Synthesis of thionato(trimethylphosphine)gold(I) complexes

M. Naseem Akhtar; Anvarhusein A. Isab; M. Sakhawat Hussain; A. Rahman Al-Arfaj

doi:10.1007/BF00229711

Synthesis of thionato(trimethylphosphine)gold(I) complexes

M. Naseem Akhtar, Anvarhusein A. Isab^*, M. Sakhawat Hussain, A. Rahman Al-Arfaj

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

New compounds of formula [AuL(PMe₃)]Cl [L = imidazolidine-2-thione (Imt), 1,3-diazinane-2-thione (Diaz), 1,3-diazepine-2-thione (Diap) and their derivatives] have been synthesized and characterized by elemental analysis, and i.r., ¹³C- and ³¹P-n.m.r. spectroscopies. The Diap ligand, which incorporates the thione in a seven-membered heterocyclic ring, binds more strongly to Au¹ compared to its Diaz (six-membered ring) and Imt (five-membered ring) analogues.

Original language	English
Pages (from-to)	553-555
Number of pages	3
Journal	Transition Metal Chemistry
Volume	21
Issue number	6
DOIs	https://doi.org/10.1007/BF00229711
State	Published - 1996

ASJC Scopus subject areas

Inorganic Chemistry
Metals and Alloys
Materials Chemistry

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@article{db8a7758a5f94140abf3178f2c114ddf,

title = "Synthesis of thionato(trimethylphosphine)gold(I) complexes",

abstract = "New compounds of formula [AuL(PMe3)]Cl [L = imidazolidine-2-thione (Imt), 1,3-diazinane-2-thione (Diaz), 1,3-diazepine-2-thione (Diap) and their derivatives] have been synthesized and characterized by elemental analysis, and i.r., 13C- and 31P-n.m.r. spectroscopies. The Diap ligand, which incorporates the thione in a seven-membered heterocyclic ring, binds more strongly to Au1 compared to its Diaz (six-membered ring) and Imt (five-membered ring) analogues.",

author = "Akhtar, \{M. Naseem\} and Isab, \{Anvarhusein A.\} and Hussain, \{M. Sakhawat\} and Al-Arfaj, \{A. Rahman\}",

year = "1996",

doi = "10.1007/BF00229711",

language = "English",

volume = "21",

pages = "553--555",

journal = "Transition Metal Chemistry",

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T1 - Synthesis of thionato(trimethylphosphine)gold(I) complexes

AU - Akhtar, M. Naseem

AU - Isab, Anvarhusein A.

AU - Hussain, M. Sakhawat

AU - Al-Arfaj, A. Rahman

PY - 1996

Y1 - 1996

N2 - New compounds of formula [AuL(PMe3)]Cl [L = imidazolidine-2-thione (Imt), 1,3-diazinane-2-thione (Diaz), 1,3-diazepine-2-thione (Diap) and their derivatives] have been synthesized and characterized by elemental analysis, and i.r., 13C- and 31P-n.m.r. spectroscopies. The Diap ligand, which incorporates the thione in a seven-membered heterocyclic ring, binds more strongly to Au1 compared to its Diaz (six-membered ring) and Imt (five-membered ring) analogues.

AB - New compounds of formula [AuL(PMe3)]Cl [L = imidazolidine-2-thione (Imt), 1,3-diazinane-2-thione (Diaz), 1,3-diazepine-2-thione (Diap) and their derivatives] have been synthesized and characterized by elemental analysis, and i.r., 13C- and 31P-n.m.r. spectroscopies. The Diap ligand, which incorporates the thione in a seven-membered heterocyclic ring, binds more strongly to Au1 compared to its Diaz (six-membered ring) and Imt (five-membered ring) analogues.

UR - https://www.scopus.com/pages/publications/0005850015

U2 - 10.1007/BF00229711

DO - 10.1007/BF00229711

M3 - Article

AN - SCOPUS:0005850015

SN - 0340-4285

VL - 21

SP - 553

EP - 555

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

IS - 6

ER -

Synthesis of thionato(trimethylphosphine)gold(I) complexes

Abstract

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