Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: A new class of metallacarbatranes and a monovalent thallium alkyl compound

Ahmed Al-Harbi; Yi Rong; Gerard Parkin

doi:10.1039/c3dt52163j

Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: A new class of metallacarbatranes and a monovalent thallium alkyl compound

Ahmed Al-Harbi, Yi Rong, Gerard Parkin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Tris(2-pyridonyl)methanes may be synthesized via the reactions of the respective 2-pyridone with CHX₃ (X = Cl, Br) and K₂CO ₃ in the presence of [Buⁿ₄N]Br, followed by acid-catalyzed isomerization with camphorsulfonic acid. These compounds provide access to a new class of alkyl ligands that feature oxygen donors and are capable of forming metallacarbatranes and a monovalent thallium alkyl compound.

Original language	English
Pages (from-to)	14053-14057
Number of pages	5
Journal	Dalton Transactions
Volume	42
Issue number	39
DOIs	https://doi.org/10.1039/c3dt52163j
State	Published - 21 Oct 2013
Externally published	Yes

ASJC Scopus subject areas

Inorganic Chemistry

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title = "Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: A new class of metallacarbatranes and a monovalent thallium alkyl compound",

abstract = "Tris(2-pyridonyl)methanes may be synthesized via the reactions of the respective 2-pyridone with CHX3 (X = Cl, Br) and K2CO 3 in the presence of [Bun4N]Br, followed by acid-catalyzed isomerization with camphorsulfonic acid. These compounds provide access to a new class of alkyl ligands that feature oxygen donors and are capable of forming metallacarbatranes and a monovalent thallium alkyl compound.",

author = "Ahmed Al-Harbi and Yi Rong and Gerard Parkin",

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T1 - Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium

T2 - A new class of metallacarbatranes and a monovalent thallium alkyl compound

AU - Al-Harbi, Ahmed

AU - Rong, Yi

AU - Parkin, Gerard

PY - 2013/10/21

Y1 - 2013/10/21

N2 - Tris(2-pyridonyl)methanes may be synthesized via the reactions of the respective 2-pyridone with CHX3 (X = Cl, Br) and K2CO 3 in the presence of [Bun4N]Br, followed by acid-catalyzed isomerization with camphorsulfonic acid. These compounds provide access to a new class of alkyl ligands that feature oxygen donors and are capable of forming metallacarbatranes and a monovalent thallium alkyl compound.

AB - Tris(2-pyridonyl)methanes may be synthesized via the reactions of the respective 2-pyridone with CHX3 (X = Cl, Br) and K2CO 3 in the presence of [Bun4N]Br, followed by acid-catalyzed isomerization with camphorsulfonic acid. These compounds provide access to a new class of alkyl ligands that feature oxygen donors and are capable of forming metallacarbatranes and a monovalent thallium alkyl compound.

UR - https://www.scopus.com/pages/publications/84884221684

U2 - 10.1039/c3dt52163j

DO - 10.1039/c3dt52163j

M3 - Article

AN - SCOPUS:84884221684

SN - 1477-9226

VL - 42

SP - 14053

EP - 14057

JO - Dalton Transactions

JF - Dalton Transactions

IS - 39

ER -

Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: A new class of metallacarbatranes and a monovalent thallium alkyl compound

Abstract

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