Synergistic effect of reduced graphene oxide layers wrapped in polyaniline sheets to porous blades for boosted oxygen evolution reaction

  • Sajid Abbas
  • , Ghazala Yasmeen
  • , Suryyia Manzoor
  • , Sumaira Manzoor
  • , Dilshad Hussain
  • , Ammar Yousaf
  • , M. S. Al-Buriahi
  • , B. Alshahrani
  • , Muhammad Naeem Ashiq*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

14 Scopus citations

Abstract

Electrochemical water splitting is a unique approach for producing renewable energy in hydrogen fuel, though it is limited due to the sluggish kinetics of oxygen evolution reaction (OER). To enhance the efficacy of hydrogen production, it is a need to regulate oxygen evolution reaction. An efficient strategy is to construct a competent electrocatalyst with an immense open, active site, highly stable, porous structure, and large surface area. This study employs an inexpensive, facile, and eco-friendly single-step route to fabricate reduced graphene oxide (rGO) layers wrapped in polyaniline (PANI) sheets to achieve the controlled blades morphology. All the synthesized materials are characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), BET to examine their structural, morphological, and textural properties. Interestingly, when all the synthesized materials are employed for electrochemical measurements, rGO/PANI nanocomposite exhibits exceptional performance with a low overpotential of 221 mV to achieve a current density of 10 mA/cm2, lower Tafel slope of 37 mV/dec, and also high stability of 20 h. Overall, this work could lead up to the fabrication of innovative blade structured nanocomposite as an efficient electrocatalyst and make it applicable for multiple applications.

Original languageEnglish
Pages (from-to)960-970
Number of pages11
JournalJournal of Taibah University for Science
Volume15
Issue number1
DOIs
StatePublished - 2021
Externally publishedYes

Bibliographical note

Publisher Copyright:
© 2021 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group.

Keywords

  • Electrocatalyst
  • OER
  • alkaline medium
  • mesoporous
  • rGO/PANI nanocomposite

ASJC Scopus subject areas

  • General Chemistry
  • General Mathematics
  • General Biochemistry, Genetics and Molecular Biology
  • General Environmental Science
  • General Agricultural and Biological Sciences
  • General Physics and Astronomy
  • General Earth and Planetary Sciences

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