Synthesis of reduced graphene oxide supported FeCu and its environmental applications

A significant share of wastewater produced during different processes is released to the surroundings without further treatment. Therefore, polluted water sources are triggering diseases like typhoid. To avoid this, various techniques have been developed for the removal of contaminants from the water. Iron-copper bimetallic nanoparticles (NPs) supported on the reduced graphene oxide (rGOFeCu) were prepared which showed excellent antibacterial activity, efficient dechlorination of 1,1,1-trichloroethane (TCA), and removal of methylene blue (MB). The characterization of prepared nanocomposites was done by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Iron-based bimetallic NPs supported on the graphene were successfully synthesized as confirmed by TEM. Iron has a strong antibacterial effect on microorganisms, especially bacteria. We conducted the antibacterial activity of different compositions of nanocomposite toward Escherichia coli to understand the efficacy of prepared nanocomposites. In the same time and concentration conditions, rGOFeCu showed the best antibacterial activity, as compared to the graphene-based iron. Results show that the excellent antibacterial activity was exhibited by using rGO-Fe₉₅Cu₀₅ within two hours. More than 98% of cell inhibition was observed. The further increase in copper loading has no major effect on antibacterial activity. rGO-Fe₉₅Cu₀₅ exhibited excellent removal efficiency of TCA (99%) within 30 min as compared to other compositions of FeCu. It was found that rGO-Fe₉₅Cu₀₅ exhibited excellent removal efficiency against degradation of methylene blue (MB) through activation of sodium percarbonate (SPC). The results indicated that more than 99% of MB was removed within 15 min. The rGOFeCu represented a great potential material for antibacterial activity towards E. coli and remediation of other pollutants in the wastewater such as TCA and removal of MB. Graphical Abstract: (Figure presented.)