TY - JOUR
T1 - Synthesis and crystal structures of cadmium iodide complexes of N,N'-diethylthiourea and 1,3-diazinane-2-thione
AU - Ahmad, Saeed
AU - Amir, Quemars
AU - Naz, Ghazala
AU - Fazal, Atif
AU - Fettouhi, Mohammed
AU - Isab, Anvarhusein A.
AU - Rüffer, Tobias
AU - Lang, Heinrich
PY - 2012/6
Y1 - 2012/6
N2 - Two cadmium(II) iodide complexes, [Cd(Detu) 2 I 2] (1) and [Cd(Diaz) 2I 2] (2) (Detu = N,N'-diethylthiourea; Diaz = 1,3-diazinane-2-thione) have been prepared and their structures been determined by X-ray crystallography. The crystal structures show that both complexes are mononuclear with the cadmiumatomcoordinated to two iodide ions and two thione ligands adopting a distorted tetrahedral geometry. Whereas, 2 exists as discretemonomeric species, the structure of 1 consists of three crystallographically independent molecules. The complexeswere also characterized by IR andNMR ( 1H and 13C) spectroscopy.
AB - Two cadmium(II) iodide complexes, [Cd(Detu) 2 I 2] (1) and [Cd(Diaz) 2I 2] (2) (Detu = N,N'-diethylthiourea; Diaz = 1,3-diazinane-2-thione) have been prepared and their structures been determined by X-ray crystallography. The crystal structures show that both complexes are mononuclear with the cadmiumatomcoordinated to two iodide ions and two thione ligands adopting a distorted tetrahedral geometry. Whereas, 2 exists as discretemonomeric species, the structure of 1 consists of three crystallographically independent molecules. The complexeswere also characterized by IR andNMR ( 1H and 13C) spectroscopy.
KW - 1,3-Diazinane-2-thione
KW - Cadmium(II) iodide
KW - Crystal structures
KW - N
KW - N'-Diethylthiourea
UR - https://www.scopus.com/pages/publications/84864665696
U2 - 10.1007/s10870-012-0291-z
DO - 10.1007/s10870-012-0291-z
M3 - Article
AN - SCOPUS:84864665696
SN - 1074-1542
VL - 42
SP - 615
EP - 620
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 6
ER -