Synthesis and crystal structure of bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II)

Saira Shahzadi; Saqib Ali; Amin Badshah; Farkhanda Shaheen; Fiaz Ahmed; Mohammed Fettouhi

doi:10.1007/s10870-006-9101-9

Synthesis and crystal structure of bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II)

Saira Shahzadi
, Saqib Ali
, Amin Badshah
, Farkhanda Shaheen
, Fiaz Ahmed
, Mohammed Fettouhi^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The complex bis(4-methylpiperidine-dithiocarbamato-S,)-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P2₁/c space group with the crystal cell parameters a=8.6491(8)Å, b=18.7305(16)Å, c=11.9933(10)Å, β=107.074(1)°, V=1857.3(3)Å³ and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS₂ moieties.

Original language	English
Pages (from-to)	567-570
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	36
Issue number	9
DOIs	https://doi.org/10.1007/s10870-006-9101-9
State	Published - Sep 2006

Bibliographical note

Funding Information:
This work was partly supported by King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia. SA is thankful to Quaid-i-Azam University, Islamabad, Pakistan for financial support.

Keywords

Crystal structure.
Dithiocarbamate
Palladium(II) complex

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics

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10.1007/s10870-006-9101-9

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@article{658b0ddfaa894f02b2df3dfe2c9a98f0,

title = "Synthesis and crystal structure of bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II)",

abstract = "The complex bis(4-methylpiperidine-dithiocarbamato-S,)-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P21/c space group with the crystal cell parameters a=8.6491(8){\AA}, b=18.7305(16){\AA}, c=11.9933(10){\AA}, β=107.074(1)°, V=1857.3(3){\AA}3 and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS2 moieties.",

keywords = "Crystal structure., Dithiocarbamate, Palladium(II) complex",

author = "Saira Shahzadi and Saqib Ali and Amin Badshah and Farkhanda Shaheen and Fiaz Ahmed and Mohammed Fettouhi",

note = "Funding Information: This work was partly supported by King Fahd University of Petroleum \& Minerals, Dhahran, Saudi Arabia. SA is thankful to Quaid-i-Azam University, Islamabad, Pakistan for financial support.",

year = "2006",

month = sep,

doi = "10.1007/s10870-006-9101-9",

language = "English",

volume = "36",

pages = "567--570",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

number = "9",

}

TY - JOUR

T1 - Synthesis and crystal structure of bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II)

AU - Shahzadi, Saira

AU - Ali, Saqib

AU - Badshah, Amin

AU - Shaheen, Farkhanda

AU - Ahmed, Fiaz

AU - Fettouhi, Mohammed

N1 - Funding Information: This work was partly supported by King Fahd University of Petroleum & Minerals, Dhahran, Saudi Arabia. SA is thankful to Quaid-i-Azam University, Islamabad, Pakistan for financial support.

PY - 2006/9

Y1 - 2006/9

N2 - The complex bis(4-methylpiperidine-dithiocarbamato-S,)-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P21/c space group with the crystal cell parameters a=8.6491(8)Å, b=18.7305(16)Å, c=11.9933(10)Å, β=107.074(1)°, V=1857.3(3)Å3 and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS2 moieties.

AB - The complex bis(4-methylpiperidine-dithiocarbamato-S,)-palladium(II) was synthesized by the reaction of 4-methyl-1-piperidine dithiocarbamic acid with palladium(II) chloride. Its structure was determined by X-ray crystal diffraction analysis. It crystallizes in the monoclinic P21/c space group with the crystal cell parameters a=8.6491(8)Å, b=18.7305(16)Å, c=11.9933(10)Å, β=107.074(1)°, V=1857.3(3)Å3 and Z=4. The palladium (II) ion is bonded to four sulfur atoms, belonging to two dithiocarbamate ligands, in a distorted square planar geometry. The X-ray data suggest a pronounced electronic delocalization in the two NCS2 moieties.

KW - Crystal structure.

KW - Dithiocarbamate

KW - Palladium(II) complex

UR - https://www.scopus.com/pages/publications/33749266695

U2 - 10.1007/s10870-006-9101-9

DO - 10.1007/s10870-006-9101-9

M3 - Article

AN - SCOPUS:33749266695

SN - 1074-1542

VL - 36

SP - 567

EP - 570

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 9

ER -

Synthesis and crystal structure of bis(4-methylpiperidine-dithiocarbamato-S,S′)-palladium(II)

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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