TY - JOUR
T1 - Synthesis and structural characterization of bis and tris(2-mercapto-1- methylbenzimidazolyl)hydroborato complexes
T2 - Benzannulation promotes κ3-coordination
AU - Al-Harbi, Ahmed
AU - Rong, Yi
AU - Parkin, Gerard
PY - 2013/8/21
Y1 - 2013/8/21
N2 - The benzannulated bis and tris(mercaptoimidazolyl)borohydride compounds, [BmMeBenz]Na and [TmMeBenz]Na, have been synthesized via the reactions of NaBH4 with two and three equivalents of 1-methyl-1,3-dihydro-2H-benzimidazole-2-thione, respectively. X-ray diffraction studies on the THF adducts, {μ-[BmMeBenz]Na(THF)2} 2 and {[TmMeBenz]Na}2(μ-THF)3, indicate that both compounds are dinuclear but differ according to the nature of the bridging ligand. Specifically, {μ-[BmMeBenz]Na(THF) 2}2 possesses bridging [BmMeBenz] ligands and terminal THF ligands, while {[TmMeBenz]Na}2(μ-THF) 3 possesses terminal [TmMeBenz] ligands and bridging THF ligands. The tris(mercaptoimidazolyl)borohydride ligand of {[Tm MeBenz]Na}2(μ-THF)3 coordinates in a κ3-manner, which is in marked contrast to the κ2-, κ1- and κ0-modes that have been reported for various [TmMe]Na derivatives. Density functional theory (DFT) geometry optimization calculations of the anions [TmMeBenz]- and [TmMe]- in the gas phase indicate that the conformation required for κ3-S 3 coordination, i.e. one in which the three sulfur donors point away from the B-H group, is relatively more stable for [TmMeBenz] - than for [TmMe]-, and thus provides a rationalization for the observation that benzannulation enables κ3-coordination of tris(mercaptoimidazolyl)borohydride ligand in {[TmMeBenz]Na}2(μ-THF)3. Furthermore, comparison of the molecular structure and IR spectroscopic properties of [TmMeBenz]Re(CO)3 with those of [TmMe]Re(CO) 3 indicates that benzannulation reduces the electron donating properties of the ligand, but has little effect on its steric properties. {μ-[BmMeBenz]Na(THF)2}2 and {[Tm MeBenz]Na}2(μ-THF)3 react with [Me 3PCuCl]4 to give [BmMeBenz]CuPMe3 and [TmMeBenz]CuPMe3, the first pair of structurally related bis and tris(mercaptoimidazolyl)hydroborato copper(i) compounds.
AB - The benzannulated bis and tris(mercaptoimidazolyl)borohydride compounds, [BmMeBenz]Na and [TmMeBenz]Na, have been synthesized via the reactions of NaBH4 with two and three equivalents of 1-methyl-1,3-dihydro-2H-benzimidazole-2-thione, respectively. X-ray diffraction studies on the THF adducts, {μ-[BmMeBenz]Na(THF)2} 2 and {[TmMeBenz]Na}2(μ-THF)3, indicate that both compounds are dinuclear but differ according to the nature of the bridging ligand. Specifically, {μ-[BmMeBenz]Na(THF) 2}2 possesses bridging [BmMeBenz] ligands and terminal THF ligands, while {[TmMeBenz]Na}2(μ-THF) 3 possesses terminal [TmMeBenz] ligands and bridging THF ligands. The tris(mercaptoimidazolyl)borohydride ligand of {[Tm MeBenz]Na}2(μ-THF)3 coordinates in a κ3-manner, which is in marked contrast to the κ2-, κ1- and κ0-modes that have been reported for various [TmMe]Na derivatives. Density functional theory (DFT) geometry optimization calculations of the anions [TmMeBenz]- and [TmMe]- in the gas phase indicate that the conformation required for κ3-S 3 coordination, i.e. one in which the three sulfur donors point away from the B-H group, is relatively more stable for [TmMeBenz] - than for [TmMe]-, and thus provides a rationalization for the observation that benzannulation enables κ3-coordination of tris(mercaptoimidazolyl)borohydride ligand in {[TmMeBenz]Na}2(μ-THF)3. Furthermore, comparison of the molecular structure and IR spectroscopic properties of [TmMeBenz]Re(CO)3 with those of [TmMe]Re(CO) 3 indicates that benzannulation reduces the electron donating properties of the ligand, but has little effect on its steric properties. {μ-[BmMeBenz]Na(THF)2}2 and {[Tm MeBenz]Na}2(μ-THF)3 react with [Me 3PCuCl]4 to give [BmMeBenz]CuPMe3 and [TmMeBenz]CuPMe3, the first pair of structurally related bis and tris(mercaptoimidazolyl)hydroborato copper(i) compounds.
UR - https://www.scopus.com/pages/publications/84880643578
U2 - 10.1039/c3dt51092a
DO - 10.1039/c3dt51092a
M3 - Article
C2 - 23801309
AN - SCOPUS:84880643578
SN - 1477-9226
VL - 42
SP - 11117
EP - 11127
JO - Dalton Transactions
JF - Dalton Transactions
IS - 31
ER -