Synthesis and solution properties of a new poly(electrolyte-zwitterion)

Mohammad A.J. Mazumder; Yunusa Umar; Sk Asrof Ali

doi:10.1016/j.polymer.2003.10.060

Synthesis and solution properties of a new poly(electrolyte-zwitterion)

Mohammad A.J. Mazumder, Yunusa Umar, Sk Asrof Ali^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A novel electrolytic-zwitterionic (EZ) monomer, Sodium N-(3-sulfopropyl)-3-(N,N-diallylamino)propanesulfonate, on homopolymerization in aqueous solution using tert-butylhydroperoxide, afforded the poly(electrolyte-zwitterions) (PEZ). The copolymer of the above monomer and sulfur dioxide was also synthesized in excellent yield. The EZ monomer as well as the PEZs contains structural features common to both polyzwitterions and conventional polyelectrolytes. The solution properties of these polymers were studied in detail. The PEZ, as the name implies, possess dual type of structural character and it is the electrolytic portion of the structure that dictates the solubility and viscosity behavior of the polymers.

Original language	English
Pages (from-to)	125-132
Number of pages	8
Journal	Polymer
Volume	45
Issue number	1
DOIs	https://doi.org/10.1016/j.polymer.2003.10.060
State	Published - 1 Jan 2004

Keywords

Polyelectrolytes
Polysulfobetaines
Polyzwitterions

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1016/j.polymer.2003.10.060

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title = "Synthesis and solution properties of a new poly(electrolyte-zwitterion)",

abstract = "A novel electrolytic-zwitterionic (EZ) monomer, Sodium N-(3-sulfopropyl)-3-(N,N-diallylamino)propanesulfonate, on homopolymerization in aqueous solution using tert-butylhydroperoxide, afforded the poly(electrolyte-zwitterions) (PEZ). The copolymer of the above monomer and sulfur dioxide was also synthesized in excellent yield. The EZ monomer as well as the PEZs contains structural features common to both polyzwitterions and conventional polyelectrolytes. The solution properties of these polymers were studied in detail. The PEZ, as the name implies, possess dual type of structural character and it is the electrolytic portion of the structure that dictates the solubility and viscosity behavior of the polymers.",

keywords = "Polyelectrolytes, Polysulfobetaines, Polyzwitterions",

author = "Mazumder, \{Mohammad A.J.\} and Yunusa Umar and Ali, \{Sk Asrof\}",

year = "2004",

month = jan,

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doi = "10.1016/j.polymer.2003.10.060",

language = "English",

volume = "45",

pages = "125--132",

journal = "Polymer",

issn = "0032-3861",

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TY - JOUR

T1 - Synthesis and solution properties of a new poly(electrolyte-zwitterion)

AU - Mazumder, Mohammad A.J.

AU - Umar, Yunusa

AU - Ali, Sk Asrof

PY - 2004/1/1

Y1 - 2004/1/1

N2 - A novel electrolytic-zwitterionic (EZ) monomer, Sodium N-(3-sulfopropyl)-3-(N,N-diallylamino)propanesulfonate, on homopolymerization in aqueous solution using tert-butylhydroperoxide, afforded the poly(electrolyte-zwitterions) (PEZ). The copolymer of the above monomer and sulfur dioxide was also synthesized in excellent yield. The EZ monomer as well as the PEZs contains structural features common to both polyzwitterions and conventional polyelectrolytes. The solution properties of these polymers were studied in detail. The PEZ, as the name implies, possess dual type of structural character and it is the electrolytic portion of the structure that dictates the solubility and viscosity behavior of the polymers.

AB - A novel electrolytic-zwitterionic (EZ) monomer, Sodium N-(3-sulfopropyl)-3-(N,N-diallylamino)propanesulfonate, on homopolymerization in aqueous solution using tert-butylhydroperoxide, afforded the poly(electrolyte-zwitterions) (PEZ). The copolymer of the above monomer and sulfur dioxide was also synthesized in excellent yield. The EZ monomer as well as the PEZs contains structural features common to both polyzwitterions and conventional polyelectrolytes. The solution properties of these polymers were studied in detail. The PEZ, as the name implies, possess dual type of structural character and it is the electrolytic portion of the structure that dictates the solubility and viscosity behavior of the polymers.

KW - Polyelectrolytes

KW - Polysulfobetaines

KW - Polyzwitterions

UR - https://www.scopus.com/pages/publications/0348049617

U2 - 10.1016/j.polymer.2003.10.060

DO - 10.1016/j.polymer.2003.10.060

M3 - Article

AN - SCOPUS:0348049617

SN - 0032-3861

VL - 45

SP - 125

EP - 132

JO - Polymer

JF - Polymer

IS - 1

ER -

Synthesis and solution properties of a new poly(electrolyte-zwitterion)

Abstract

Keywords

ASJC Scopus subject areas

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