Synergistic inhibition of mild steel corrosion by sodium phosphate with sodium tungstate

V. S. Saji*, S. M.A. Shibli

*Corresponding author for this work

Research output: Contribution to specialist publicationArticle

3 Scopus citations

Abstract

It is not feasible to use tungstate alone as a corrosion inhibitor in industrial cooling water systems due to its low oxidizing ability and high cost. The objective of this paper is to develop efficient synergistic inhibitor combinations that include very low concentrations of tungstate, keeping in a view their application in industrial cooling water system. The other inhibitor selected for this work is sodium phosphate, one of the cost-effective conventional inhibitors. Even though all the synergistic combinations studied in the present work showed high inhibition efficiency, a 4:1 ratio of sodium phosphate and sodium tungstate of total 1000ppm (800ppm SP + 200ppm ST) was found to be the optimum. The effect of temperature and depletion of the inhibitor solution were also studied. The metal oxide layer incorporated with tungstate and phosphate was found to cause effective passivation.

Original languageEnglish
Pages117-122
Number of pages6
Volume49
No3
Specialist publicationCorrosion Prevention and Control
StatePublished - Sep 2002
Externally publishedYes

ASJC Scopus subject areas

  • Metals and Alloys

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