Abstract
Mesoporous polymer particles (MPPs) have been synthesized by using the spherical microparticles of siliceous mesocellular foam (MCF) as a hard template. The MPPs possessed a robust structure with ultralarge mesopores, and a clean and inert surface. The surface properties of the MPPs could be tailored for various applications by using different functionalized monomers. An imidazolium-pyrrolidine ligand was successfully immobilized onto MPPs and used as a supported platinum organometallic catalyst in olefin hydrosilylation. The MPP-supported catalyst provided superior activity and selectivity for this reaction as compared to the MCF-supported catalyst.
| Original language | English |
|---|---|
| Pages (from-to) | 662-666 |
| Number of pages | 5 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 350 |
| Issue number | 5 |
| DOIs | |
| State | Published - 25 Mar 2008 |
| Externally published | Yes |
Keywords
- Catalyst support
- Heterogeneous catalysis
- Hydrosilylation
- Mesoporous materials
- Platinum
ASJC Scopus subject areas
- Catalysis
- Organic Chemistry
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