Synthesis and spectroscopic studies of gold(I) thiocyanate with imidazolidine-2-thione and its derivatives

Anvarhusein A. Isab

doi:10.1016/S0277-5387(00)80543-4

Synthesis and spectroscopic studies of gold(I) thiocyanate with imidazolidine-2-thione and its derivatives

Anvarhusein A. Isab^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The reaction of ammonium gold(III) thiocyanate with imidazolidine-2-thione (Imt) and its N- and N,N'-disubstituted derivatives yields complexes of stoichiometry LAu^I-SCN (where L = Imt and its derivatives). However, a six-membered heterocyclic ligand, 1,3-diazinane-2-thione (Diaz), and its N-substituted derivative yields complexes of the type L'₂Au^ISCN (where L' = Diaz and its derivative). These complexes are characterized by elemental analysis, IR and ¹³C NMR spectroscopy.

Original language	English
Pages (from-to)	2823-2827
Number of pages	5
Journal	Polyhedron
Volume	8
Issue number	23
DOIs	https://doi.org/10.1016/S0277-5387(00)80543-4
State	Published - 1989

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0277-5387(00)80543-4

Cite this

@article{e321faf5e4144430a01e51ea3984045f,

title = "Synthesis and spectroscopic studies of gold(I) thiocyanate with imidazolidine-2-thione and its derivatives",

abstract = "The reaction of ammonium gold(III) thiocyanate with imidazolidine-2-thione (Imt) and its N- and N,N'-disubstituted derivatives yields complexes of stoichiometry LAuI-SCN (where L = Imt and its derivatives). However, a six-membered heterocyclic ligand, 1,3-diazinane-2-thione (Diaz), and its N-substituted derivative yields complexes of the type L'2AuISCN (where L' = Diaz and its derivative). These complexes are characterized by elemental analysis, IR and 13C NMR spectroscopy.",

author = "Isab, \{Anvarhusein A.\}",

year = "1989",

doi = "10.1016/S0277-5387(00)80543-4",

language = "English",

volume = "8",

pages = "2823--2827",

journal = "Polyhedron",

issn = "0277-5387",

number = "23",

}

TY - JOUR

T1 - Synthesis and spectroscopic studies of gold(I) thiocyanate with imidazolidine-2-thione and its derivatives

AU - Isab, Anvarhusein A.

PY - 1989

Y1 - 1989

N2 - The reaction of ammonium gold(III) thiocyanate with imidazolidine-2-thione (Imt) and its N- and N,N'-disubstituted derivatives yields complexes of stoichiometry LAuI-SCN (where L = Imt and its derivatives). However, a six-membered heterocyclic ligand, 1,3-diazinane-2-thione (Diaz), and its N-substituted derivative yields complexes of the type L'2AuISCN (where L' = Diaz and its derivative). These complexes are characterized by elemental analysis, IR and 13C NMR spectroscopy.

AB - The reaction of ammonium gold(III) thiocyanate with imidazolidine-2-thione (Imt) and its N- and N,N'-disubstituted derivatives yields complexes of stoichiometry LAuI-SCN (where L = Imt and its derivatives). However, a six-membered heterocyclic ligand, 1,3-diazinane-2-thione (Diaz), and its N-substituted derivative yields complexes of the type L'2AuISCN (where L' = Diaz and its derivative). These complexes are characterized by elemental analysis, IR and 13C NMR spectroscopy.

UR - https://www.scopus.com/pages/publications/0347769038

U2 - 10.1016/S0277-5387(00)80543-4

DO - 10.1016/S0277-5387(00)80543-4

M3 - Article

AN - SCOPUS:0347769038

SN - 0277-5387

VL - 8

SP - 2823

EP - 2827

JO - Polyhedron

JF - Polyhedron

IS - 23

ER -

Synthesis and spectroscopic studies of gold(I) thiocyanate with imidazolidine-2-thione and its derivatives

Abstract

ASJC Scopus subject areas

Access to Document

Fingerprint

Cite this