Sustainable valorization of asphaltenes via flash joule heating

  • M. A.S.R. Saadi
  • , Paul A. Advincula
  • , Md Shajedul Hoque Thakur
  • , Ali Zein Khater
  • , Shabab Saad
  • , Ali Shayesteh Zeraati
  • , Shariful Kibria Nabil
  • , Aasha Zinke
  • , Soumyabrata Roy
  • , Minghe Lou
  • , Sravani N. Bheemasetti
  • , Md Abdullah Al Bari
  • , Yiwen Zheng
  • , Jacob L. Beckham
  • , Venkataramana Gadhamshetty
  • , Aniruddh Vashisth
  • , Md Golam Kibria*
  • , James M. Tour*
  • , Pulickel M. Ajayan*
  • , Muhammad M. Rahman*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

58 Scopus citations

Abstract

The refining process of petroleum crude oil generates asphaltenes, which poses complicated problems during the production of cleaner fuels. Following refining, asphaltenes are typically combusted for reuse as fuel or discarded into tailing ponds and landfills, leading to economic and environmental disruption. Here, we show that low-value asphaltenes can be converted into a high-value carbon allotrope, asphaltene-derived flash graphene (AFG), via the flash joule heating (FJH) process. After successful conversion, we develop nanocomposites by dispersing AFG into a polymer effectively, which have superior mechanical, thermal, and corrosion-resistant properties compared to the bare polymer. In addition, the life cycle and technoeconomic analysis show that the FJH process leads to reduced environmental impact compared to the traditional processing of asphaltene and lower production cost compared to other FJH precursors. Thus, our work suggests an alternative pathway to the existing asphaltene processing that directs toward a higher value stream while sequestering downstream emissions from the processing.

Original languageEnglish
Article numbereadd3555
JournalScience advances
Volume8
Issue number46
DOIs
StatePublished - Nov 2022
Externally publishedYes

Bibliographical note

Publisher Copyright:
Copyright © 2022 The Authors, some rights reserved;

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 8 - Decent Work and Economic Growth
    SDG 8 Decent Work and Economic Growth
  2. SDG 15 - Life on Land
    SDG 15 Life on Land

ASJC Scopus subject areas

  • General

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