Synthesis and synergistic effect of positively charged jute carbon supported AuNPs coated polymer nanocomposite for selective determination of nitrite

Nasrin Sultana; S. M. Abu Nayem; Syed Shaheen Shah; Hyeonggon Kang; Mohammad A. Jafar Mazumder; Abdul Awal; Subrata Chandra Roy; Jamal Uddin; Md Abdul Aziz; A. J.Saleh Ahammad

doi:10.1016/j.mseb.2023.116572

Synthesis and synergistic effect of positively charged jute carbon supported AuNPs coated polymer nanocomposite for selective determination of nitrite

Nasrin Sultana, S. M. Abu Nayem, Syed Shaheen Shah, Hyeonggon Kang, Mohammad A. Jafar Mazumder, Abdul Awal, Subrata Chandra Roy, Jamal Uddin, Md Abdul Aziz^*, A. J.Saleh Ahammad

^*Corresponding author for this work

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9 Scopus citations

Abstract

A nanocomposite with highly dispersed AuNPs coated poly[2-(methacryloyloxy) ethyl] trimethylammonium chloride (PMTC) supported upon jute carbon (AuNPs-PMTC-JC) was prepared in aqueous medium for the selective determination of nitrite (NO₂⁻) ions. Quaternary ammonium groups of PMTC in the nanocomposite results in a positive zeta potential, elevating the electrocatalytic properties of the modified electrode for negatively charged NO₂⁻ ions oxidation. The AuNPs-PMTC-JC composite was characterized using UV–vis, FESEM, TEM, SAED, XRD, EDS, CV and EIS. The LOD (S/N = 3) value for NO₂⁻ determination is 0.16 µM in the linear range of 0.4–706.5 µM based on the i-t current response, while it is 1.28 µM based on CV responses in the wide range of 10–1000 µM. The modified electrode is highly selective for NO₂⁻ ions and shows highly stable, and reproducible results. CV was used to analyze tap water spiked with NO₂⁻ and a recovery close to 100 % was observed.

Original language	English
Article number	116572
Journal	Materials Science and Engineering B: Solid-State Materials for Advanced Technology
Volume	295
DOIs	https://doi.org/10.1016/j.mseb.2023.116572
State	Published - Sep 2023

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Publisher Copyright:
© 2023 Elsevier B.V.

Keywords

AuNPs
Ball milled jute carbon
Electrocatalyst
Nitrite determination
Quaternary ammonium group in PMTC

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1016/j.mseb.2023.116572

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Sultana, N., Abu Nayem, S. M., Shah, S. S., Kang, H., Jafar Mazumder, M. A., Awal, A., Chandra Roy, S., Uddin, J., Aziz, M. A., & Ahammad, A. J. S. (2023). Synthesis and synergistic effect of positively charged jute carbon supported AuNPs coated polymer nanocomposite for selective determination of nitrite. Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 295, Article 116572. https://doi.org/10.1016/j.mseb.2023.116572

@article{20e950204a214e438baf02bd4154fdcb,

title = "Synthesis and synergistic effect of positively charged jute carbon supported AuNPs coated polymer nanocomposite for selective determination of nitrite",

abstract = "A nanocomposite with highly dispersed AuNPs coated poly[2-(methacryloyloxy) ethyl] trimethylammonium chloride (PMTC) supported upon jute carbon (AuNPs-PMTC-JC) was prepared in aqueous medium for the selective determination of nitrite (NO2−) ions. Quaternary ammonium groups of PMTC in the nanocomposite results in a positive zeta potential, elevating the electrocatalytic properties of the modified electrode for negatively charged NO2− ions oxidation. The AuNPs-PMTC-JC composite was characterized using UV–vis, FESEM, TEM, SAED, XRD, EDS, CV and EIS. The LOD (S/N = 3) value for NO2− determination is 0.16 µM in the linear range of 0.4–706.5 µM based on the i-t current response, while it is 1.28 µM based on CV responses in the wide range of 10–1000 µM. The modified electrode is highly selective for NO2− ions and shows highly stable, and reproducible results. CV was used to analyze tap water spiked with NO2− and a recovery close to 100 % was observed.",

keywords = "AuNPs, Ball milled jute carbon, Electrocatalyst, Nitrite determination, Quaternary ammonium group in PMTC",

author = "Nasrin Sultana and {Abu Nayem}, {S. M.} and Shah, {Syed Shaheen} and Hyeonggon Kang and {Jafar Mazumder}, {Mohammad A.} and Abdul Awal and {Chandra Roy}, Subrata and Jamal Uddin and Aziz, {Md Abdul} and Ahammad, {A. J.Saleh}",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier B.V.",

year = "2023",

month = sep,

doi = "10.1016/j.mseb.2023.116572",

language = "English",

volume = "295",

journal = "Materials Science and Engineering B: Solid-State Materials for Advanced Technology",

issn = "0921-5107",

publisher = "Elsevier Ltd.",

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Sultana, N, Abu Nayem, SM, Shah, SS, Kang, H, Jafar Mazumder, MA, Awal, A, Chandra Roy, S, Uddin, J, Aziz, MA & Ahammad, AJS 2023, 'Synthesis and synergistic effect of positively charged jute carbon supported AuNPs coated polymer nanocomposite for selective determination of nitrite', Materials Science and Engineering B: Solid-State Materials for Advanced Technology, vol. 295, 116572. https://doi.org/10.1016/j.mseb.2023.116572

Synthesis and synergistic effect of positively charged jute carbon supported AuNPs coated polymer nanocomposite for selective determination of nitrite. / Sultana, Nasrin; Abu Nayem, S. M.; Shah, Syed Shaheen et al.
In: Materials Science and Engineering B: Solid-State Materials for Advanced Technology, Vol. 295, 116572, 09.2023.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and synergistic effect of positively charged jute carbon supported AuNPs coated polymer nanocomposite for selective determination of nitrite

AU - Sultana, Nasrin

AU - Abu Nayem, S. M.

AU - Shah, Syed Shaheen

AU - Kang, Hyeonggon

AU - Jafar Mazumder, Mohammad A.

AU - Awal, Abdul

AU - Chandra Roy, Subrata

AU - Uddin, Jamal

AU - Aziz, Md Abdul

AU - Ahammad, A. J.Saleh

PY - 2023/9

Y1 - 2023/9

N2 - A nanocomposite with highly dispersed AuNPs coated poly[2-(methacryloyloxy) ethyl] trimethylammonium chloride (PMTC) supported upon jute carbon (AuNPs-PMTC-JC) was prepared in aqueous medium for the selective determination of nitrite (NO2−) ions. Quaternary ammonium groups of PMTC in the nanocomposite results in a positive zeta potential, elevating the electrocatalytic properties of the modified electrode for negatively charged NO2− ions oxidation. The AuNPs-PMTC-JC composite was characterized using UV–vis, FESEM, TEM, SAED, XRD, EDS, CV and EIS. The LOD (S/N = 3) value for NO2− determination is 0.16 µM in the linear range of 0.4–706.5 µM based on the i-t current response, while it is 1.28 µM based on CV responses in the wide range of 10–1000 µM. The modified electrode is highly selective for NO2− ions and shows highly stable, and reproducible results. CV was used to analyze tap water spiked with NO2− and a recovery close to 100 % was observed.

AB - A nanocomposite with highly dispersed AuNPs coated poly[2-(methacryloyloxy) ethyl] trimethylammonium chloride (PMTC) supported upon jute carbon (AuNPs-PMTC-JC) was prepared in aqueous medium for the selective determination of nitrite (NO2−) ions. Quaternary ammonium groups of PMTC in the nanocomposite results in a positive zeta potential, elevating the electrocatalytic properties of the modified electrode for negatively charged NO2− ions oxidation. The AuNPs-PMTC-JC composite was characterized using UV–vis, FESEM, TEM, SAED, XRD, EDS, CV and EIS. The LOD (S/N = 3) value for NO2− determination is 0.16 µM in the linear range of 0.4–706.5 µM based on the i-t current response, while it is 1.28 µM based on CV responses in the wide range of 10–1000 µM. The modified electrode is highly selective for NO2− ions and shows highly stable, and reproducible results. CV was used to analyze tap water spiked with NO2− and a recovery close to 100 % was observed.

KW - AuNPs

KW - Ball milled jute carbon

KW - Electrocatalyst

KW - Nitrite determination

KW - Quaternary ammonium group in PMTC

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U2 - 10.1016/j.mseb.2023.116572

DO - 10.1016/j.mseb.2023.116572

M3 - Article

AN - SCOPUS:85159609808

SN - 0921-5107

VL - 295

JO - Materials Science and Engineering B: Solid-State Materials for Advanced Technology

JF - Materials Science and Engineering B: Solid-State Materials for Advanced Technology

M1 - 116572

ER -

Synthesis and synergistic effect of positively charged jute carbon supported AuNPs coated polymer nanocomposite for selective determination of nitrite

Abstract

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Keywords

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