Synthesis, X-ray crystal structure, spectroscopic characterization, and thermal chemistry of trans-diaqua-bis-(2-hydroxyiminopropionato-N,O) zinc(II), trans-{(H2O)2[H3CC(=NOH)COO)]2Zn} - A precursor for nano-crystalline zincite

Abdulaziz A. Bagabas; Allen W. Apblett; Ahsan M. Shemsi; Zaki S. Seddigi

doi:10.1080/10241220802184434

Synthesis, X-ray crystal structure, spectroscopic characterization, and thermal chemistry of trans-diaqua-bis-(2-hydroxyiminopropionato-N,O) zinc(II), trans-{(H₂O)₂[H₃CC(=NOH)COO)]₂Zn} - A precursor for nano-crystalline zincite

Abdulaziz A. Bagabas
, Allen W. Apblett
, Ahsan M. Shemsi
, Zaki S. Seddigi

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Zinc(II) 2-oximinopropionate dihydrate [Zn(PAO)₂(H₂O)₂] was precipitated by treatment of an aqueous solution of zinc sulfate with sodium pyruvate oxime, Na(PAO) · H₂O. The product was characterized by infrared spectroscopy, solid-state carbon-13 nuclear magnetic resonance spectroscopy, X-ray diffraction (XRD), and thermal gravimetric and differential thermal analyses (TGA and DTA). A stepwise decomposition pathway was observed in the TGA trace of this complex. The product produced at each step was investigated by IR, XRD, solid-state, ¹³C NMR, and scanning and transmission electron microscopy (SEM and TEM). The crystallite size of the zincite was measured by XRD. Surface area of the zincite was also measured. Furthermore, the structure of the Zn(PAO)₂(H₂O)₂ complex was established for the first time by X-ray single crystal diffraction of suitable crystals obtained in aqueous medium.

Original language	English
Pages (from-to)	65-81
Number of pages	17
Journal	Main Group Chemistry
Volume	7
Issue number	1
DOIs	https://doi.org/10.1080/10241220802184434
State	Published - 2008

Keywords

Nanocrystalline
Pyruvic acid oxime (PAO)
Zincite

ASJC Scopus subject areas

Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1080/10241220802184434

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Bagabas, A. A., Apblett, A. W., Shemsi, A. M., & Seddigi, Z. S. (2008). Synthesis, X-ray crystal structure, spectroscopic characterization, and thermal chemistry of trans-diaqua-bis-(2-hydroxyiminopropionato-N,O) zinc(II), trans-{(H₂O)₂[H₃CC(=NOH)COO)]₂Zn} - A precursor for nano-crystalline zincite. Main Group Chemistry, 7(1), 65-81. https://doi.org/10.1080/10241220802184434

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title = "Synthesis, X-ray crystal structure, spectroscopic characterization, and thermal chemistry of trans-diaqua-bis-(2-hydroxyiminopropionato-N,O) zinc(II), trans-\{(H2O)2[H3CC(=NOH)COO)]2Zn\} - A precursor for nano-crystalline zincite",

abstract = "Zinc(II) 2-oximinopropionate dihydrate [Zn(PAO)2(H2O)2] was precipitated by treatment of an aqueous solution of zinc sulfate with sodium pyruvate oxime, Na(PAO) · H2O. The product was characterized by infrared spectroscopy, solid-state carbon-13 nuclear magnetic resonance spectroscopy, X-ray diffraction (XRD), and thermal gravimetric and differential thermal analyses (TGA and DTA). A stepwise decomposition pathway was observed in the TGA trace of this complex. The product produced at each step was investigated by IR, XRD, solid-state, 13C NMR, and scanning and transmission electron microscopy (SEM and TEM). The crystallite size of the zincite was measured by XRD. Surface area of the zincite was also measured. Furthermore, the structure of the Zn(PAO)2(H2O)2 complex was established for the first time by X-ray single crystal diffraction of suitable crystals obtained in aqueous medium.",

keywords = "Nanocrystalline, Pyruvic acid oxime (PAO), Zincite",

author = "Bagabas, \{Abdulaziz A.\} and Apblett, \{Allen W.\} and Shemsi, \{Ahsan M.\} and Seddigi, \{Zaki S.\}",

year = "2008",

doi = "10.1080/10241220802184434",

language = "English",

volume = "7",

pages = "65--81",

journal = "Main Group Chemistry",

issn = "1024-1221",

publisher = "SAGE Publications Ltd",

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Bagabas, AA, Apblett, AW, Shemsi, AM & Seddigi, ZS 2008, 'Synthesis, X-ray crystal structure, spectroscopic characterization, and thermal chemistry of trans-diaqua-bis-(2-hydroxyiminopropionato-N,O) zinc(II), trans-{(H₂O)₂[H₃CC(=NOH)COO)]₂Zn} - A precursor for nano-crystalline zincite', Main Group Chemistry, vol. 7, no. 1, pp. 65-81. https://doi.org/10.1080/10241220802184434

Synthesis, X-ray crystal structure, spectroscopic characterization, and thermal chemistry of trans-diaqua-bis-(2-hydroxyiminopropionato-N,O) zinc(II), trans-{(H₂O)₂[H₃CC(=NOH)COO)]₂Zn} - A precursor for nano-crystalline zincite. / Bagabas, Abdulaziz A.; Apblett, Allen W.; Shemsi, Ahsan M. et al.
In: Main Group Chemistry, Vol. 7, No. 1, 2008, p. 65-81.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, X-ray crystal structure, spectroscopic characterization, and thermal chemistry of trans-diaqua-bis-(2-hydroxyiminopropionato-N,O) zinc(II), trans-{(H2O)2[H3CC(=NOH)COO)]2Zn} - A precursor for nano-crystalline zincite

AU - Bagabas, Abdulaziz A.

AU - Apblett, Allen W.

AU - Shemsi, Ahsan M.

AU - Seddigi, Zaki S.

PY - 2008

Y1 - 2008

N2 - Zinc(II) 2-oximinopropionate dihydrate [Zn(PAO)2(H2O)2] was precipitated by treatment of an aqueous solution of zinc sulfate with sodium pyruvate oxime, Na(PAO) · H2O. The product was characterized by infrared spectroscopy, solid-state carbon-13 nuclear magnetic resonance spectroscopy, X-ray diffraction (XRD), and thermal gravimetric and differential thermal analyses (TGA and DTA). A stepwise decomposition pathway was observed in the TGA trace of this complex. The product produced at each step was investigated by IR, XRD, solid-state, 13C NMR, and scanning and transmission electron microscopy (SEM and TEM). The crystallite size of the zincite was measured by XRD. Surface area of the zincite was also measured. Furthermore, the structure of the Zn(PAO)2(H2O)2 complex was established for the first time by X-ray single crystal diffraction of suitable crystals obtained in aqueous medium.

AB - Zinc(II) 2-oximinopropionate dihydrate [Zn(PAO)2(H2O)2] was precipitated by treatment of an aqueous solution of zinc sulfate with sodium pyruvate oxime, Na(PAO) · H2O. The product was characterized by infrared spectroscopy, solid-state carbon-13 nuclear magnetic resonance spectroscopy, X-ray diffraction (XRD), and thermal gravimetric and differential thermal analyses (TGA and DTA). A stepwise decomposition pathway was observed in the TGA trace of this complex. The product produced at each step was investigated by IR, XRD, solid-state, 13C NMR, and scanning and transmission electron microscopy (SEM and TEM). The crystallite size of the zincite was measured by XRD. Surface area of the zincite was also measured. Furthermore, the structure of the Zn(PAO)2(H2O)2 complex was established for the first time by X-ray single crystal diffraction of suitable crystals obtained in aqueous medium.

KW - Nanocrystalline

KW - Pyruvic acid oxime (PAO)

KW - Zincite

UR - https://www.scopus.com/pages/publications/70350139300

U2 - 10.1080/10241220802184434

DO - 10.1080/10241220802184434

M3 - Article

AN - SCOPUS:70350139300

SN - 1024-1221

VL - 7

SP - 65

EP - 81

JO - Main Group Chemistry

JF - Main Group Chemistry

IS - 1

ER -