Synthesis and crystal structure of a novel self-assembled 2D coordination polymer of chloridobis(imidazolidine-2-thione)thiocyanato dicopper(I)

Fouzia Noreen; Tobias Rüffer; Heinrich Lang; Anvarhusein A. Isab; Saeed Ahmad

doi:10.1007/s10870-008-9387-x

Synthesis and crystal structure of a novel self-assembled 2D coordination polymer of chloridobis(imidazolidine-2-thione)thiocyanato dicopper(I)

Fouzia Noreen, Tobias Rüffer, Heinrich Lang, Anvarhusein A. Isab, Saeed Ahmad^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A copper(I) complex, poly(chloridobis(imidazolidine-2-thione)thiocyanato dicopper(I)), [Cu₂(Imt)₂(SCN)Cl] _n (1) (Imt = Imidazolidine-2-thione) has been prepared by the reaction of CuCl₂ with imidazolidine-2-thione and potassium thiocyanate in the ratio of 1:1:2. Compound 1 crystallizes in the monoclinic space group P2₁/a in the form of a coordination polymer, consisting of 2D layers. The solid-state structure is composed of dinuclear units having each copper(I) ion tetrahedrally coordinated. These units aggregate through bridging Imt and thiocyanate leading to a supramolecular 2D-network.

Original language	English
Pages (from-to)	765-768
Number of pages	4
Journal	Journal of Chemical Crystallography
Volume	38
Issue number	10
DOIs	https://doi.org/10.1007/s10870-008-9387-x
State	Published - Oct 2008

Bibliographical note

Funding Information:
Acknowledgements Financial support from the UET Research Center and Pakistan Council for Science and Technology Islamabad, Pakistan, and from KFUPM Research Committee, Dhahran, Saudi Arabia is gratefully acknowledged.

Keywords

Copper(I)
Crystal structure
Imidazolidine-2-thione
Thiocyanate

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics

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10.1007/s10870-008-9387-x

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title = "Synthesis and crystal structure of a novel self-assembled 2D coordination polymer of chloridobis(imidazolidine-2-thione)thiocyanato dicopper(I)",

abstract = "A copper(I) complex, poly(chloridobis(imidazolidine-2-thione)thiocyanato dicopper(I)), [Cu2(Imt)2(SCN)Cl] n (1) (Imt = Imidazolidine-2-thione) has been prepared by the reaction of CuCl2 with imidazolidine-2-thione and potassium thiocyanate in the ratio of 1:1:2. Compound 1 crystallizes in the monoclinic space group P21/a in the form of a coordination polymer, consisting of 2D layers. The solid-state structure is composed of dinuclear units having each copper(I) ion tetrahedrally coordinated. These units aggregate through bridging Imt and thiocyanate leading to a supramolecular 2D-network.",

keywords = "Copper(I), Crystal structure, Imidazolidine-2-thione, Thiocyanate",

author = "Fouzia Noreen and Tobias R{\"u}ffer and Heinrich Lang and Isab, \{Anvarhusein A.\} and Saeed Ahmad",

note = "Funding Information: Acknowledgements Financial support from the UET Research Center and Pakistan Council for Science and Technology Islamabad, Pakistan, and from KFUPM Research Committee, Dhahran, Saudi Arabia is gratefully acknowledged.",

year = "2008",

month = oct,

doi = "10.1007/s10870-008-9387-x",

language = "English",

volume = "38",

pages = "765--768",

journal = "Journal of Chemical Crystallography",

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TY - JOUR

T1 - Synthesis and crystal structure of a novel self-assembled 2D coordination polymer of chloridobis(imidazolidine-2-thione)thiocyanato dicopper(I)

AU - Noreen, Fouzia

AU - Rüffer, Tobias

AU - Lang, Heinrich

AU - Isab, Anvarhusein A.

AU - Ahmad, Saeed

N1 - Funding Information: Acknowledgements Financial support from the UET Research Center and Pakistan Council for Science and Technology Islamabad, Pakistan, and from KFUPM Research Committee, Dhahran, Saudi Arabia is gratefully acknowledged.

PY - 2008/10

Y1 - 2008/10

N2 - A copper(I) complex, poly(chloridobis(imidazolidine-2-thione)thiocyanato dicopper(I)), [Cu2(Imt)2(SCN)Cl] n (1) (Imt = Imidazolidine-2-thione) has been prepared by the reaction of CuCl2 with imidazolidine-2-thione and potassium thiocyanate in the ratio of 1:1:2. Compound 1 crystallizes in the monoclinic space group P21/a in the form of a coordination polymer, consisting of 2D layers. The solid-state structure is composed of dinuclear units having each copper(I) ion tetrahedrally coordinated. These units aggregate through bridging Imt and thiocyanate leading to a supramolecular 2D-network.

AB - A copper(I) complex, poly(chloridobis(imidazolidine-2-thione)thiocyanato dicopper(I)), [Cu2(Imt)2(SCN)Cl] n (1) (Imt = Imidazolidine-2-thione) has been prepared by the reaction of CuCl2 with imidazolidine-2-thione and potassium thiocyanate in the ratio of 1:1:2. Compound 1 crystallizes in the monoclinic space group P21/a in the form of a coordination polymer, consisting of 2D layers. The solid-state structure is composed of dinuclear units having each copper(I) ion tetrahedrally coordinated. These units aggregate through bridging Imt and thiocyanate leading to a supramolecular 2D-network.

KW - Copper(I)

KW - Crystal structure

KW - Imidazolidine-2-thione

KW - Thiocyanate

UR - https://www.scopus.com/pages/publications/50249172213

U2 - 10.1007/s10870-008-9387-x

DO - 10.1007/s10870-008-9387-x

M3 - Article

AN - SCOPUS:50249172213

SN - 1074-1542

VL - 38

SP - 765

EP - 768

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 10

ER -

Synthesis and crystal structure of a novel self-assembled 2D coordination polymer of chloridobis(imidazolidine-2-thione)thiocyanato dicopper(I)

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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