Synthesis, characterization and antimicrobial studies of mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones: Crystal structure of bis[{(μ2-diazinane-2-thione)(diazinane-2-thione) (triphenylphosphine)silver(I) nitrate}]

Sidra Nawaz; Anvarhusein A. Isab; Klaus Merz; Vera Vasylyeva; Nils Metzler-Nolte; Muhammad Saleem; Saeed Ahmad

doi:10.1016/j.poly.2011.02.054

Synthesis, characterization and antimicrobial studies of mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones: Crystal structure of bis[{(μ²-diazinane-2-thione)(diazinane-2-thione) (triphenylphosphine)silver(I) nitrate}]

Sidra Nawaz
, Anvarhusein A. Isab
, Klaus Merz
, Vera Vasylyeva
, Nils Metzler-Nolte
, Muhammad Saleem
, Saeed Ahmad^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones (imidazolidine-2-thione (Imt), diazinane-2-thione (Diaz) and 2-mercaptopyridine (Mpy)) having the general formulae [(Ph₃P) Ag(thione)₂]NO₃ and [(Ph₃P) ₂Ag(thione)]NO₃ were prepared and characterized by elemental analysis, IR and NMR (¹H, ¹³C and ³¹P) spectroscopic methods. The crystal structure of one of the complexes, [Ag(Ph₃P)(Diaz)₂]₂(NO ₃)₂ (1) was determined by X-ray crystallography. The title complex (1) is dinuclear, having each silver atom coordinated to three thione sulfur atoms of Diaz and to one phosphorus atom of PPh₃ in a nearly tetrahedral environment, with an average P-Ag-S bond angle of 108.5°. The spectral data of the complexes are consistent with sulfur coordination of the thiones to silver(I). Antimicrobial activities of the complexes were evaluated by minimum inhibitory concentrations and the results showed that the complexes exhibit a wide range of activity against two gram-negative bacteria (E. coli, P. aeruginosa) and molds (A. niger, P. citrinum), while the activities were poor against yeasts (C. albicans, S. cerevisiae).

Original language	English
Pages (from-to)	1502-1506
Number of pages	5
Journal	Polyhedron
Volume	30
Issue number	9
DOIs	https://doi.org/10.1016/j.poly.2011.02.054
State	Published - 26 May 2011

Keywords

Antimicrobial activity
Silver(I) complexes
Thiones
Triphenylphosphine
X-ray structure

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Nawaz, S., Isab, A. A., Merz, K., Vasylyeva, V., Metzler-Nolte, N., Saleem, M., & Ahmad, S. (2011). Synthesis, characterization and antimicrobial studies of mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones: Crystal structure of bis[{(μ²-diazinane-2-thione)(diazinane-2-thione) (triphenylphosphine)silver(I) nitrate}]. Polyhedron, 30(9), 1502-1506. https://doi.org/10.1016/j.poly.2011.02.054

@article{3ef0b5c3519643c4bd9530513f7ecd2f,

title = "Synthesis, characterization and antimicrobial studies of mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones: Crystal structure of bis[\{(μ2-diazinane-2-thione)(diazinane-2-thione) (triphenylphosphine)silver(I) nitrate\}]",

abstract = "Mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones (imidazolidine-2-thione (Imt), diazinane-2-thione (Diaz) and 2-mercaptopyridine (Mpy)) having the general formulae [(Ph3P) Ag(thione)2]NO3 and [(Ph3P) 2Ag(thione)]NO3 were prepared and characterized by elemental analysis, IR and NMR (1H, 13C and 31P) spectroscopic methods. The crystal structure of one of the complexes, [Ag(Ph3P)(Diaz)2]2(NO 3)2 (1) was determined by X-ray crystallography. The title complex (1) is dinuclear, having each silver atom coordinated to three thione sulfur atoms of Diaz and to one phosphorus atom of PPh3 in a nearly tetrahedral environment, with an average P-Ag-S bond angle of 108.5°. The spectral data of the complexes are consistent with sulfur coordination of the thiones to silver(I). Antimicrobial activities of the complexes were evaluated by minimum inhibitory concentrations and the results showed that the complexes exhibit a wide range of activity against two gram-negative bacteria (E. coli, P. aeruginosa) and molds (A. niger, P. citrinum), while the activities were poor against yeasts (C. albicans, S. cerevisiae).",

keywords = "Antimicrobial activity, Silver(I) complexes, Thiones, Triphenylphosphine, X-ray structure",

author = "Sidra Nawaz and Isab, \{Anvarhusein A.\} and Klaus Merz and Vera Vasylyeva and Nils Metzler-Nolte and Muhammad Saleem and Saeed Ahmad",

year = "2011",

month = may,

day = "26",

doi = "10.1016/j.poly.2011.02.054",

language = "English",

volume = "30",

pages = "1502--1506",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "9",

}

Nawaz, S, Isab, AA, Merz, K, Vasylyeva, V, Metzler-Nolte, N, Saleem, M & Ahmad, S 2011, 'Synthesis, characterization and antimicrobial studies of mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones: Crystal structure of bis[{(μ²-diazinane-2-thione)(diazinane-2-thione) (triphenylphosphine)silver(I) nitrate}]', Polyhedron, vol. 30, no. 9, pp. 1502-1506. https://doi.org/10.1016/j.poly.2011.02.054

Synthesis, characterization and antimicrobial studies of mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones: Crystal structure of bis[{(μ²-diazinane-2-thione)(diazinane-2-thione) (triphenylphosphine)silver(I) nitrate}]. / Nawaz, Sidra; Isab, Anvarhusein A.; Merz, Klaus et al.
In: Polyhedron, Vol. 30, No. 9, 26.05.2011, p. 1502-1506.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, characterization and antimicrobial studies of mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones

T2 - Crystal structure of bis[{(μ2-diazinane-2-thione)(diazinane-2-thione) (triphenylphosphine)silver(I) nitrate}]

AU - Nawaz, Sidra

AU - Isab, Anvarhusein A.

AU - Merz, Klaus

AU - Vasylyeva, Vera

AU - Metzler-Nolte, Nils

AU - Saleem, Muhammad

AU - Ahmad, Saeed

PY - 2011/5/26

Y1 - 2011/5/26

N2 - Mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones (imidazolidine-2-thione (Imt), diazinane-2-thione (Diaz) and 2-mercaptopyridine (Mpy)) having the general formulae [(Ph3P) Ag(thione)2]NO3 and [(Ph3P) 2Ag(thione)]NO3 were prepared and characterized by elemental analysis, IR and NMR (1H, 13C and 31P) spectroscopic methods. The crystal structure of one of the complexes, [Ag(Ph3P)(Diaz)2]2(NO 3)2 (1) was determined by X-ray crystallography. The title complex (1) is dinuclear, having each silver atom coordinated to three thione sulfur atoms of Diaz and to one phosphorus atom of PPh3 in a nearly tetrahedral environment, with an average P-Ag-S bond angle of 108.5°. The spectral data of the complexes are consistent with sulfur coordination of the thiones to silver(I). Antimicrobial activities of the complexes were evaluated by minimum inhibitory concentrations and the results showed that the complexes exhibit a wide range of activity against two gram-negative bacteria (E. coli, P. aeruginosa) and molds (A. niger, P. citrinum), while the activities were poor against yeasts (C. albicans, S. cerevisiae).

AB - Mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones (imidazolidine-2-thione (Imt), diazinane-2-thione (Diaz) and 2-mercaptopyridine (Mpy)) having the general formulae [(Ph3P) Ag(thione)2]NO3 and [(Ph3P) 2Ag(thione)]NO3 were prepared and characterized by elemental analysis, IR and NMR (1H, 13C and 31P) spectroscopic methods. The crystal structure of one of the complexes, [Ag(Ph3P)(Diaz)2]2(NO 3)2 (1) was determined by X-ray crystallography. The title complex (1) is dinuclear, having each silver atom coordinated to three thione sulfur atoms of Diaz and to one phosphorus atom of PPh3 in a nearly tetrahedral environment, with an average P-Ag-S bond angle of 108.5°. The spectral data of the complexes are consistent with sulfur coordination of the thiones to silver(I). Antimicrobial activities of the complexes were evaluated by minimum inhibitory concentrations and the results showed that the complexes exhibit a wide range of activity against two gram-negative bacteria (E. coli, P. aeruginosa) and molds (A. niger, P. citrinum), while the activities were poor against yeasts (C. albicans, S. cerevisiae).

KW - Antimicrobial activity

KW - Silver(I) complexes

KW - Thiones

KW - Triphenylphosphine

KW - X-ray structure

UR - https://www.scopus.com/pages/publications/79955751926

U2 - 10.1016/j.poly.2011.02.054

DO - 10.1016/j.poly.2011.02.054

M3 - Article

AN - SCOPUS:79955751926

SN - 0277-5387

VL - 30

SP - 1502

EP - 1506

JO - Polyhedron

JF - Polyhedron

IS - 9

ER -

Nawaz S, Isab AA, Merz K, Vasylyeva V, Metzler-Nolte N, Saleem M et al. Synthesis, characterization and antimicrobial studies of mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones: Crystal structure of bis[{(μ²-diazinane-2-thione)(diazinane-2-thione) (triphenylphosphine)silver(I) nitrate}]. Polyhedron. 2011 May 26;30(9):1502-1506. doi: 10.1016/j.poly.2011.02.054