Synthesis of Nitrogen-Rich Carbon Nitride-Based Hybrids and a New Insight of Their Battery Behaviors

Jang Mee Lee; Stalin Joseph; Ian Chirchir Bargoria; Sungho Kim; Gurwinder Singh; Jae Hun Yang; Kavitha Ramadass; Rohan Bahadur; Xiaojiang Yu; Mark BH Breese; Jiabao Yi; Ajayan Vinu

doi:10.1002/batt.202100369

Synthesis of Nitrogen-Rich Carbon Nitride-Based Hybrids and a New Insight of Their Battery Behaviors

Jang Mee Lee^*, Stalin Joseph, Ian Chirchir Bargoria, Sungho Kim, Gurwinder Singh, Jae Hun Yang, Kavitha Ramadass, Rohan Bahadur, Xiaojiang Yu, Mark BH Breese, Jiabao Yi, Ajayan Vinu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

N-rich carbon nitride (CN) is a promising framework that can generate innovative hybrid structures for energy applications. However, the low thermal stability of N atoms in the CN matrix is a major drawback as the crystallization of the hybridized counterpart requires a high temperature. Herein, we report the successful synthesis of the hybrid of N-rich CN and Fe_1-xS at 700 °C by constructing a stable C−N−Fe−S heterointerface using a Fe-incorporated metal-organic framework (MOF) and dithiooxamide containing C, N and S atoms. The hybrids display promising capacities toward Li⁺ and Na⁺ ions storage, highlighting the beneficial role of N-rich CN on battery performance. By systematically investigating their structure and electrochemical properties, we show that N-rich CN, along with the heterointerface, not only acts as a hybridization matrix that helps facilitate the charge transfer kinetics but also generates substantial capacity. This unique study reveals a powerful platform for the rational design of N-rich CN based hybrids from MOF.

Original language	English
Article number	e202100369
Journal	Batteries and Supercaps
Volume	5
Issue number	4
DOIs	https://doi.org/10.1002/batt.202100369
State	Published - Apr 2022
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2021 Wiley-VCH GmbH.

Keywords

C−N−Fe−S HI
N-rich carbon nitride
battery
hybrids
iron sulfide

ASJC Scopus subject areas

Energy Engineering and Power Technology
Electrical and Electronic Engineering
Electrochemistry

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1002/batt.202100369

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title = "Synthesis of Nitrogen-Rich Carbon Nitride-Based Hybrids and a New Insight of Their Battery Behaviors",

abstract = "N-rich carbon nitride (CN) is a promising framework that can generate innovative hybrid structures for energy applications. However, the low thermal stability of N atoms in the CN matrix is a major drawback as the crystallization of the hybridized counterpart requires a high temperature. Herein, we report the successful synthesis of the hybrid of N-rich CN and Fe1-xS at 700 °C by constructing a stable C−N−Fe−S heterointerface using a Fe-incorporated metal-organic framework (MOF) and dithiooxamide containing C, N and S atoms. The hybrids display promising capacities toward Li+ and Na+ ions storage, highlighting the beneficial role of N-rich CN on battery performance. By systematically investigating their structure and electrochemical properties, we show that N-rich CN, along with the heterointerface, not only acts as a hybridization matrix that helps facilitate the charge transfer kinetics but also generates substantial capacity. This unique study reveals a powerful platform for the rational design of N-rich CN based hybrids from MOF.",

keywords = "C−N−Fe−S HI, N-rich carbon nitride, battery, hybrids, iron sulfide",

author = "\{Mee Lee\}, Jang and Stalin Joseph and \{Chirchir Bargoria\}, Ian and Sungho Kim and Gurwinder Singh and Yang, \{Jae Hun\} and Kavitha Ramadass and Rohan Bahadur and Xiaojiang Yu and \{BH Breese\}, Mark and Jiabao Yi and Ajayan Vinu",

note = "Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH.",

year = "2022",

month = apr,

doi = "10.1002/batt.202100369",

language = "English",

volume = "5",

journal = "Batteries and Supercaps",

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T1 - Synthesis of Nitrogen-Rich Carbon Nitride-Based Hybrids and a New Insight of Their Battery Behaviors

AU - Mee Lee, Jang

AU - Joseph, Stalin

AU - Chirchir Bargoria, Ian

AU - Kim, Sungho

AU - Singh, Gurwinder

AU - Yang, Jae Hun

AU - Ramadass, Kavitha

AU - Bahadur, Rohan

AU - Yu, Xiaojiang

AU - BH Breese, Mark

AU - Yi, Jiabao

AU - Vinu, Ajayan

PY - 2022/4

Y1 - 2022/4

N2 - N-rich carbon nitride (CN) is a promising framework that can generate innovative hybrid structures for energy applications. However, the low thermal stability of N atoms in the CN matrix is a major drawback as the crystallization of the hybridized counterpart requires a high temperature. Herein, we report the successful synthesis of the hybrid of N-rich CN and Fe1-xS at 700 °C by constructing a stable C−N−Fe−S heterointerface using a Fe-incorporated metal-organic framework (MOF) and dithiooxamide containing C, N and S atoms. The hybrids display promising capacities toward Li+ and Na+ ions storage, highlighting the beneficial role of N-rich CN on battery performance. By systematically investigating their structure and electrochemical properties, we show that N-rich CN, along with the heterointerface, not only acts as a hybridization matrix that helps facilitate the charge transfer kinetics but also generates substantial capacity. This unique study reveals a powerful platform for the rational design of N-rich CN based hybrids from MOF.

AB - N-rich carbon nitride (CN) is a promising framework that can generate innovative hybrid structures for energy applications. However, the low thermal stability of N atoms in the CN matrix is a major drawback as the crystallization of the hybridized counterpart requires a high temperature. Herein, we report the successful synthesis of the hybrid of N-rich CN and Fe1-xS at 700 °C by constructing a stable C−N−Fe−S heterointerface using a Fe-incorporated metal-organic framework (MOF) and dithiooxamide containing C, N and S atoms. The hybrids display promising capacities toward Li+ and Na+ ions storage, highlighting the beneficial role of N-rich CN on battery performance. By systematically investigating their structure and electrochemical properties, we show that N-rich CN, along with the heterointerface, not only acts as a hybridization matrix that helps facilitate the charge transfer kinetics but also generates substantial capacity. This unique study reveals a powerful platform for the rational design of N-rich CN based hybrids from MOF.

KW - C−N−Fe−S HI

KW - N-rich carbon nitride

KW - battery

KW - hybrids

KW - iron sulfide

UR - https://www.scopus.com/pages/publications/85122687318

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DO - 10.1002/batt.202100369

M3 - Article

AN - SCOPUS:85122687318

SN - 2566-6223

VL - 5

JO - Batteries and Supercaps

JF - Batteries and Supercaps

IS - 4

M1 - e202100369

ER -

Synthesis of Nitrogen-Rich Carbon Nitride-Based Hybrids and a New Insight of Their Battery Behaviors

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

UN SDGs

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