Synthesis and characterization of carbon and carbon-nitrogen doped black tio₂ nanomaterials and their application in sonophotocatalytic remediation of treated agro-industrial wastewater

The conventional open ponding system employed for palm oil mill agro-effluent (POME) treatment fails to lower the levels of organic pollutants to the mandatory standard discharge limits. In this work, carbon doped black TiO₂ (CB-TiO₂ ) and carbon-nitrogen co-doped black TiO₂ (CNB-TiO₂ ) were synthesized via glycerol assisted sol-gel techniques and employed for the remediation of treated palm oil mill effluent (TPOME). Both the samples were anatase phase, with a crystallite size of 11.09–22.18 nm, lower bandgap of 2.06–2.63 eV, superior visible light absorption ability, and a high surface area of 239.99–347.26 m²/g. The performance of CNB-TiO₂ was higher (51.48%) compared to only (45.72%) CB-TiO₂ . Thus, the CNB-TiO₂ is employed in sonophotocatalytic reactions. Sonophotocatalytic process based on CNB-TiO₂, assisted by hydrogen peroxide (H₂O₂ ), and operated at an ultrasonication (US) frequency of 30 kHz and 40 W power under visible light irradiation proved to be the most efficient for chemical oxygen demand (COD) removal. More than 90% of COD was removed within 60 min of sonophotocatalytic reaction, producing the effluent with the COD concentration well below the stipulated permissible limit of 50 mg/L. The electrical energy required per order of magnitude was estimated to be only 177.59 kWh/m³, indicating extreme viability of the proposed process for the remediation of TPOME.