Synthesis of new cardanol and cardol derivatives by allylation and regioselective cyclocarbonylation reactions

Riccardo Amorati; Orazio A. Attanasi; Bassam El Ali; Paolino Filippone; Giuseppe Mele; Jolanda Spadavecchia; Giuseppe Vasapollo

doi:10.1055/s-2002-35983

Synthesis of new cardanol and cardol derivatives by allylation and regioselective cyclocarbonylation reactions

Riccardo Amorati, Orazio A. Attanasi, Bassam El Ali, Paolino Filippone^*, Giuseppe Mele, Jolanda Spadavecchia, Giuseppe Vasapollo

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

Palladium acetate [Pd(OAc)₂] and 1,4-bis(diphenylphosphino)butane (dppb) catalyse cyclocarbonylation of allylic cardanol and cardol derivatives to give regioselectively 7-membered ring lactones in good yields. One of the compounds prepared exhibits excellent antioxidant properties.

Original language	English
Pages (from-to)	2749-2755
Number of pages	7
Journal	Synthesis
Issue number	18
DOIs	https://doi.org/10.1055/s-2002-35983
State	Published - 2002

Keywords

Allylations
Carbonylations
Cardanol
Cardol
Lactones
Palladium

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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title = "Synthesis of new cardanol and cardol derivatives by allylation and regioselective cyclocarbonylation reactions",

abstract = "Palladium acetate [Pd(OAc)2] and 1,4-bis(diphenylphosphino)butane (dppb) catalyse cyclocarbonylation of allylic cardanol and cardol derivatives to give regioselectively 7-membered ring lactones in good yields. One of the compounds prepared exhibits excellent antioxidant properties.",

keywords = "Allylations, Carbonylations, Cardanol, Cardol, Lactones, Palladium",

author = "Riccardo Amorati and Attanasi, {Orazio A.} and {El Ali}, Bassam and Paolino Filippone and Giuseppe Mele and Jolanda Spadavecchia and Giuseppe Vasapollo",

year = "2002",

doi = "10.1055/s-2002-35983",

language = "English",

pages = "2749--2755",

journal = "Synthesis",

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T1 - Synthesis of new cardanol and cardol derivatives by allylation and regioselective cyclocarbonylation reactions

AU - Amorati, Riccardo

AU - Attanasi, Orazio A.

AU - El Ali, Bassam

AU - Filippone, Paolino

AU - Mele, Giuseppe

AU - Spadavecchia, Jolanda

AU - Vasapollo, Giuseppe

PY - 2002

Y1 - 2002

N2 - Palladium acetate [Pd(OAc)2] and 1,4-bis(diphenylphosphino)butane (dppb) catalyse cyclocarbonylation of allylic cardanol and cardol derivatives to give regioselectively 7-membered ring lactones in good yields. One of the compounds prepared exhibits excellent antioxidant properties.

AB - Palladium acetate [Pd(OAc)2] and 1,4-bis(diphenylphosphino)butane (dppb) catalyse cyclocarbonylation of allylic cardanol and cardol derivatives to give regioselectively 7-membered ring lactones in good yields. One of the compounds prepared exhibits excellent antioxidant properties.

KW - Allylations

KW - Carbonylations

KW - Cardanol

KW - Cardol

KW - Lactones

KW - Palladium

UR - http://www.scopus.com/inward/record.url?scp=0036920927&partnerID=8YFLogxK

U2 - 10.1055/s-2002-35983

DO - 10.1055/s-2002-35983

M3 - Article

AN - SCOPUS:0036920927

SN - 0039-7881

SP - 2749

EP - 2755

JO - Synthesis

JF - Synthesis

IS - 18

ER -

Synthesis of new cardanol and cardol derivatives by allylation and regioselective cyclocarbonylation reactions

Abstract

Keywords

ASJC Scopus subject areas

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