Synthesis, X-ray crystal structures and magnetic properties of Cu(II)(NITpPy)2[N(CN)2]2·solv (NITpPy = nitronyl nitroxide radical, solv = H2O or CH3CN). From discrete molecules to 2-D polymeric coordination compounds

Iwayan Dasna; Stéphane Golhen; Lahcène Ouahab; Mohammed Fettouhi; Octavio Pena; Nathalie Daro; Jean Pascal Sutter

doi:10.1016/S0020-1693(01)00592-8

Synthesis, X-ray crystal structures and magnetic properties of Cu(II)(NITpPy)₂[N(CN)₂]₂·solv (NITpPy = nitronyl nitroxide radical, solv = H₂O or CH₃CN). From discrete molecules to 2-D polymeric coordination compounds

Iwayan Dasna
, Stéphane Golhen
, Lahcène Ouahab^*
, Mohammed Fettouhi
, Octavio Pena
, Nathalie Daro
, Jean Pascal Sutter

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

The synthesis, X-ray crystal structures and magnetic properties of five new copper(II) complexes containing nitroxide radicals Cu(NITpPy)₂(NO₃)₂ (1), Cu(NITpPy)₂(CH₃COO)₂ (2), Cu(NITpPy)₂[N(CN)₂]₂· (H₂O)₂ (3), Cu(NITpPy)₂[N(CN)₂]₂·3CH₃ CN (4) and Cu(NITpPy)₂[N(CN)₂]₂·2CH₃ CN (5) are reported. Compounds 1-3 consists of discrete molecules in the solid state, but in compounds 4 and 5 the Cu(NITpPy)₂²⁺ units are connected through N(CN)₂^- bridging ligands in μ₂ coordination developing, respectively, into one-dimensional and two-dimensional polymeric networks. For all compounds, the magnetic properties have been investigated and antiferromagnetic interactions dominate at low temperature.

Original language	English
Pages (from-to)	37-46
Number of pages	10
Journal	Inorganica Chimica Acta
Volume	326
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(01)00592-8
State	Published - 17 Dec 2001

Bibliographical note

Funding Information:
This work is supported by the CNRS and the Université de Rennes 1. I.D. thanks the Indonesian Ministry of National Education (PGSM Project) for a PhD grant.

Keywords

Copper
Dicyanamide
Magnetism
Nitronyl-nitroxide
Polymeric compounds

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Dasna, I., Golhen, S., Ouahab, L., Fettouhi, M., Pena, O., Daro, N., & Sutter, J. P. (2001). Synthesis, X-ray crystal structures and magnetic properties of Cu(II)(NITpPy)₂[N(CN)₂]₂·solv (NITpPy = nitronyl nitroxide radical, solv = H₂O or CH₃CN). From discrete molecules to 2-D polymeric coordination compounds. Inorganica Chimica Acta, 326(1), 37-46. https://doi.org/10.1016/S0020-1693(01)00592-8

@article{e870d06808024ef8b99ac74af01a51e3,

title = "Synthesis, X-ray crystal structures and magnetic properties of Cu(II)(NITpPy)2[N(CN)2]2·solv (NITpPy = nitronyl nitroxide radical, solv = H2O or CH3CN). From discrete molecules to 2-D polymeric coordination compounds",

abstract = "The synthesis, X-ray crystal structures and magnetic properties of five new copper(II) complexes containing nitroxide radicals Cu(NITpPy)2(NO3)2 (1), Cu(NITpPy)2(CH3COO)2 (2), Cu(NITpPy)2[N(CN)2]2· (H2O)2 (3), Cu(NITpPy)2[N(CN)2]2·3CH3 CN (4) and Cu(NITpPy)2[N(CN)2]2·2CH3 CN (5) are reported. Compounds 1-3 consists of discrete molecules in the solid state, but in compounds 4 and 5 the Cu(NITpPy)22+ units are connected through N(CN)2- bridging ligands in μ2 coordination developing, respectively, into one-dimensional and two-dimensional polymeric networks. For all compounds, the magnetic properties have been investigated and antiferromagnetic interactions dominate at low temperature.",

keywords = "Copper, Dicyanamide, Magnetism, Nitronyl-nitroxide, Polymeric compounds",

author = "Iwayan Dasna and St{\'e}phane Golhen and Lahc{\`e}ne Ouahab and Mohammed Fettouhi and Octavio Pena and Nathalie Daro and Sutter, \{Jean Pascal\}",

note = "Funding Information: This work is supported by the CNRS and the Universit{\'e} de Rennes 1. I.D. thanks the Indonesian Ministry of National Education (PGSM Project) for a PhD grant. ",

year = "2001",

month = dec,

day = "17",

doi = "10.1016/S0020-1693(01)00592-8",

language = "English",

volume = "326",

pages = "37--46",

journal = "Inorganica Chimica Acta",

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Dasna, I, Golhen, S, Ouahab, L, Fettouhi, M, Pena, O, Daro, N & Sutter, JP 2001, 'Synthesis, X-ray crystal structures and magnetic properties of Cu(II)(NITpPy)₂[N(CN)₂]₂·solv (NITpPy = nitronyl nitroxide radical, solv = H₂O or CH₃CN). From discrete molecules to 2-D polymeric coordination compounds', Inorganica Chimica Acta, vol. 326, no. 1, pp. 37-46. https://doi.org/10.1016/S0020-1693(01)00592-8

Synthesis, X-ray crystal structures and magnetic properties of Cu(II)(NITpPy)₂[N(CN)₂]₂·solv (NITpPy = nitronyl nitroxide radical, solv = H₂O or CH₃CN). From discrete molecules to 2-D polymeric coordination compounds. / Dasna, Iwayan; Golhen, Stéphane; Ouahab, Lahcène et al.
In: Inorganica Chimica Acta, Vol. 326, No. 1, 17.12.2001, p. 37-46.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, X-ray crystal structures and magnetic properties of Cu(II)(NITpPy)2[N(CN)2]2·solv (NITpPy = nitronyl nitroxide radical, solv = H2O or CH3CN). From discrete molecules to 2-D polymeric coordination compounds

AU - Dasna, Iwayan

AU - Golhen, Stéphane

AU - Ouahab, Lahcène

AU - Fettouhi, Mohammed

AU - Pena, Octavio

AU - Daro, Nathalie

AU - Sutter, Jean Pascal

N1 - Funding Information: This work is supported by the CNRS and the Université de Rennes 1. I.D. thanks the Indonesian Ministry of National Education (PGSM Project) for a PhD grant.

PY - 2001/12/17

Y1 - 2001/12/17

N2 - The synthesis, X-ray crystal structures and magnetic properties of five new copper(II) complexes containing nitroxide radicals Cu(NITpPy)2(NO3)2 (1), Cu(NITpPy)2(CH3COO)2 (2), Cu(NITpPy)2[N(CN)2]2· (H2O)2 (3), Cu(NITpPy)2[N(CN)2]2·3CH3 CN (4) and Cu(NITpPy)2[N(CN)2]2·2CH3 CN (5) are reported. Compounds 1-3 consists of discrete molecules in the solid state, but in compounds 4 and 5 the Cu(NITpPy)22+ units are connected through N(CN)2- bridging ligands in μ2 coordination developing, respectively, into one-dimensional and two-dimensional polymeric networks. For all compounds, the magnetic properties have been investigated and antiferromagnetic interactions dominate at low temperature.

AB - The synthesis, X-ray crystal structures and magnetic properties of five new copper(II) complexes containing nitroxide radicals Cu(NITpPy)2(NO3)2 (1), Cu(NITpPy)2(CH3COO)2 (2), Cu(NITpPy)2[N(CN)2]2· (H2O)2 (3), Cu(NITpPy)2[N(CN)2]2·3CH3 CN (4) and Cu(NITpPy)2[N(CN)2]2·2CH3 CN (5) are reported. Compounds 1-3 consists of discrete molecules in the solid state, but in compounds 4 and 5 the Cu(NITpPy)22+ units are connected through N(CN)2- bridging ligands in μ2 coordination developing, respectively, into one-dimensional and two-dimensional polymeric networks. For all compounds, the magnetic properties have been investigated and antiferromagnetic interactions dominate at low temperature.

KW - Copper

KW - Dicyanamide

KW - Magnetism

KW - Nitronyl-nitroxide

KW - Polymeric compounds

UR - https://www.scopus.com/pages/publications/0035905063

U2 - 10.1016/S0020-1693(01)00592-8

DO - 10.1016/S0020-1693(01)00592-8

M3 - Article

AN - SCOPUS:0035905063

SN - 0020-1693

VL - 326

SP - 37

EP - 46

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -