Tandem catalysis: A sustainable alternative for direct hydrogenation of CO2 to light olefins

Yahya Gambo; Sagir Adamu; Rahima A. Lucky; Mohammed S. Ba-Shammakh; Mohammad M. Hossain

doi:10.1016/j.apcata.2022.118658

Tandem catalysis: A sustainable alternative for direct hydrogenation of CO₂ to light olefins

Yahya Gambo, Sagir Adamu, Rahima A. Lucky, Mohammed S. Ba-Shammakh, Mohammad M. Hossain^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

32 Scopus citations

Abstract

The design and development of novel tandem catalysts to facilitate the production of value-added chemicals and fuels via heterogeneous routes holds great prospect in revolutionizing the chemical industry. Herein, we discuss the fundamentals of tandem catalysis and provided a comprehensive account of recent advances related to the design and tuning of tandem catalysts for direct CO₂ hydrogenation to light olefins. Moreover, insights on catalyst deactivation in tandem CO₂ hydrogenation has been provided. In addition, the prospects of core-shell configuration and its high flexibility in implementing efficient tandem catalyst design strategies has been discussed. Most importantly, the insights and perspectives provided therein are hoped to stimulate and guide in the future design of highly efficient tandem catalysts that could enable the commercialization of the process as a sustainable and environmentally benign alternative for olefin production.

Original language	English
Article number	118658
Journal	Applied Catalysis A: General
Volume	641
DOIs	https://doi.org/10.1016/j.apcata.2022.118658
State	Published - 5 Jul 2022

Bibliographical note

Publisher Copyright:
© 2022 Elsevier B.V.

Keywords

CO hydrogenation
Deactivation
Fe-based
Metal-organic framework
Olefins
Tandem catalysis

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.apcata.2022.118658

Cite this

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title = "Tandem catalysis: A sustainable alternative for direct hydrogenation of CO2 to light olefins",

abstract = "The design and development of novel tandem catalysts to facilitate the production of value-added chemicals and fuels via heterogeneous routes holds great prospect in revolutionizing the chemical industry. Herein, we discuss the fundamentals of tandem catalysis and provided a comprehensive account of recent advances related to the design and tuning of tandem catalysts for direct CO2 hydrogenation to light olefins. Moreover, insights on catalyst deactivation in tandem CO2 hydrogenation has been provided. In addition, the prospects of core-shell configuration and its high flexibility in implementing efficient tandem catalyst design strategies has been discussed. Most importantly, the insights and perspectives provided therein are hoped to stimulate and guide in the future design of highly efficient tandem catalysts that could enable the commercialization of the process as a sustainable and environmentally benign alternative for olefin production.",

keywords = "CO hydrogenation, Deactivation, Fe-based, Metal-organic framework, Olefins, Tandem catalysis",

author = "Yahya Gambo and Sagir Adamu and Lucky, {Rahima A.} and Ba-Shammakh, {Mohammed S.} and Hossain, {Mohammad M.}",

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AU - Gambo, Yahya

AU - Adamu, Sagir

AU - Lucky, Rahima A.

AU - Ba-Shammakh, Mohammed S.

AU - Hossain, Mohammad M.

PY - 2022/7/5

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AB - The design and development of novel tandem catalysts to facilitate the production of value-added chemicals and fuels via heterogeneous routes holds great prospect in revolutionizing the chemical industry. Herein, we discuss the fundamentals of tandem catalysis and provided a comprehensive account of recent advances related to the design and tuning of tandem catalysts for direct CO2 hydrogenation to light olefins. Moreover, insights on catalyst deactivation in tandem CO2 hydrogenation has been provided. In addition, the prospects of core-shell configuration and its high flexibility in implementing efficient tandem catalyst design strategies has been discussed. Most importantly, the insights and perspectives provided therein are hoped to stimulate and guide in the future design of highly efficient tandem catalysts that could enable the commercialization of the process as a sustainable and environmentally benign alternative for olefin production.

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KW - Fe-based

KW - Metal-organic framework

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