Synthesis of tetraarylpyridines by chemo-selective Suzuki-Miyaura reactions of 3,5-dibromo-2,6-dichloropyridine

Sebastian Reimann; Silvio Parpart; Peter Ehlers; Muhammad Sharif; Anke Spannenberg; Peter Langer

doi:10.1039/c5ob00866b

Synthesis of tetraarylpyridines by chemo-selective Suzuki-Miyaura reactions of 3,5-dibromo-2,6-dichloropyridine

Sebastian Reimann
, Silvio Parpart
, Peter Ehlers
, Muhammad Sharif
, Anke Spannenberg
, Peter Langer^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Chemoselective Suzuki-Miyaura reactions on 3,5-dibromo-2,6-dichloropyridine were studied. The optimized reaction conditions allow for the facile access of 3-aryl- and 3,5-diarylpyridines in good yields. Suzuki-Miyaura reactions of the selectively synthesized 2,6-dichloro-3,5-diarylpyridines gave the corresponding 2,3,5,6-tetraarylpyridines, containing two different aryl moieties.

Original language	English
Pages (from-to)	6832-6838
Number of pages	7
Journal	Organic and Biomolecular Chemistry
Volume	13
Issue number	24
DOIs	https://doi.org/10.1039/c5ob00866b
State	Published - 28 Jun 2015
Externally published	Yes

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Publisher Copyright:
© The Royal Society of Chemistry 2015.

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1039/c5ob00866b

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title = "Synthesis of tetraarylpyridines by chemo-selective Suzuki-Miyaura reactions of 3,5-dibromo-2,6-dichloropyridine",

abstract = "Chemoselective Suzuki-Miyaura reactions on 3,5-dibromo-2,6-dichloropyridine were studied. The optimized reaction conditions allow for the facile access of 3-aryl- and 3,5-diarylpyridines in good yields. Suzuki-Miyaura reactions of the selectively synthesized 2,6-dichloro-3,5-diarylpyridines gave the corresponding 2,3,5,6-tetraarylpyridines, containing two different aryl moieties.",

author = "Sebastian Reimann and Silvio Parpart and Peter Ehlers and Muhammad Sharif and Anke Spannenberg and Peter Langer",

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doi = "10.1039/c5ob00866b",

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T1 - Synthesis of tetraarylpyridines by chemo-selective Suzuki-Miyaura reactions of 3,5-dibromo-2,6-dichloropyridine

AU - Reimann, Sebastian

AU - Parpart, Silvio

AU - Ehlers, Peter

AU - Sharif, Muhammad

AU - Spannenberg, Anke

AU - Langer, Peter

PY - 2015/6/28

Y1 - 2015/6/28

N2 - Chemoselective Suzuki-Miyaura reactions on 3,5-dibromo-2,6-dichloropyridine were studied. The optimized reaction conditions allow for the facile access of 3-aryl- and 3,5-diarylpyridines in good yields. Suzuki-Miyaura reactions of the selectively synthesized 2,6-dichloro-3,5-diarylpyridines gave the corresponding 2,3,5,6-tetraarylpyridines, containing two different aryl moieties.

AB - Chemoselective Suzuki-Miyaura reactions on 3,5-dibromo-2,6-dichloropyridine were studied. The optimized reaction conditions allow for the facile access of 3-aryl- and 3,5-diarylpyridines in good yields. Suzuki-Miyaura reactions of the selectively synthesized 2,6-dichloro-3,5-diarylpyridines gave the corresponding 2,3,5,6-tetraarylpyridines, containing two different aryl moieties.

UR - https://www.scopus.com/pages/publications/84935881297

U2 - 10.1039/c5ob00866b

DO - 10.1039/c5ob00866b

M3 - Article

AN - SCOPUS:84935881297

SN - 1477-0520

VL - 13

SP - 6832

EP - 6838

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 24

ER -

Synthesis of tetraarylpyridines by chemo-selective Suzuki-Miyaura reactions of 3,5-dibromo-2,6-dichloropyridine

Abstract

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