Synthesis and characterization of waterborne polyurethane/clay Nanocomposite - Effect on adhesive strength

Mohammad Mizanur Rahman; Hye Jin Yoo; Chung Jung Mi; Han Do Kim

doi:10.1002/masy.200750341

Synthesis and characterization of waterborne polyurethane/clay Nanocomposite - Effect on adhesive strength

Mohammad Mizanur Rahman
, Hye Jin Yoo
, Chung Jung Mi
, Han Do Kim^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Waterborne polyurethane (WBPU)/clay nanocomposites were synthesized using prepolymer process with different clay content (0-5 wt%) of organoclay cioisite 15A. The optimum dispersion temperature of clay in polyot was found to be 8o°C at 3 hours. The XRD confirmed the exfoliation dispersion of clay by polyol in WBPU/clay nanocomposite. IR and ¹H-NMR spectroscopy confirmed the unreacted condition of clay component. Particle size of the WBPU/clay nanocomposite dispersion was increased with increasing of clay concentration. Water swelling was decreased with increasing of clay up to the optimum content (2 wt %) and then leveled off. The thermal stability, mechanical property and adhesive strength were increased with increasing clay content up to 2 wt% to reach its maximum value.

Original language	English
Pages (from-to)	251-258
Number of pages	8
Journal	Macromolecular Symposia
Volume	249-250
DOIs	https://doi.org/10.1002/masy.200750341
State	Published - 2007
Externally published	Yes

Keywords

Adhesion
Clay
Nanocomposites
Polyurethanes
Waterborne

ASJC Scopus subject areas

Condensed Matter Physics
Organic Chemistry
Polymers and Plastics
Materials Chemistry

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10.1002/masy.200750341

Cite this

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title = "Synthesis and characterization of waterborne polyurethane/clay Nanocomposite - Effect on adhesive strength",

abstract = "Waterborne polyurethane (WBPU)/clay nanocomposites were synthesized using prepolymer process with different clay content (0-5 wt\%) of organoclay cioisite 15A. The optimum dispersion temperature of clay in polyot was found to be 8o°C at 3 hours. The XRD confirmed the exfoliation dispersion of clay by polyol in WBPU/clay nanocomposite. IR and 1H-NMR spectroscopy confirmed the unreacted condition of clay component. Particle size of the WBPU/clay nanocomposite dispersion was increased with increasing of clay concentration. Water swelling was decreased with increasing of clay up to the optimum content (2 wt \%) and then leveled off. The thermal stability, mechanical property and adhesive strength were increased with increasing clay content up to 2 wt\% to reach its maximum value.",

keywords = "Adhesion, Clay, Nanocomposites, Polyurethanes, Waterborne",

author = "Rahman, \{Mohammad Mizanur\} and Yoo, \{Hye Jin\} and Mi, \{Chung Jung\} and Kim, \{Han Do\}",

year = "2007",

doi = "10.1002/masy.200750341",

language = "English",

volume = "249-250",

pages = "251--258",

journal = "Macromolecular Symposia",

issn = "1022-1360",

publisher = "Wiley-VCH Verlag",

}

TY - JOUR

T1 - Synthesis and characterization of waterborne polyurethane/clay Nanocomposite - Effect on adhesive strength

AU - Rahman, Mohammad Mizanur

AU - Yoo, Hye Jin

AU - Mi, Chung Jung

AU - Kim, Han Do

PY - 2007

Y1 - 2007

N2 - Waterborne polyurethane (WBPU)/clay nanocomposites were synthesized using prepolymer process with different clay content (0-5 wt%) of organoclay cioisite 15A. The optimum dispersion temperature of clay in polyot was found to be 8o°C at 3 hours. The XRD confirmed the exfoliation dispersion of clay by polyol in WBPU/clay nanocomposite. IR and 1H-NMR spectroscopy confirmed the unreacted condition of clay component. Particle size of the WBPU/clay nanocomposite dispersion was increased with increasing of clay concentration. Water swelling was decreased with increasing of clay up to the optimum content (2 wt %) and then leveled off. The thermal stability, mechanical property and adhesive strength were increased with increasing clay content up to 2 wt% to reach its maximum value.

AB - Waterborne polyurethane (WBPU)/clay nanocomposites were synthesized using prepolymer process with different clay content (0-5 wt%) of organoclay cioisite 15A. The optimum dispersion temperature of clay in polyot was found to be 8o°C at 3 hours. The XRD confirmed the exfoliation dispersion of clay by polyol in WBPU/clay nanocomposite. IR and 1H-NMR spectroscopy confirmed the unreacted condition of clay component. Particle size of the WBPU/clay nanocomposite dispersion was increased with increasing of clay concentration. Water swelling was decreased with increasing of clay up to the optimum content (2 wt %) and then leveled off. The thermal stability, mechanical property and adhesive strength were increased with increasing clay content up to 2 wt% to reach its maximum value.

KW - Adhesion

KW - Clay

KW - Nanocomposites

KW - Polyurethanes

KW - Waterborne

UR - https://www.scopus.com/pages/publications/34547174726

U2 - 10.1002/masy.200750341

DO - 10.1002/masy.200750341

M3 - Article

AN - SCOPUS:34547174726

SN - 1022-1360

VL - 249-250

SP - 251

EP - 258

JO - Macromolecular Symposia

JF - Macromolecular Symposia

ER -

Synthesis and characterization of waterborne polyurethane/clay Nanocomposite - Effect on adhesive strength

Abstract

Keywords

ASJC Scopus subject areas

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