structure without any CdS crystalline phase. As-deposited multilayer heterostructures were amorphous and transformed into polycrystalline upon annealing. The surface modification of the films during annealing was revealed by scanning electron microscopy. Spectrophotometric measurements were used to determine the optical properties, including the transmittance, absorbance, and band gap. All the films had both direct as well as indirect band gaps.

Original languageEnglish
Pages (from-to)653-657
Number of pages5
JournalApplied Surface Science
Volume320
DOIs
StatePublished - 30 Nov 2014

Bibliographical note

Publisher Copyright:
© 2014 Elsevier B.V. All rights reserved.

Keywords

  • Absorbance
  • Annealing
  • CdS/α-Fe O multilayers
  • Composite films

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

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