Synthesis characterisation and stability of mixed aryldichalcogenide bis(diphenylphosphino)ethanenickel(II) complexes. X-ray structure of Ni(dppe)(SeC6H4S)

Mary S. Thomas; James Darkwa; Emmanuel Y. Osei-Twum; Luis A. Litorja

doi:10.1016/S0277-5387(99)00191-6

Synthesis characterisation and stability of mixed aryldichalcogenide bis(diphenylphosphino)ethanenickel(II) complexes. X-ray structure of Ni(dppe)(SeC₆H₄S)

Mary S. Thomas
, James Darkwa^*
, Emmanuel Y. Osei-Twum
, Luis A. Litorja

^*Corresponding author for this work

King Fahd University of Petroleum & Minerals

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Mixed chalcogenide complexes of the type Ni(dppe)(SeC₆H₄S) (dppe=bis(diphenylphosphino)ethane), Ni(dppe)(SC₅H₃NCO₂) and Ni(dppe)(EC₅H₃NE′) (E=NH, E′=O; E=E′=NH) have been prepared from the reactions of Ni(dppe)Cl₂ with the appropriate aryldichalcogen or pyridine-based compound, using Et₃N as a base. The relative solution and thermal stabilities of the above compounds, other mixed chalcogen ones, Ni(dppe)(SC₆H₄O), Ni(dppe)(SC₆H₄CO₂) and Ni(dppe)(SC₆H₄NH), and the homoleptic compounds Ni(dppe)(EC₆H₄E′) (E=E′=O, E=E′=S; R=H, Me), were established by a combination of electron impact mass spectrometry (EIMS) and fast atom bombardment (FABMS). The most stable ones were the compounds with homoleptic sulfur ligands.

Original language	English
Pages (from-to)	2803-2810
Number of pages	8
Journal	Polyhedron
Volume	18
Issue number	21
DOIs	https://doi.org/10.1016/S0277-5387(99)00191-6
State	Published - 10 Sep 1999

Bibliographical note

Funding Information:
Financial support from the Foundation for Research Development, South Africa (J.D.), University of the North and the Research Institute, King Fahd University of Petroleum and Minerals is gratefully acknowledged. We are also grateful to Professor J.C.A. Boeyens and Ms. Leanne Cook, Structural Chemistry Department, University of the Witwatersrand, South Africa, determining the crystal structure as a service.

Keywords

Crystal structure
Mass spectrometry
Nickel(II) complexes
Stability

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0277-5387(99)00191-6

Cite this

@article{dbd6e774699540c094f837ccafeab092,

title = "Synthesis characterisation and stability of mixed aryldichalcogenide bis(diphenylphosphino)ethanenickel(II) complexes. X-ray structure of Ni(dppe)(SeC6H4S)",

abstract = "Mixed chalcogenide complexes of the type Ni(dppe)(SeC6H4S) (dppe=bis(diphenylphosphino)ethane), Ni(dppe)(SC5H3NCO2) and Ni(dppe)(EC5H3NE′) (E=NH, E′=O; E=E′=NH) have been prepared from the reactions of Ni(dppe)Cl2 with the appropriate aryldichalcogen or pyridine-based compound, using Et3N as a base. The relative solution and thermal stabilities of the above compounds, other mixed chalcogen ones, Ni(dppe)(SC6H4O), Ni(dppe)(SC6H4CO2) and Ni(dppe)(SC6H4NH), and the homoleptic compounds Ni(dppe)(EC6H4E′) (E=E′=O, E=E′=S; R=H, Me), were established by a combination of electron impact mass spectrometry (EIMS) and fast atom bombardment (FABMS). The most stable ones were the compounds with homoleptic sulfur ligands.",

keywords = "Crystal structure, Mass spectrometry, Nickel(II) complexes, Stability",

author = "Thomas, \{Mary S.\} and James Darkwa and Osei-Twum, \{Emmanuel Y.\} and Litorja, \{Luis A.\}",

note = "Funding Information: Financial support from the Foundation for Research Development, South Africa (J.D.), University of the North and the Research Institute, King Fahd University of Petroleum and Minerals is gratefully acknowledged. We are also grateful to Professor J.C.A. Boeyens and Ms. Leanne Cook, Structural Chemistry Department, University of the Witwatersrand, South Africa, determining the crystal structure as a service.",

year = "1999",

month = sep,

day = "10",

doi = "10.1016/S0277-5387(99)00191-6",

language = "English",

volume = "18",

pages = "2803--2810",

journal = "Polyhedron",

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publisher = "Elsevier Ltd.",

number = "21",

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TY - JOUR

T1 - Synthesis characterisation and stability of mixed aryldichalcogenide bis(diphenylphosphino)ethanenickel(II) complexes. X-ray structure of Ni(dppe)(SeC6H4S)

AU - Thomas, Mary S.

AU - Darkwa, James

AU - Osei-Twum, Emmanuel Y.

AU - Litorja, Luis A.

N1 - Funding Information: Financial support from the Foundation for Research Development, South Africa (J.D.), University of the North and the Research Institute, King Fahd University of Petroleum and Minerals is gratefully acknowledged. We are also grateful to Professor J.C.A. Boeyens and Ms. Leanne Cook, Structural Chemistry Department, University of the Witwatersrand, South Africa, determining the crystal structure as a service.

PY - 1999/9/10

Y1 - 1999/9/10

N2 - Mixed chalcogenide complexes of the type Ni(dppe)(SeC6H4S) (dppe=bis(diphenylphosphino)ethane), Ni(dppe)(SC5H3NCO2) and Ni(dppe)(EC5H3NE′) (E=NH, E′=O; E=E′=NH) have been prepared from the reactions of Ni(dppe)Cl2 with the appropriate aryldichalcogen or pyridine-based compound, using Et3N as a base. The relative solution and thermal stabilities of the above compounds, other mixed chalcogen ones, Ni(dppe)(SC6H4O), Ni(dppe)(SC6H4CO2) and Ni(dppe)(SC6H4NH), and the homoleptic compounds Ni(dppe)(EC6H4E′) (E=E′=O, E=E′=S; R=H, Me), were established by a combination of electron impact mass spectrometry (EIMS) and fast atom bombardment (FABMS). The most stable ones were the compounds with homoleptic sulfur ligands.

AB - Mixed chalcogenide complexes of the type Ni(dppe)(SeC6H4S) (dppe=bis(diphenylphosphino)ethane), Ni(dppe)(SC5H3NCO2) and Ni(dppe)(EC5H3NE′) (E=NH, E′=O; E=E′=NH) have been prepared from the reactions of Ni(dppe)Cl2 with the appropriate aryldichalcogen or pyridine-based compound, using Et3N as a base. The relative solution and thermal stabilities of the above compounds, other mixed chalcogen ones, Ni(dppe)(SC6H4O), Ni(dppe)(SC6H4CO2) and Ni(dppe)(SC6H4NH), and the homoleptic compounds Ni(dppe)(EC6H4E′) (E=E′=O, E=E′=S; R=H, Me), were established by a combination of electron impact mass spectrometry (EIMS) and fast atom bombardment (FABMS). The most stable ones were the compounds with homoleptic sulfur ligands.

KW - Crystal structure

KW - Mass spectrometry

KW - Nickel(II) complexes

KW - Stability

UR - https://www.scopus.com/pages/publications/0006988090

U2 - 10.1016/S0277-5387(99)00191-6

DO - 10.1016/S0277-5387(99)00191-6

M3 - Article

AN - SCOPUS:0006988090

SN - 0277-5387

VL - 18

SP - 2803

EP - 2810

JO - Polyhedron

JF - Polyhedron

IS - 21

ER -