Synthesis of dodecamolybdoantimonate(V) salts containing the Keggin structure

  • Raj P. Singh*
  • , Radheshyam P. Khatri
  • , Jean Dubois
  • , Sushma S. Gaur
  • , Mitsuo Abe
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Ammonium dodecamolybdoantimonate, with a body-centred cubic symmetry, has been synthesized from antimony(III) oxide and ammonium heptamolybdate in aqueous acidic solution. The corresponding potassium, rubidium and caesium salts were prepared by ion exchange. They were characterized by elemental analysis, X-ray diffraction, X-ray fluorescence, i.r., X-ray photoelectron spectroscopy, thermogravimetry, and differential thermal analysis.

Original languageEnglish
Pages (from-to)947-951
Number of pages5
JournalJournal of the Chemical Society, Dalton Transactions
Issue number3
DOIs
StatePublished - 1990

ASJC Scopus subject areas

  • General Chemistry

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