Synthesis and photophysical properties of tetra and pentaarylated fluorobenzenes

Aneela Maalik; Muhammad Sharif; Naeem Abbas; Anke Spannenberg; Alexander Villinger; Peter Langer

doi:10.1016/j.tet.2016.01.009

Synthesis and photophysical properties of tetra and pentaarylated fluorobenzenes

Aneela Maalik, Muhammad Sharif, Naeem Abbas, Anke Spannenberg, Alexander Villinger, Peter Langer^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Novel difluoro-tetraaryl and monofluoro-pentaarylbenzenes were prepared by palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of novel 1,2- and 1,4-difluorotetraiodobenzene and of 1-fluoropentaiodobenzene. These Suzuki-Miyaura reactions allowed a convenient synthesis of fluoro-substituted aryl benzenes. The photophysical properties (absorption and fluorescence) of the products have been studied.

Original language	English
Pages (from-to)	1076-1082
Number of pages	7
Journal	Tetrahedron
Volume	72
Issue number	8
DOIs	https://doi.org/10.1016/j.tet.2016.01.009
State	Published - 2016
Externally published	Yes

Bibliographical note

Publisher Copyright:
© 2016 Elsevier Ltd. All rights reserved.

Keywords

Arenes
Catalysis
Cross-coupling
Fluorine
Palladium
Suzuki-Miyaura reaction

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tet.2016.01.009

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title = "Synthesis and photophysical properties of tetra and pentaarylated fluorobenzenes",

abstract = "Novel difluoro-tetraaryl and monofluoro-pentaarylbenzenes were prepared by palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of novel 1,2- and 1,4-difluorotetraiodobenzene and of 1-fluoropentaiodobenzene. These Suzuki-Miyaura reactions allowed a convenient synthesis of fluoro-substituted aryl benzenes. The photophysical properties (absorption and fluorescence) of the products have been studied.",

keywords = "Arenes, Catalysis, Cross-coupling, Fluorine, Palladium, Suzuki-Miyaura reaction",

author = "Aneela Maalik and Muhammad Sharif and Naeem Abbas and Anke Spannenberg and Alexander Villinger and Peter Langer",

year = "2016",

doi = "10.1016/j.tet.2016.01.009",

language = "English",

volume = "72",

pages = "1076--1082",

journal = "Tetrahedron",

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TY - JOUR

T1 - Synthesis and photophysical properties of tetra and pentaarylated fluorobenzenes

AU - Maalik, Aneela

AU - Sharif, Muhammad

AU - Abbas, Naeem

AU - Spannenberg, Anke

AU - Villinger, Alexander

AU - Langer, Peter

PY - 2016

Y1 - 2016

N2 - Novel difluoro-tetraaryl and monofluoro-pentaarylbenzenes were prepared by palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of novel 1,2- and 1,4-difluorotetraiodobenzene and of 1-fluoropentaiodobenzene. These Suzuki-Miyaura reactions allowed a convenient synthesis of fluoro-substituted aryl benzenes. The photophysical properties (absorption and fluorescence) of the products have been studied.

AB - Novel difluoro-tetraaryl and monofluoro-pentaarylbenzenes were prepared by palladium-catalyzed Suzuki-Miyaura cross-coupling reactions of novel 1,2- and 1,4-difluorotetraiodobenzene and of 1-fluoropentaiodobenzene. These Suzuki-Miyaura reactions allowed a convenient synthesis of fluoro-substituted aryl benzenes. The photophysical properties (absorption and fluorescence) of the products have been studied.

KW - Arenes

KW - Catalysis

KW - Cross-coupling

KW - Fluorine

KW - Palladium

KW - Suzuki-Miyaura reaction

UR - https://www.scopus.com/pages/publications/84955326787

U2 - 10.1016/j.tet.2016.01.009

DO - 10.1016/j.tet.2016.01.009

M3 - Article

AN - SCOPUS:84955326787

SN - 0040-4020

VL - 72

SP - 1076

EP - 1082

JO - Tetrahedron

JF - Tetrahedron

IS - 8

ER -

Synthesis and photophysical properties of tetra and pentaarylated fluorobenzenes

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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