Synthesis and crystal structure of mercury complex of saccharin with pyridine [Hg(sac)(2)(py)(2)]

Zaki Shaker Abdallah Seddigi, A Banu, GMG Hossain

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Abstract

The structure of the mercury saccharinate complex with pyridine has been studied by IR and single crystal X-ray diffraction methods. The compound was,crystallized in the monoclinic space group P2(1)/n with unit cell dimensions of a = 9.8114(2) b = 21.2444(3), c = 12.0557(5), 8 = 97.8431(8)degrees, Z = 4, and the crystal structure was solved to an R value of 0.0425 for 5700 observations. The Hg atom has slightly distorted tetrahedral configuration with four nitrogen (N) atoms from two pyridine and two saccharinate anions in the complex.
Original languageEnglish
JournalArabian Journal for Science and Engineering
StatePublished - 2007

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