Synthesis, X-ray structure and 199Hg, 77Se CP MAS NMR studies on the first tris(imidazolidine-2-selone) mercury complex: {Chloro-tris[N-methyl-2(3H)-imidazolidine-2- selone]mercury(II)}chloride

Abdul Hadi D. Al-Amri; Mohammed Fettouhi; Mohamed I.M. Wazeer; Anvarhusein A. Isab

doi:10.1016/j.inoche.2005.09.010

Synthesis, X-ray structure and ¹⁹⁹Hg, ⁷⁷Se CP MAS NMR studies on the first tris(imidazolidine-2-selone) mercury complex: {Chloro-tris[N-methyl-2(3H)-imidazolidine-2- selone]mercury(II)}chloride

Abdul Hadi D. Al-Amri, Mohammed Fettouhi^*, Mohamed I.M. Wazeer, Anvarhusein A. Isab

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A novel cationic Hg(II) complex has been synthesized with N-methyl-imidazolidine-2-selone ligand. The tris(N-Methyl-imidazolidine-2- selone) mercury(II) complex, [(MeImSe)₃HgCl]⁺Cl ^- (1), has been characterized by single crystal X-ray analysis and CP MAS ¹⁹⁹Hg and ⁷⁷Se NMR.

Original language	English
Pages (from-to)	1109-1112
Number of pages	4
Journal	Inorganic Chemistry Communication
Volume	8
Issue number	12
DOIs	https://doi.org/10.1016/j.inoche.2005.09.010
State	Published - Dec 2005

Bibliographical note

Funding Information:
We gratefully acknowledge King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia for the financial support through research project No. CY/NMR STUDY/277.

Keywords

CP MAS Hg NMR
Crystal structure
Hg(II) complex
N-methyl-imidazolidine-2-selone
Se NMR

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.inoche.2005.09.010

Cite this

@article{8cdd2642754447baa56bdbd44f389768,

title = "Synthesis, X-ray structure and 199Hg, 77Se CP MAS NMR studies on the first tris(imidazolidine-2-selone) mercury complex: {Chloro-tris[N-methyl-2(3H)-imidazolidine-2- selone]mercury(II)}chloride",

abstract = "A novel cationic Hg(II) complex has been synthesized with N-methyl-imidazolidine-2-selone ligand. The tris(N-Methyl-imidazolidine-2- selone) mercury(II) complex, [(MeImSe)3HgCl]+Cl - (1), has been characterized by single crystal X-ray analysis and CP MAS 199Hg and 77Se NMR.",

keywords = "CP MAS Hg NMR, Crystal structure, Hg(II) complex, N-methyl-imidazolidine-2-selone, Se NMR",

author = "Al-Amri, {Abdul Hadi D.} and Mohammed Fettouhi and Wazeer, {Mohamed I.M.} and Isab, {Anvarhusein A.}",

note = "Funding Information: We gratefully acknowledge King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia for the financial support through research project No. CY/NMR STUDY/277. ",

year = "2005",

month = dec,

doi = "10.1016/j.inoche.2005.09.010",

language = "English",

volume = "8",

pages = "1109--1112",

journal = "Inorganic Chemistry Communication",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "12",

}

Synthesis, X-ray structure and ¹⁹⁹Hg, ⁷⁷Se CP MAS NMR studies on the first tris(imidazolidine-2-selone) mercury complex: {Chloro-tris[N-methyl-2(3H)-imidazolidine-2- selone]mercury(II)}chloride. / Al-Amri, Abdul Hadi D.; Fettouhi, Mohammed; Wazeer, Mohamed I.M. et al.
In: Inorganic Chemistry Communication, Vol. 8, No. 12, 12.2005, p. 1109-1112.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, X-ray structure and 199Hg, 77Se CP MAS NMR studies on the first tris(imidazolidine-2-selone) mercury complex

T2 - {Chloro-tris[N-methyl-2(3H)-imidazolidine-2- selone]mercury(II)}chloride

AU - Al-Amri, Abdul Hadi D.

AU - Fettouhi, Mohammed

AU - Wazeer, Mohamed I.M.

AU - Isab, Anvarhusein A.

N1 - Funding Information: We gratefully acknowledge King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia for the financial support through research project No. CY/NMR STUDY/277.

PY - 2005/12

Y1 - 2005/12

N2 - A novel cationic Hg(II) complex has been synthesized with N-methyl-imidazolidine-2-selone ligand. The tris(N-Methyl-imidazolidine-2- selone) mercury(II) complex, [(MeImSe)3HgCl]+Cl - (1), has been characterized by single crystal X-ray analysis and CP MAS 199Hg and 77Se NMR.

AB - A novel cationic Hg(II) complex has been synthesized with N-methyl-imidazolidine-2-selone ligand. The tris(N-Methyl-imidazolidine-2- selone) mercury(II) complex, [(MeImSe)3HgCl]+Cl - (1), has been characterized by single crystal X-ray analysis and CP MAS 199Hg and 77Se NMR.

KW - CP MAS Hg NMR

KW - Crystal structure

KW - Hg(II) complex

KW - N-methyl-imidazolidine-2-selone

KW - Se NMR

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U2 - 10.1016/j.inoche.2005.09.010

DO - 10.1016/j.inoche.2005.09.010

M3 - Article

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SN - 1387-7003

VL - 8

SP - 1109

EP - 1112

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

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ER -